全文获取类型
收费全文 | 2305篇 |
免费 | 45篇 |
国内免费 | 85篇 |
专业分类
化学 | 389篇 |
晶体学 | 7篇 |
力学 | 12篇 |
综合类 | 14篇 |
数学 | 1723篇 |
物理学 | 290篇 |
出版年
2024年 | 5篇 |
2023年 | 10篇 |
2022年 | 14篇 |
2021年 | 19篇 |
2020年 | 16篇 |
2019年 | 79篇 |
2018年 | 72篇 |
2017年 | 31篇 |
2016年 | 21篇 |
2015年 | 24篇 |
2014年 | 85篇 |
2013年 | 234篇 |
2012年 | 35篇 |
2011年 | 157篇 |
2010年 | 142篇 |
2009年 | 142篇 |
2008年 | 165篇 |
2007年 | 196篇 |
2006年 | 152篇 |
2005年 | 111篇 |
2004年 | 79篇 |
2003年 | 69篇 |
2002年 | 66篇 |
2001年 | 33篇 |
2000年 | 40篇 |
1999年 | 30篇 |
1998年 | 31篇 |
1997年 | 17篇 |
1996年 | 58篇 |
1995年 | 38篇 |
1994年 | 44篇 |
1993年 | 30篇 |
1992年 | 32篇 |
1991年 | 34篇 |
1990年 | 17篇 |
1989年 | 12篇 |
1988年 | 7篇 |
1987年 | 17篇 |
1986年 | 6篇 |
1985年 | 13篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 5篇 |
1979年 | 5篇 |
1978年 | 7篇 |
1977年 | 5篇 |
1976年 | 2篇 |
1973年 | 4篇 |
排序方式: 共有2435条查询结果,搜索用时 21 毫秒
41.
George Khelashvili Xiaolu Cheng Maria E. Falzone Milka Doktorova Alessio Accardi Harel Weinstein 《Journal of computational chemistry》2020,41(6):538-551
Recent discoveries about functional mechanisms of proteins in the TMEM16 family of phospholipid scramblases have illuminated the dual role of the membrane as both the substrate and a mechanistically responsive environment in the wide range of physiological processes and genetic disorders in which they are implicated. This is highlighted in the review of recent findings from our collaborative investigations of molecular mechanisms of TMEM16 scramblases that emerged from iterative functional, structural, and computational experimentation. In the context of this review, we present new MD simulations and trajectory analyses motivated by the fact that new structural information about the TMEM16 scramblases is emerging from cryo-EM determinations in lipid nanodiscs. Because the functional environment of these proteins in in vivo and in in vitro is closer to flat membranes, we studied comparatively the responses of the membrane to the TMEM16 proteins in flat membranes and nanodiscs. We find that bilayer shapes in the nanodiscs are very different from those observed in the flat membrane systems, but the function-related slanting of the membrane observed at the nhTMEM16 boundary with the protein is similar in the nanodiscs and in the flat bilayers. This changes, however, in the bilayer composed of longer-tail lipids, which is thicker near the phospholipid translocation pathway, which may reflect an enhanced tendency of the long tails to penetrate the pathway and create, as shown previously, a nonconductive environment. These findings support the correspondence between the mechanistic involvement of the lipid environment in the flat membranes, and the nanodiscs. © 2019 Wiley Periodicals, Inc. 相似文献
42.
采用傅里叶变换红外光谱仪记录了富含15N216O同位素的一氧化二氮样品在1650-3450 cm-1波段的高分辨振转光谱,得到了该同位素分子超过7300吸收谱线位置的实验值,经分析实验精确度好于5.0×10-4 cm-1. 基于有效哈密顿量模型预测和带带转动分析,确定了所有吸收线的归属;获得了29个新吸收带的振转光谱参数,并优化了其他44个吸收带的光谱参数值. 并且发现有效哈 相似文献
43.
44.
