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51.
Deep InP Gratings for Opto-Electronic Devices Etched by C12/CH4/Ar Inductively Coupled Plasma 下载免费PDF全文
Deep InP gratings are etched by C12/CH4/Ar inductively coupled plasma (ICP) at room temperature. A comparison is made between SiNz mask patterns formed by wet and dry etching. SF6 reactive ion etching is adopted for smooth and vertical sidewall. The etching conditions of C12/CH4/Ar ICP are optimized for high anisotropy, and a 1.7-μm-deep InP grating with an aspect ratio of 10:1 is demonstrated. The technique is then used for the fabrication of 1.55-μm laterally coupled distributed feedback A1GMnAs-InP laser. 相似文献
52.
Ling Tian TANG Yi WANG Xin Qi LIU Shao Wen HU Tai Wei CHU Xiang Yun WANG* College of Chemistry Molecular Engineering Peking University Beijing 《中国化学快报》2005,16(3):345-348
Benzimidazole compounds have attracted a renewed interest recently owing to theirpotential applications in high-performance composite materials, electronic chemicals,photosensitive materials, and their special potentials in biological and/or medicinalapplication1,2. Typically, aromatic compounds with near planar structures and contain-ing hydrogen-donor groups or groups, which are capable of being protonated, havespecial interactions with DNA via intercalation, hydrogen-bonding, and so on3.Me… 相似文献
53.
Jia Rong Li~* Li Jun Zhang Xi Quan Yang Qing Li Dong Wang Chun Xia Wang Da Xin Shi Qi Zhang School of Chemical Engineering Environment Beijing Institute of Technology Beijing China 《中国化学快报》2008,(1)
Two different skeletons of heterocyclic compounds,quinoline and quinazolinone analogs could be obtained by a novel one-pot synthesis from substituted 3-amino-1 H-benzo[f]chromene-2-carbonitrile derivatives and cyclohexanone in DMF in the catalyst of anhydrous zinc chloride under reflux.A plausible mechanism was proposed. 相似文献
54.
Jing Lin CHEN Gang Qiang YIN Zhong Ning CHEN* State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Fuzhou 《中国化学快报》2003,(5)
Great attention is currently paid to the synthesis of polynuclear transition metal complexes as well as their photochemical, photophysical, and electrochemical properties. The design of multicomponent systems capable of performing useful light- and/or redox-induced function is of special interest1. The oxo-centered carboxylate-bridge trinuclear ruthenium clusters have been investigated extensively during recent decades because they have remarkable electron-transfer properties, intense visibl… 相似文献
55.
Dong Yu ZHAO Sheng Hua YANG Ming HU Xue Yi MA* Department of Chemistry National Laboratory of Applied Organic Chemistry Lanzhou University Lanzhou 《中国化学快报》2003,14(2)
Andrographolide (Andro) (Figure 1) is a diterpene lactone isolated from Andrographis paniculate Nees1. It has showed several biological activities including analgesic, antipyretic and anti-inflammatory effects2. However, its poor water solubility and unstability towards oxygen restrained its application. In pharmaceutics, b-CD is used to increase solubility and stability3. We have prepared the inclusion compound of Andro/b-CD (Figure 2) under microwave irradiation4. It has been found… 相似文献
56.
Vertical and Smooth, etching of InP by Cl2/CH4/Ar Inductively Coupled Plasma at Room Temperature 总被引:2,自引:0,他引:2 下载免费PDF全文
We study the room-temperature dry, etching of InP by inductively coupled plasma (ICP) using C12/CH4/Ar mixtures. Etches were characterized in terms of anisotropy and surface roughness by scanning electron microscopy and atomic force microscopy, respectively. It is found that the flow ratio between C12 and Ctt4, ICP power, rf chuck power, and table temperature can greatly influence the, etching results. By adjusting, etching parameters,vertical sidewall and smooth surface can be obtained simultaneously, together with a moderate, etch rate and a good select ratio. The root-mean-square surface roughness is measured to be as low as 0.27nm. To the best of our knowledge, this is the best result for InP to date. The, etch rate is 855nm/min, and the selectivity ratio overSi02 is estimated to be higher than 15:1. The stoichiometry of the, etched surface has also been investigated by Auger electron spectroscopy. The, etched surface is found to manifest a slight P deficiency, and the ratio between P and In reaches the stoichiometric value within about 0.75nm depth into the surface. 相似文献
57.
Investigation of External Optical Feedback Resistance of IC—DFB and GC—DFB Lasers Using a Very Simple Experimental set—up 下载免费PDF全文
We study the external optical feedback resistance of both index-coupled(IC) and gain-coupled distributed feed-back(DFB) lasers using a very simple experimental set-up.Though IC-DFB lasers with large coupling coefficients are found to be less sensitive to external reflection,they suffer from mode instability at high injection level.On the other hand ,the introduction of gain-coupling mechanism can significantly improve both the immunity of external optical feedback and the single mode yield of the device. 相似文献
58.
Ruo Jun SUN Hui JIANG Zhi Zhen HUANG* Department of Chemistry Zhejiang University Hangzhou 《中国化学快报》2003,(3)
Wittigreactionisoneofthemostimportantmethodfortheformationofcarbon-carbondoublebondandhasbeenwidelyusedinthesynthesisofnaturalproducts1,2.Recentlyitwasfoundthatalcoholscanundergoinsituoxidation-Wittigreactionwithphosponiumylidestogivecorrespondingolefinationproducts,whichhasgreatpotentialutilitiesinorganicsynthesis3.Tosimplifytheprocedureofthereactionfurther,weconsideredtocombinethedeprotonationofylide,oxidationofalcoholandWittigreactionintoonetandemreaction.Weutilizedphosphoniumorarsoniumsal… 相似文献
59.
~~Formation of α,α'-Bis(substituted benzylidene)cycloalkanones from Masked Aldehydes Promoted by Samarium(III) Triiodide~~ 相似文献
60.
Hydrogen peroxide biosensor based on electrodeposition of zinc oxide nanoflowers onto carbon nanotubes film electrode 总被引:2,自引:0,他引:2
Hui Ping Bai Xu Xiao Lu Guang Ming Yang Yun Hui Yang~* Department of Chemistry Chemical Engineering Yunnan Normal University Kunming China 《中国化学快报》2008,19(3):314-318
A new amperometric biosensor for hydrogen peroxide was developed based on adsorption of horseradish peroxidase at the glassy carbon electrode modified with zinc oxide nanoflowers produced by electrodeposition onto multi-walled carbon nanotubes (MWNTs) film. The morphology of the MWNTs/nano-ZnO electrode has been investigated by scanning electron microscopy (SEM), and the electrochemical performance of the electrode has also been studied by amperometric method. The resulting electrode offered an excellent detection for hydrogen peroxide at -0.11 V with a linear response range of 9.9×10^-7 to 2.9×10^-3 mol/L with a correlation coefficient of 0.991, and response time 〈5 s. The biosensor displays rapid response and expanded linear response range, and excellent stability. 相似文献