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41.
1引言香豆素是一类具有重要生理活性的天然产物,具抗凝血、抗肿瘤、抗病毒等多种活性,最近又发现某些香豆素化合物具有钙桔抗活性[‘,’]。目前对此类物质钙站抗活性的研究国内外还开展较少。我们设计合成了一系列苯并吠哺并香豆素化合物,选取其中三个(;、D。、D3)$0一个简单二羟基香豆素(C。)经放射性‘’Ca跨膜流动技术测定,表明其对电压依赖性钙离于通道(PDC)均有较显著阻滞作用(见表1)。其中D。未见文献报道,其结构经NMR、IR、MS确证。已知物D;、D。和C。的钙通道阻滞活性尚未见其它文献报道… 相似文献
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The relation between diffractive beam parameters and normalized frequency is analyzed that leads to two improved Tormulas for two kinds of mode-field halT-widths and several formulas for divergence angle as well as beam propagation factor. The numerical calculation indicates that the maximal relative error is less than 0.5% within a reasonable parameter range. 相似文献
44.
In this paper, a compound binomial model with a constant dividend barrier and random income is considered. Two types of individual claims, main claims and by-claims, are defined, where every by-claim is induced by the main claim and may be delayed for one time period with a certain probability. The premium income is assumed to another binomial process to capture the uncertainty of the customer's arrivals and payments. A system of difference equations with certain boundary conditions for the expected present value of total dividend payments prior to ruin is derived and solved. Explicit results are obtained when the claim sizes are Kn distributed or the claim size distributions have finite support. Numerical results are also provided to illustrate the impact of the delay of by-claims on the expected present value of dividends. 相似文献
45.
颗粒分离的物理机制目前没有统一解释.本文采用三维离散元模型,模拟了剪切槽内两种尺度的球形二元颗粒在高度方向上位置互相颠倒的现象.关注大颗粒跃升过程中的运动学和动力学行为特征,观测到大颗粒跃升过程分三个阶段:弛豫阶段、起跳阶段和平衡阶段.定量分析了摩擦系数对颗粒受力等具体影响.结果显示弛豫时间随着摩擦系数的增大而减少,颗粒最终的平衡高度随着摩擦系数的增大而增大.定义了浮升因子,发现浮升因子在大颗粒起跳点处陡降,形成大颗粒跃升的"窗口时间".揭示大颗粒的起跳是受力脉动高频特性和浮升因子陡降两个因素共同作用的结果,即颗粒的上升运动由受力和周围空间决定. 相似文献
46.
Robust H∞state estimation for a class of complex networks with dynamic event-triggered scheme against hybrid attacks 下载免费PDF全文
We investigate the dynamic event-triggered state estimation for uncertain complex networks with hybrid delays suffering from both deception attacks and denial-of-service attacks.Firstly,the effects of time-varying delays and finitedistributed delays are considered during data transmission between nodes.Secondly,a dynamic event-triggered scheme(ETS)is introduced to reduce the frequency of data transmission between sensors and estimators.Thirdly,by considering the discussed plant,dynamic ETS,state estimator,and hybrid attacks into a unified framework,this framework is transferred into a novel dynamical model.Furthermore,with the help of Lyapunov stability theory and linear matrix inequality techniques,sufficient condition to ensure that the system is exponentially stable and satisfies H∞performance constraints is obtained,and the design algorithm for estimator gains is given.Finally,two numerical examples verify the effectiveness of the proposed method. 相似文献
47.
空芯反谐振光纤由于其优异的光学特性,如低非线性、超低群速度色散、低温度敏感性和高损伤阈值等,使其在大功率激光传输、量子通信、传感、航空航天等多个领域有着潜在的应用,成为未来最具发展潜力的特种光纤.由于空芯反谐振光纤能够将99.9%以上光场限制在光纤的空芯区域中,这也使其成为光纤滤波器、模式转换等领域的重要光子器件.本文针对980 nm单模激光器的迫切需求,研制了一种应用于980 nm多模激光转980 nm单模激光的空芯反谐振光纤,并对其应用进行了实验验证. 相似文献
48.
碳中和发展理念的提出使得生物质基催化剂的关注度不断提高,将木质素作为过渡金属催化剂的载体来制备非均相催化剂应用于有机合成领域,可以极大地提高木质素的利用价值.木质素结构中广泛存在的含氧官能团为金属催化剂的负载提供了多种结合位点,通过物理吸附/沉积、离子交换以及与羟基官能团通过静电络合可以有效地捕获金属粒子.首先介绍了木质素的结构,然后介绍了制备非均相催化剂的方法,重点介绍了木质素及其衍生物负载金属催化剂催化点击反应、Glaser反应、Huisgen [3+2]环加成反应、Heck反应、Suzuki反应、Sonogashira反应、Stille偶联反应、迈克尔加成/脱水串联反应、亲电开环反应、Fridel-Crafts型反应及乙烯聚合反应等,并对存在的问题和发展趋势进行了展望. 相似文献
49.
Electroluminescence from the InGaN/GaN Superlattices Interlayer of Yellow LEDs with Large V-Pits Grown on Si(111) 下载免费PDF全文
A blue emission originated from In GaN/GaN superlattice(SL) interlayer is observed in the yellow LEDs with V-pits embedded in the quantum wells(QWs), revealing that sufficient holes have penetrated through the QWs into SLs far away from the p-type layer. In the V-pits embedded LEDs, hole transport has two paths: via the flat c-plane region or via the sidewalls of V-pits. It is proved that the holes in SLs are injected from the sidewalls of V-pits, and the transportation process is significantly affected by working temperature, current density, and the size of V-pits. Four motion possibilities are discussed when the holes flow via the sidewalls. All these may contribute to a better understanding of hole transport and device design. 相似文献
50.
Effect of AlGaN interlayer on luminous efficiency and reliability of GaN-based green LEDs on silicon substrate 下载免费PDF全文
The effect of AlGaN interlayer in quantum barrier on the electroluminescence characteristics of GaN-based green light emitting diodes(LEDs)grown on silicon substrate was investigated.The results show that AlGaN interlayer is beneficial to improve the luminous efficiency of LED devices and restrain the phase separation of In GaN.The former is ascribed to the inserted AlGaN layers can play a key role in determining the carrier distribution and screening dislocations in the active region,and the latter is attributed to the increased compressive stress in the quantum well.However,when the electrical stress aging tests were performed at a current density of 100 A/cm^2,LED devices with AlGaN interlayers are more likely to induce the generation/proliferation of defects in the active region under the effect of electrical stress,resulting in the reduced light output power at low current density. 相似文献