基于磁性纳米复合棒的“咖啡环”效应

研究了含有不溶性纳米复合棒的液滴在蒸发过程中出现的"咖啡环"效应,证实了"咖啡环"现象的形成和抑制与液滴体积、液滴浓度、基底温度、表面活性剂添加量及外加磁场等因素有关,并根据实验数据拟合"咖啡环"宽度与实验参量间的关系.证实了减小液滴体积、增大液滴浓度或升高基底温度,导致"咖啡环"变宽,而添加表面活性剂或施加外磁场则能够抑制"咖啡环"效应的出现.建立了磁性纳米复合棒在液滴蒸发过程中的受力模型,探讨了液滴重力、毛细流引起的牵引力、马兰戈尼流引起的牵引力及外加磁场提供的牵引力对"咖啡环"的形成及其宽度的调控影响规律.     

Facile fabrication of highly flexible,porous PEDOT: PSS/SWCNTs films for thermoelectric applications

High-performance organic composite thermoelectric(TE)materials are considered as a promising alternative for harvesting heat energy.Herein,composite films of poly(3,4-ethyienedioxythiophene):poly(styrene sulfonate)/single-walled carbon nanotubes(PEDOT:PSS/SWCNTs)were fabricated by utilizing a convenient solution mixing method.Thereafter,the as-prepared hybrid films were treated using sulfuric acid(H₂SO₄)to further optimize the TE performance.Film morphological studies revealed that the sulfuric acid treated PEDOT:PSS/SWCNTs composite samples all possessed porous structures.Due to the successful fabrication of highly conductive networks,the porous nano-architecture also exhibited much more excellent TE properties when compared with the dense structure of the pristine samples.For the post-treated sample,a high power factor of 156.43μW·m^-1·K^-2can be achieved by adjusting the content of CNTs,which is approximately 3 orders of magnitude higher than that of the corresponding untreated samples(0.23μW·m^-1·K^-2).Besides,the obtained films also showed excellent mechanical flexibility,owing to the porous nanostructure and the strong p–p interactions between the two components.This work indicates that the H₂SO₄ treatment could be a promising strategy for fabricating highly-flexible and porous PEDOT:PSS/SWCNTs films with high TE performances.     

Fifty-five km reach,bidirectional, 400 Gb/s(40×10 Gb/s), channel-reuse DWDM–PON employing a self-wavelength managed tunable laser

We experimentally demonstrate a channel-reuse bidirectional 10 Gb∕s∕λ long-reach dense wavelength-division multiplexing passive optical network(DWDM-PON) and an optical beat-noise-based automatic wavelength control method for a tunable laser used in a colorless optical network unit(where λ· wavelength). A55 km, bidirectional, 400 Gb/s(40 × 10 Gb∕s) capacity channel-reuse transmission with 100 GHz channel spacing is achieved. The transmission performance is also measured with different optical signal to Rayleigh backscattering noise ratios and different central wavelength shifts between upstream and downstream in the channel-reuse system.     

太阳能热光伏系统辐射器热设计

本文针对太阳能热光伏系统中的能量吸收模块,建立了不同结构的灰体辐射吸收器吸收太阳能及瞬态导热过程的数理模型.通过数值模拟获得了吸收相同太阳能时各辐射器的温度分布及能量泄漏量,结果表明在四种辐射器结构中,球形辐射器具有较好的辐射热性能,更适用于STPV系统;而通过将四种不同材料的选择性辐射器和灰体辐射器比较发现,选择性辐射器可显著减小辐射能量中的不可用部分,从而提高系统性能和稳定性.     

火焰原子吸收光谱法连续测定化探样品中的银、铜、铅和锌

样品以氢氟酸、硝酸、高氯酸分解.制成HCl(1+9)溶液,在空气-乙炔火焰中,水相直接测定铜、锌,TOA-MIBK萃取,有机相中测定银、铅.     

