系列类立方烷型Fe4S4簇合物的XPS分析

对7种类立方烷型Fe_4S_4簇合物进行了XPS分析,得到了中心离子Fe的价态,给出了系列Fe_4S_4中骨架硫的结合能,由峰合成结果给出各种S、N的比例与按结构式计算的结果相同。     

C_nP_4~4(n=1～7)团簇结构与能量的密度泛函研究

使用分子图形软件设计出多种CnP-4(n =1～ 7)的结构模型 ,并进行B3LYP密度泛函几何构型优化和振动频率计算 .最稳定的CP-4和C2 P-3 都是平面环状结构 .最稳定的CnP-4(n =3 ,5 ,7)结构在直碳链的一端连接 1个磷原子且另一端是P3 C的四元环的平面结构 .最稳定的CnP-4(n =4,6)结构在直碳链的一端连接 1个磷原子且另一端是P3 的三元环的锄状结构 .直碳链可与平面环的磷原子生成大π键 .大多数构型是由C2 ,C3 ,C4子结构以环状或链状方式组成的 .碳原子与磷原子以交替方式排列的结构数量少、能量高 .     

牛血清白蛋白对Pluronic聚合物胶团形成的影响研究

用吡啶作为荧光探针研究了嵌段共聚物PluronicF108胶团形成以及牛血清白蛋白(BSA)对嵌段共聚物胶团形成的影响。研究表明,BSA阻碍嵌段共聚物的胶团形成,BSA与嵌段共聚物疏水链段的疏水相互作用是其阻碍嵌段共聚物胶团形成的主要原因。     

Time-Resolved Investigation of Ionization of Clusters Irradiated by a Strong Laser

Ionization dynamics of clusters irradiated by chirped femtosecond lasers is investigated by using a linearly chirped pulse spectral interferometry with a time resolution of less than lOOfs. The production of an average charged-Xe^18 and -Kr^9 ions indicates a strong energy coupling between laser and cluster. Ultrafast depletion of the probing laser is observed to be strictly coincident with the ionization front as seen in other experiments. Moreover,a two-step ionization process for Xe and Kr clusters irradiated by high-intensity lasers has been observed, which implies the role of resonance enhancement during the cluster explosion.     

氚化钛中氦的热解析

氚以金属氚化物贮存形式过程中，会衰变生成氦-3，从而影响金属氚化物的使用性能。文中采用热解析方法研究了不同贮存周期氦在金属氚化物中的能量状态的变化情况。     

再论q^—图

本文在文[1]的基础上,讨论了没有q-割团、但有(q+1)-割团且q-色唯一的q-图的结构。     

一维He与超短强激光脉冲相互作用的经典模型

采用经典理论研究了一维氦原子与超短强激光脉冲相互作用的动力学过程 .利用经典理论中的系综平均方法 ,对氦原子的一阶和二阶电离几率的时间演化进行了数值模拟 .并对模拟结果进行了分析 .     

A Heterogeneous Agent Herding Model with Time and Space Effect

We propose a heterogeneous agent herding model, in which the agent clusters are in active or inactive states. When agent clusters are in active states, they tend to buy or sell. In active states, an exchange may occur when two heterogeneous agent clusters encounter each other, and they may merge into a bigger one when two homogeneous agent clusters meet. The ratio of successful exchange or merging depends on two parameters： i.e. the reliability κ, reflecting the credible degree in the interacting agent clusters, being the space effect of the market, and the response degree q, reflecting the influence of the former trading to the current action, being the time effect of the market. Our numerical calculation shows that the dynamics of the model exhibits some behaviour very close to real markets when tuning the reliability and the degree of reaction to some specific values.     

FULL DISCRETE NONLINEAR GALERKIN METHOD FOR THE NAVIER-STOKES EQUATIONS

This paper deals with the inertial manifold and the approximate inertial manifold concepts of the Navier-Stokes equations with nonhomogeneous boundary conditions and inertial algorithm. Furtheremore, we provide the error estimates of the approximate solutions of the Navier-Stokes Equations.