首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2965篇
  免费   38篇
  国内免费   62篇
化学   1133篇
晶体学   15篇
力学   115篇
数学   1004篇
物理学   798篇
  2022年   27篇
  2020年   19篇
  2019年   20篇
  2018年   24篇
  2017年   38篇
  2016年   36篇
  2015年   38篇
  2014年   72篇
  2013年   131篇
  2012年   102篇
  2011年   138篇
  2010年   111篇
  2009年   103篇
  2008年   127篇
  2007年   118篇
  2006年   137篇
  2005年   128篇
  2004年   99篇
  2003年   109篇
  2002年   82篇
  2001年   74篇
  2000年   57篇
  1999年   69篇
  1998年   43篇
  1997年   41篇
  1996年   44篇
  1995年   47篇
  1994年   23篇
  1993年   28篇
  1992年   31篇
  1991年   38篇
  1990年   35篇
  1989年   41篇
  1988年   71篇
  1987年   85篇
  1986年   67篇
  1985年   46篇
  1984年   37篇
  1983年   43篇
  1982年   50篇
  1981年   53篇
  1980年   41篇
  1979年   34篇
  1978年   37篇
  1977年   28篇
  1976年   28篇
  1975年   37篇
  1974年   34篇
  1973年   33篇
  1972年   20篇
排序方式: 共有3065条查询结果,搜索用时 15 毫秒
41.
Formation of core-shell poly(N-vinylcaprolactam) (PVCL) single-molecule nanostructures due to interaction of PVCL with metal ions was studied using transmission electron microscopy, 13C NMR, and light scattering. This study demonstrates that addition of CoCl2 to PVCL in its globular conformation yields unimolecular core-shell polymer particles with the core decorated with Co(II) ions. The crucial condition for formation of well-defined unimolecular nanostructures is the presence of stable globular aggregates in aqueous solution. Moreover, the metal ions should have a sufficiently high coordination number (higher than 2) to provide a cross-linking and stabilization of the core.  相似文献   
42.
Applied Biochemistry and Biotechnology - Photoproduction of H2 by green algae utilizes electrons originating from the photosynthetic oxidation of water and does not require metabolic intermediates....  相似文献   
43.
Treatment of the disodium salts of 7,8- and 7,9-B9H9CHE2? with germanium diiodide in refluxing benzene results in the formation of 1,2,3- and 1,2,7-GeB9H9CHE (E = P or As), icosahedral boranes containing three different heteroatoms in the cage. Heating 1,2,7-GeB9H9CHP at 512° for 8 hours in an evacuated sealed tube yields a mixture of three new isomers one of which has been isolated and characterized.  相似文献   
44.
The current status of plasma source-mass spectrometry (PS-MS) is reviewed. An overview of interference effects that exist, alternative plasma sources available, and mass spectrometer interface studies is provided. A discussion of current and future development areas in plasma source mass spectrometry is also included.  相似文献   
45.
A simple and rapid single-step method is presented to fabricate an enzyme reactor using trypsin immobilized on a macroporous polymer monolith. A reactor produced in a capillary format is ready to use within 1 h of preparation. The monomers making up the monolith, including N-acryloxysuccinimide for covalent immobilization of the enzyme, are mixed with trypsin and introduced into the column by capillary force for polymerization/immobilization. The enzyme activity from column-to-column is reproducible below 5% relative standard deviation (RSD), while the reactor is durable for at least 20 weeks when stored at room temperature. The apparent kinetic constants V(max) and K(m) are of value similar to those obtained by free trypsin in solution. Enzymatic digestion of proteins was shown to be feasible on a time-scale of seconds and submicromolar concentrations enabling peptide mass mapping by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry.  相似文献   
46.
We study a discrete dynamical system whose evolution is governed by rules similar to those of Conway's game of Life but also include a stochastic element (parametrized by a temperature). Statistical properties that are examined are density as a function of temperature and entropy (suitably defined). A phase transition and a certain thermodynamic constant of the motion are observed.Lady Davis Visiting Scientist at the Technion 1974–75.  相似文献   
47.
A straightforward synthesis of aziridines is reported from an electron-rich azide (alkyl or aryl azide), electron-deficient olefin, and triflic acid in cold acetonitrile. The only coproduct of the reaction is dinitrogen (N2). Active ester substrates bearing a nucleophilic carbonyl engage the putative protonated aziridine intermediate to produce the product of olefin aminohydroxylation in which the nitrogen is benzyl protected and the oxygen is acylated. The possibility that a triazoline need not be an intermediate in aziridine production is advanced.  相似文献   
48.
The purpose of this paper is to study the appearance of time asymmetry in dynamical systems. The systems are harmonic oscillators and a certain mixing flow on the torus. The asymmetry is a kind of frictional force, but we emphasize that the boundary conditions, a usual source of asymmetry in studies of this sort, are taken to be time symmetric. For the mixing flow the response of the system, as reflected in its entropy as a function of time, occurs only subsequent to the friction, while for the oscillators the effects are both before and after. Some general discussion also takes up the question of which of the foregoing systems is a better model of the physical world for purposes of correlating arrows of time.Work supported in part by U.S. Army Research Office (Durham, N.C.).  相似文献   
49.
[reaction: see text] The use of a pyridinophane, a macrocycle composed of three pyridines linked, via all ortho positions through CH(2) or CH(2)CH(2) groups, bound to copper, gives good performance (rate and yield) catalyzing the conversion of substituted aliphatic olefins and PhINTs to aziridines. Advantages also derive from using CH(2)Cl(2) solvent and the weakly coordinating anions BAr(4)(-) (Ar = C(6)H(5) or 3,5-C(6)H(3)(CF(3))(2)). Reactions are complete in minutes at 20 degrees C, and yields are almost quantitative for olefins not bearing secondary allylic CH bonds; however, cis-cyclooctene gives only the aziridine despite the allylic hydrogens.  相似文献   
50.
Fused-silica capillaries chemically derivatized with silane/poly(vinylpyrrolidone) (PVP) or dynamically modified with plexiglas [poly(methyl methacrylate)] were prepared and evaluated with regard to column stability and separation performance for capillary isoelectric focusing of standard proteins. The PVP coating showed the better stability and was good for at least 100 runs while the plexiglas coating started to deteriorate after about 30 runs. The time spent for the plexiglas coating is about 40 minutes while the PVP coating requires two days. The migration time reproducibility was better with the PVP capillary (RSD 0.7-1.6%, n = 5) compared to the plexiglas-coated column (RSD 1.2-2.9%, n = 5) while peak area and height varied over a similar interval (RSD 2-28.1% area; 0.9-22.7% height, n = 5). The two most consistent proteins in this evaluation, viz. myoglobin A and carbonic anhydrase II, showed linear dynamic ranges between 5-150 and 5-50 microg/mL, and limits of detections at 2 and 1 microg/mL, respectively, employing UV detection at 280 nm.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号