For representations of tame quivers the degenerations are controlled by the dimensions of various homomorphism spaces. Furthermore, there is no proper degeneration to an indecomposable. Therefore, up to common direct summands, any minimal degeneration from M to N is induced by a short exact sequence 0→U→M→V→0 with indecomposable ends that add up to N. We study these ‘building blocs’ of degenerations and we prove that the codimensions are bounded by two. Therefore, a quiver is Dynkin resp. Euclidean resp. wild iff the codimension of the building blocs is one resp. bounded by two resp. unbounded. We explain also that for tame quivers the complete classification of all the building blocs is a finite problem that can be solved with the help of a computer. 相似文献
45.
46.
David Dol?an 《Linear algebra and its applications》2011,435(7):1657-1665
We calculate diameters and girths of commuting graphs of the set of all nilpotent matrices over a semiring, the group of all invertible matrices over a semiring, and the full matrix semiring. 相似文献
47.
Yaroslav Shitov 《Linear algebra and its applications》2011,435(7):1769-1777
The rank-sum, rank-product, and rank-union inequalities for Gondran-Minoux rank of matrices over idempotent semirings are considered. We prove these inequalities for matrices over quasi-selective semirings without zero divisors, which include matrices over the max-plus semiring. Moreover, it is shown that the inequalities provide the linear algebraic characterization for the class of quasi-selective semirings. Namely, it is proven that the inequalities hold for matrices over an idempotent semiring S without zero divisors if and only if S is quasi-selective. For any idempotent semiring which is not quasi-selective it is shown that the rank-sum, rank-product, and rank-union inequalities do not hold in general. Also, we provide an example of a selective semiring with zero divisors such that the rank-sum, rank-product, and rank-union inequalities do not hold in general. 相似文献
48.
The existence of multiple positive solutions of systems of singular Hammerstein integral equations is studied, where the nonlinearities involved are allowed to have singularities in their second variables and satisfy weaker conditions involving the first eigenvalues of the corresponding linear Hammerstein integral operators. Such systems contain some mathematical models arising in science and engineering. Applications are given to the existence of multiple positive radial solutions of systems of semilinear singular elliptic equations in annuli on which, to the best of our knowledge, there has been little study. 相似文献
49.
The absorption spectrum of the 16O3 isotopologue of ozone has been recorded in the 7000-7920 cm−1 region by high sensitivity CW-Cavity Ring Down Spectroscopy. This report is devoted to the analyses of the 7065-7300 cm−1 region dominated by the ν1 + 2ν2 + 5ν3 and ν1 + 5ν2 + 3ν3 A-type bands at 7130.8 and 7286.8 cm−1 respectively. 289 transitions were assigned to the ν1 + 2ν2 + 5ν3 band. The corresponding line positions were modeled with an effective Hamiltonian involving Coriolis resonance interactions between the (1 2 5) upper state and the (4 4 0), (0 2 6) and (6 1 0) dark states, and an anharmonic resonance interaction with the (2 0 5) state. The very strong interaction (up to 50% mixing of the wavefunctions) between the (1 2 5) and (6 1 0) states leads to the observation of two extra lines of the 6ν1 + ν2 band due to a resonance intensity transfer. 213 transitions of the ν1 + 5ν2 + 3ν3 band were assigned and modeled taking into account a Coriolis resonance interaction with the (3 6 0) state.We take the opportunity of the present work to report the analysis of the very weak 4ν2 + 4ν3 B-type band at 6506.1 cm−1 which was assigned from previously recorded CRDS spectra. 286 transitions were modeled using the effective Hamiltonian approach.The dipole transition moment parameters of the three analyzed bands were determined by a least-squares fit to the measured line intensities. For the three studied band systems, the effective Hamiltonian and transition moment operator parameters were used to generate line lists provided as Supplementary Materials. 相似文献
50.
A Lie group is called quadratic if it carries a bi-invariant semi-Riemannian metric. Oscillator Lie groups constitute a subclass of the class of quadratic Lie groups. In this paper, we determine the Lie bialgebra structures and the solutions of the classical Yang–Baxter equation on a generic class of oscillator Lie algebras. Moreover, we show that any solution of the generalized classical Yang–Baxter equation (resp. classical Yang–Baxter equation) on a quadratic Lie group determines a left invariant locally symmetric (resp. flat) semi-Riemannian metric on the corresponding dual Lie groups. 相似文献