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51.
A. Bergamin G. Cavagnero G. Mana G. Zosi 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,9(2):225-232
In order to reduce measurement uncertainty of the (220) lattice spacing of silicon to a few parts per 109, a combined X-ray and optical interferometer capable of millimeter scans is being tested. A new series of measurements confirmed
the value obtained with our previous set-up, and the bounds of measurement uncertainty were investigated. The article supplements
the analysis of the error budget and provides a safer footing for the monocrystalline silicon lattice parameter value.
Received 13 August 1998 相似文献
52.
The direct string computation of anomalous D-brane and orientifold plane couplings is extended to include the curvature of the normal bundle. The normalization of these terms is fixed unambiguously. New, non-anomalous gravitational couplings are found. 相似文献
53.
Lorena M. A. Silva Elenilson G. A. Filho Sérgio S. Thomasi Bianca F. Silva Antonio G. Ferreira Tiago Venâncio 《Magnetic resonance in chemistry : MRC》2013,51(9):541-548
The informal (and/or illegal) e‐commerce of pharmaceutical formulations causes problems that governmental health agencies find hard to control, one of which concerns formulas sold as natural products. The purpose of this work was to explore the advantages and limitations of DOSY and HPLC–UV–SPE–NMR. These techniques were used to identify the components of a formula illegally marketed in Brazil as an herbal medicine possessing anti‐inflammatory and analgesic properties. DOSY was able to detect the major components present at higher concentrations. Complete characterization was achieved using HPLC–UV–SPE–NMR, and 1D and 2D NMR analyses enabled the identification of known synthetic drugs. These were ranitidine and a mixture of orphenadrine citrate, piroxicam, and dexamethasone, which are co‐formulated in a remedy called Rheumazim that is used to relieve severe pain, but it is prohibited in Brazil because of a lack of sufficient pharmacokinetic and pharmacodynamic information. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
54.
半群上的Green(e)-关系是半群上通常Green's关系的一种推广.借助半群的左(右)S-系及半群的双系深入研究了Green(e)-关系的代数性质,证明了每个H(e)-类R(e)e∩L(e)f为一个强无挠的(H(e)e,H(e)f)-双系,其中e,f为幂等元,并给出了每个含幂等元的D(e)-类的代数结构. 相似文献
55.
We introduce a numerical method for the numerical solution of the Lur'e equations, a system of matrix equations that arises, for instance, in linear‐quadratic infinite time horizon optimal control. We focus on small‐scale, dense problems. Via a Cayley transformation, the problem is transformed to the discrete‐time case, and the structural infinite eigenvalues of the associated matrix pencil are deflated. The deflated problem is associated with a symplectic pencil with several Jordan blocks of eigenvalue 1 and even size, which arise from the nontrivial Kronecker chains at infinity of the original problem. For the solution of this modified problem, we use the structure‐preserving doubling algorithm. Implementation issues such as the choice of the parameter γ in the Cayley transform are discussed. The most interesting feature of this method, with respect to the competing approaches, is the absence of arbitrary rank decisions, which may be ill‐posed and numerically troublesome. The numerical examples presented confirm the effectiveness of this method. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
56.
《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(34):10232-10236
QM/MM calculations reveal that the nickel pincer complex in lactate racemase functions as a reversible “single‐center electrode” that accepts and donates back an electron. In this way, it catalyzes the isomerization process d ‐lactate⇌l ‐lactate through successive proton‐coupled electron‐transfer steps. 相似文献
57.
Khoder Makkawi Nourdine Ait-Tmazirte Maan El Badaoui El Najjar Nazih Moubayed 《Entropy (Basel, Switzerland)》2021,23(4)
When applying a diagnostic technique to complex systems, whose dynamics, constraints, and environment evolve over time, being able to re-evaluate the residuals that are capable of detecting defaults and proposing the most appropriate ones can quickly prove to make sense. For this purpose, the concept of adaptive diagnosis is introduced. In this work, the contributions of information theory are investigated in order to propose a Fault-Tolerant multi-sensor data fusion framework. This work is part of studies proposing an architecture combining a stochastic filter for state estimation with a diagnostic layer with the aim of proposing a safe and accurate state estimation from potentially inconsistent or erroneous sensors measurements. From the design of the residuals, using α-Re9;nyi Divergence (α-RD), to the optimization of the decision threshold, through the establishment of a function that is dedicated to the choice of α at each moment, we detail each step of the proposed automated decision-support framework. We also dwell on: (1) the consequences of the degree of freedom provided by this α parameter and on (2) the application-dictated policy to design the α tuning function playing on the overall performance of the system (detection rate, false alarms, and missed detection rates). Finally, we present a real application case on which this framework has been tested. The problem of multi-sensor localization, integrating sensors whose operating range is variable according to the environment crossed, is a case study to illustrate the contributions of such an approach and show the performance. 相似文献
58.