辐照诱变对小麦生理学效应的影响

以小麦品种小偃81为材料, 利用低能N+离子, 60Co-γ射线以及紫外线UV-C等为诱变源, 对种子胚部进行辐照处理。 研究其对小麦发芽势、 发芽率、 根长及苗高等生理指标的影响。 以辐照后的幼苗为材料研究了低能N+注入对过氧化氢酶（CAT）、 过氧化物酶（POD）、 超氧化物歧化酶（SOD）活性及还原型谷胱甘肽（GSH）含量的影响。 研究结果表明: N+注入后种子活力先升高后降低, 苗高在5×1017 N+/cm2时显著低于对照; 60Co和紫外线辐照对种子活力有较显著的影响, 辐照后的根长和苗高均显著低于对照; N+束辐照后的幼苗CAT酶活随剂量的变化规律性不明显, POD和SOD酶活总体趋势随剂量的增加先升高后降低, GSH含量随剂量的增大先降低后升高。 由此可知, 辐照诱变可以诱导小麦一系列的生理变化。60Co-γ射线和紫外线UV C对小麦胚根的伤害较大, 导致幼苗在后期大量死亡。N+注入对小麦的损伤效应较60Co和紫外线γ射线和紫外线UV-C小, 一定注量的N+注入处理可促进小麦生长。 In this paper, the biological effects,such as germination percentage, germination index and the length of seedlings and roots were investigated by using low energy N+, 60Co- γ rays and ultraviolet UV C to irradiate the embryos of wheat seeds （Xiaoyan81）. The anti oxidative enzyme system (CAT,POD, SOD) and GSH content were studied as well. The results show that the vitality of seed increased and then reduced with increasing the dosage of N+ ion implantation. The length of roots and seedlings were significantly higher than control. The seed vigor was significant effected after irradiated by 60Co-γ rays and ultraviolet UV-C, but the length of roots and seedlings were significantly lower than control. After N+ implantation, the changing pattern of CAT was not obviously. The enzymatic activity of POD and SOD were increased at low dosage and reduced at high dosage. The content of GSH was reduced and then raised. The results proved that the damage induced by γ ray and UV C to the radicle of wheat was severe that result in a large number of seedling died. However the damage induced by N+ implantation was lower than that by rays and UV C irradiation. Certain dosage of ion implantation can promote the growth of wheat.     

聚乙二醇二甲基丙烯酸酯整体柱固相萃取-高效液相色谱法测定血清中卡马西平和10-羟基卡马西平

使用乙二醇二甲基丙烯酸酯（EDMA）在注射器中构筑固相萃取整体柱,并结合高效液相色谱法,建立了测定血清中卡马西平（CBZ）和10-羟基卡马西平（MHD）的分析方法。实验考察了反应温度和反应时间对整体柱萃取性能的影响和淋洗溶液种类、洗脱溶液种类及体积对固相萃取的影响。在优化条件下,该固相萃取柱对血清中CBZ和MHD能够有效富集、净化。对0.02~40 μg/mL CBZ和0.05~100 μg/mL MHD标准溶液进行分析,结果表明,在各自的范围内CBZ和MHD线性关系良好,相关系数（r）均为0.999。CBZ和MHD的检出限分别为0.004 μg/mL和0.01 μg/mL;在3个加标水平下,CBZ和MHD的平均回收率分别为92.7%和94.2%,日内（n=3）和日间（n=3） RSD≤6.1%。该固相萃取柱批内（n=3）和批间（n=5） RSD≤5.3%,反复使用8次的RSD≤5.8%。该法简单、高效,适用于癫痫患者血清中CBZ和MHD的测定。     

醇酮环合法合成dl-麝香酮

麝香酮(β-甲基环十五烷酮)是天然麝香的组成成分,并具有天然麝香某些重要的药理作用,本文报道它的合成工艺和纯化的研究。有关麝香酮的合成方法,国内外报道很多^[1]。我们选用α,ω-长链二元酸酯进行醇酮环合法制备dl-麝香酮。早先Stoll和Commarmont^[2]报道用β-甲基十五烷二酸双乙酯经醇酮环合法合成dl-麝香酮。     

高效时空同步四阶熵稳定格式

求解双曲守恒律方程的高阶半离散熵稳定方法在时间方向上采用Runge-Kutta型方法时,算法的计算效率较低,Lax-Wendroff型时间离散方法为这一问题的解决提供了新思路．将WENO (Weighted Essentially NonOscillatory)型四阶熵稳定格式与Lax-Wendroff型两步四阶时间离散方法相结合求解双曲守恒律方程,时空同步可达到四阶精度．相较于流行的Runge-Kutta型时间离散方法,Lax-Wendroff型两步四阶方法只需两步就可以达到四阶精度,从而可提高计算效率．多个不同类型双曲型方程数值结果表明：新的耦合算法计算效率有明显提高,一维问题计算效率至少提高35%,二维问题计算效率至少提高39%,且新算法依旧具有熵稳定性,数值结果分辨率高．     

POLYNOMIAL REPRESENTATIONS OF THE h AFFINE NAPPI-WITTEN LIE ALGEBRA H4

In this paper,the representation theory for the affine Lie algebra H4 associated to the Nappi-Witten Lie algebra H4 is studied.Polynomial representations of the affine Nappi-Witten Lie algebra H4 are given.