High quality electromagnetically induced transparency spectroscopy of ~(87)Rb in a buffer gas cell with a magnetic field

We have studied the phenomenon of electromagnetically induced transparency(EIT) of ~(87)Rb vapor with a buffer gas in a magnetic field at room temperature. It is found that the spectral lines caused by the velocity selective optical pump effects get much weaker and wider when the sample cell is mixed with a 5-Torr N_2 gas while the EIT signal is kept almost unchanged. A weighted least-square fit is also developed to remove the Doppler broadening completely. This spectral method provides a way to measure the Zeeman splitting with high resolution, for example, the Λ-type EIT resonance splits into four peaks on the D_2 line of ~(87)Rb in the thermal 2-cm vapor cell with a magnetic field along the electric field of the linearly polarized coupling laser. The high-resolution spectrum can be used to lock the laser to a given frequency by tuning the magnetic field.     

Exact quantum defect theory approach for lithium in magnetic fields

We calculate the diamagnetic spectrum of lithium at highly excited states up to the positive energy range using the exact quantum defect theory approach. The concerned excitation is one-photon transition from the ground state 2s to the highly excited states np with π and σ polarizations respectively. Lithium has a small quantum defect value 0.05 for the np states, and its diamagnetic spectrum is very similar to that of hydrogen in the energy range approaching the ionization limit. However, a careful calculation shows that the spectrum has a significant discrepancy with that of hydrogen when the energy is lower than 70cm-1 . The effect of the quantum defect is also discussed for the Stark spectrum. It is found that the σ transition to the np states in an electric field has a similar behavior to that of hydrogen due to zero interaction with channel ns.     

Theoretical simulation of ~(87)Rb absorption spectrum in a thermal cell

In this paper,we present a theoretical simulation of ~(87)Rb absorption spectrum in a thermal cm-cell which is adaptive to the experimental observation.In experiment,the coupling and probe beams are configured to copropagate but perpendicular polarized,making up to five velocity selective optical pumping(VSOP) absorption dips able to be identified.A A-type electromagnetically induced transparency(EIT) is also observed for each group of velocity-selected atoms.The spectrum by only sweeping the probe beam can be decomposed into a combination of Doppier-broadened background and three VSOP dips for each group of velocity-selected atoms,accompanied by an EIT peak.This proposed theoretical model can be used to simulate the spectrum adaptive to the experimental observation by the non-linear least-square fit method.The fit for the high quality of experimental observation can determine valuable transition parameters such as decaying rates and coupling beam power accurately.     

飞秒泵浦-探测质谱方法研究苯内转换动力学

以飞秒400及266 nm激光脉冲结合泵浦-探测飞行时间质谱方法研究了苯S2态内转换动力学. 400 nm双光子过程将苯分子激发到S2电子态,布居在S2电子态的分子由于能级耦合无辐射弛豫到S1电子态. 通过测定C6H6+讯号强度随泵浦-探测延迟时间的改变,获得苯S2及S1电子态的衰减寿命分别为(48±1)fs及(6.5±0.2)ps, S2态及S1电子态的消激发机理被认为是相应势能面间的锥形交叉引起的内转换.     

飞秒泵浦-探测实验数据分析

陈述了几种获取飞秒泵浦-探测实验数据中的光解动力学信息的解析物理模型.其中单分量和双分量模型用来解释母体分子的单通道和双通道解离过程,另一个单分量模型用来解释碎片分子的解离或去激发过程.所有模型都结合泵浦-探测实验数据予以解释.