Frank Nielsen 《Entropy (Basel, Switzerland)》2021,23(4)
We generalize the Jensen-Shannon divergence and the Jensen-Shannon diversity index by considering a variational definition with respect to a generic mean, thereby extending the notion of Sibson’s information radius. The variational definition applies to any arbitrary distance and yields a new way to define a Jensen-Shannon symmetrization of distances. When the variational optimization is further constrained to belong to prescribed families of probability measures, we get relative Jensen-Shannon divergences and their equivalent Jensen-Shannon symmetrizations of distances that generalize the concept of information projections. Finally, we touch upon applications of these variational Jensen-Shannon divergences and diversity indices to clustering and quantization tasks of probability measures, including statistical mixtures. 相似文献
59.
In this paper, we present order invariance theoretical results for weighted quasi-arithmetic means of a monotonic series of numbers. The quasi-arithmetic mean, or Kolmogorov–Nagumo mean, generalizes the classical mean and appears in many disciplines, from information theory to physics, from economics to traffic flow. Stochastic orders are defined on weights (or equivalently, discrete probability distributions). They were introduced to study risk in economics and decision theory, and recently have found utility in Monte Carlo techniques and in image processing. We show in this paper that, if two distributions of weights are ordered under first stochastic order, then for any monotonic series of numbers their weighted quasi-arithmetic means share the same order. This means for instance that arithmetic and harmonic mean for two different distributions of weights always have to be aligned if the weights are stochastically ordered, this is, either both means increase or both decrease. We explore the invariance properties when convex (concave) functions define both the quasi-arithmetic mean and the series of numbers, we show its relationship with increasing concave order and increasing convex order, and we observe the important role played by a new defined mirror property of stochastic orders. We also give some applications to entropy and cross-entropy and present an example of multiple importance sampling Monte Carlo technique that illustrates the usefulness and transversality of our approach. Invariance theorems are useful when a system is represented by a set of quasi-arithmetic means and we want to change the distribution of weights so that all means evolve in the same direction. 相似文献
60.
Stochastic Configuration Network (SCN) has a powerful capability for regression and classification analysis. Traditionally, it is quite challenging to correctly determine an appropriate architecture for a neural network so that the trained model can achieve excellent performance for both learning and generalization. Compared with the known randomized learning algorithms for single hidden layer feed-forward neural networks, such as Randomized Radial Basis Function (RBF) Networks and Random Vector Functional-link (RVFL), the SCN randomly assigns the input weights and biases of the hidden nodes in a supervisory mechanism. Since the parameters in the hidden layers are randomly generated in uniform distribution, hypothetically, there is optimal randomness. Heavy-tailed distribution has shown optimal randomness in an unknown environment for finding some targets. Therefore, in this research, the authors used heavy-tailed distributions to randomly initialize weights and biases to see if the new SCN models can achieve better performance than the original SCN. Heavy-tailed distributions, such as Le9;vy distribution, Cauchy distribution, and Weibull distribution, have been used. Since some mixed distributions show heavy-tailed properties, the mixed Gaussian and Laplace distributions were also studied in this research work. Experimental results showed improved performance for SCN with heavy-tailed distributions. For the regression model, SCN-Le9;vy, SCN-Mixture, SCN-Cauchy, and SCN-Weibull used less hidden nodes to achieve similar performance with SCN. For the classification model, SCN-Mixture, SCN-Le9;vy, and SCN-Cauchy have higher test accuracy of 91.5%, 91.7% and 92.4%, respectively. Both are higher than the test accuracy of the original SCN. 相似文献