Synthesis and unusual properties of novel alkylbenzene sulfonate gemini surfactants

Seven new dialkyldibenzene disulfonate gemini surfactants have been synthesised. The physico-chemical properties such as their surface tensions, krafft temperatures and melting temperatures have been measured. It was found that the anionic gemini surfactants showed some aberrant properties. The results determined by drop-volume method indicated that surfactants Id, Ie at 25 °C and IIb at 50 °C showed no cmc and lowered surface tension of water hardly despite their seemingly favorable amphiphilic components. However, the three surfactants showed a sharp cmc and good surface activity with the increment of temperature. Surfactant Ie with two longer chains had a higher cmc than that for shorter chain surfactant Id. Furthermore, for this class of anionic gemini surfactants, the spacer carbon number had more important effects than the alkyl chain carbon number on their krafft temperatures and melting temperatures.     

Vibrational spectroscopic study of the electron transfer for the Cl- + CH3Cl S(N)2 reaction in the gas phase

The vibrational spectra study of electron transfer of Cl- + CH3Cl --> ClCH3 + Cl- reaction has been examined by density function theory (DFT) calculations at 6-311 + +G** level in this paper. This reaction includes old bond rupture, new bond formation and electronic transfer in the intermolecular. The vibrational frequencies and vibrational modes of reactant, precursor complex, transition state, successor complex and product are analyzed. The relationship and the change among them can confirm the rupture of bond, the formation of bond and the process of electron transfer.     

REDUCIBILITY OF REVERSIBLE SYSTEM WITH SMALL PERTURBATION

Reversible system following Hamiltonian system turns out to be another type of equation which has aroused wide interest in recent years. One open problem is whether the celebrated KAM theory and Nekhoroshev method can be extended to reversible system. As showed in [5], there exist KAM tori in reversible system. In this paper, we give a preliminary discussion on whether there is Nekhoroshev type result in reversible system. In particular, we try to apply this method to the reducibility of a type of common reversible system.     

金属原子（离子）-苯配合物的电子转移反应

用密度泛函理论（ＤＦＴ／ＢＬＹＰ）在６－３１Ｇ基组水平上研究了金属原子－苯与离子－苯配合物的气相电子转移过程,得到了Ｍ（Ｌｉ,Ｎａ,Ｍｇ）－Ｃ６Ｈ６和Ｍ＾＋－Ｃ６Ｈ６络合物以及它们之间电子转移过程的先驱络合物的最优几何构型和电子结构。同时,利用线性坐标确定了过滤态的结构,结果表明：ＤＦＴ方法计算得到的单体,即原子（离子）－苯的构型,同ＭＰ２结果较为一致。先驱络合物具有Ｃ６ν对称性,给体与受体间距离     

行波光参量过程的理论与实验研究

通过对行波光参量三波耦合过程时域特性的理论计算,预示了光参量时域过程可能存在“弛豫”振荡,理论与实验相结合分析了抽运光强度、晶体长度、腔长、输出耦合系数等一系列参数对参量输出的影响,并采用一种新的棱镜环形腔进行实验,得到从０．４１～２．６ｕｍ的连续宽调谐输出和２２％折能量转换效率。     

非定常IV型激波－激波干扰数值模拟研究

对IV型激波-激波干扰非定常流动进行了数值模拟，采用有限体积法，结合空间半隐的二阶OC-TVD格式与时间二阶显式Runge-Kutta法求解三维全N-S方程，并且使用了Baldwin-Lomax代数湍流模型．得到了周期性流场变化结果，其中包括周期变化的双涡结构．壁面压强峰值的大小和位置均呈周期性振动，壁面压力系数和Stanton数的时均分布与定常实验结果符合得较好．并从一周期内流场结构的扰动传播出发，分析了结构变化的相位，说明了IV型激波一激波干扰内在的非定常性机理与影响因素。     

Preparation of highly dispersed Pt-SnOx nanoparticles supported on multi-walled carbon nanotubes for methanol oxidation

To maximize the utilization of catalysts and thereby reduce the high price, a new strategy was developed to prepare highly dispersed Pt-SnO_x nanoparticles supported on 8-Hydroxyquinoline (HQ) functionalized multi-walled carbon nanotubes (MWCNTs). HQ functionalized MWCNTs (HQ-MWCNTs) provide an ideal support for improving the utilization of platinum-based catalysts, and the introduction of SnO_x to the catalyst prevents the CO poisoning effectively. The as-prepared catalysts are characterized by Transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. It is found that the HQ functionalization process preserves the integrity and electronic structure of MWCNTs, and the resulting Pt-SnO_x particles are well dispersed on the HQ-MWCNTs with an average diameter of ca. 2.2 nm. Based on the electrochemical properties characterized by cyclic voltammetry and chronoamperometry, the Pt-SnO_x/HQ-MWCNTs catalyst displays better electrocatalytic activity and stability for the methanol oxidation. It is worth mentioning that the forward peak current density of Pt-SnO_x/HQ-MWCNTs catalyst is ca. 1.9 times of that of JM commercial 20% Pt/C catalyst, which makes it the preferable catalyst for direct methanol fuel cells.