农科有机化学课程建设的探索与实践

对农科有机化学课程存在的一些普遍问题进行了分析;结合当前农林院校的特点,建立了符合农业院校特点的教学新体系;编制了一系列教材;建设了精品课程网站;建立了教学质量评价体系;建设了一支结构合理、教学水平高、团队精神好的教学队伍。     

正构烷烃在Pt/SAPO-11催化剂上的临氢异构化反应历程

 通过比较正庚烷(n-C7)与正十四烷(n-C14)的临氢异构化反应,探讨了正构烷烃在0.4%Pt/SAPO-11催化剂上临氢异构化的反应历程. 在低转化率下即产生裂解产物的实验结果支持质子环丙烷(PCP)作用机理,提出了在一次反应中就生成裂解产物的观点. 通过分析n-C7与n-C14临氢异构产物的分布,认为异构化过程主要发生在分子筛孔道内. 根据n-C7与n-C14呈现相同的反应规律,将加氢转化过程中链长超过C10的烷烃的正碳离子反应的相对速率与链长无关的观点扩展到C7,并在传统反应历程的基础上提出了修正的烷烃异构化反应历程.     

马尾松经营图的编制和应用

马尾松是豫南主要树种,它分布面积广、更新容易、生长迅速,综合利用价值大,而且耐干早瘠薄,适应性强,并能与多种树种混交。为科学地经营与管理马尾松林、提高林分生产力,就必须研究解决抚育间伐的起始期、强度、间隔期等。为此我们针对信阳地区的马尾松生长实际情况,研制了马尾松经营图。一、经营图的编制首先在马尾松集中产区依不同树令和不同生长条件,设标准地117块,逐棵测定各令阶树高、胸径、年令、材积,计算了每亩株数、蓄积等.然后对所得资料进行整     

双奇核136La的集体带结构

通过重离子核反应与在束γ谱的实验技术, 对A=130缺中子核区的双奇核¹³⁶La的高自旋态进行了研究, 所用核反应为¹³⁰Te(¹¹B,5n). 实验结果扩展了¹³⁶La的能级纲图, 包括3个集体转动带, 最高自旋态达20h. 对于\uppi h_{11/2}\otimes \upnu h_{11/2}$~带, 观测到了旋称反转与集体回弯现象. 通过系统学比较, 对旋称反转特性进行了讨论. 由推转壳模型的计算指出, 此集体回弯是由一对中子的角动量顺排引起的. 另外两个集体带为具有~$\gamma\approx -60^\circ$~的扁椭形变带, 其可能的组态为: $\uppi h_{11/2}\otimes \upnu g_{7/2}h_{11/2}^2$~与~$\uppi g_{7/2}\otimes\upnu g_{7/2}^2 d_{5/2} h_{11/2}^2$.     

A Numerical Study of Vortex and Precipitating Cloud Merging in Middle Latitudes

We mainly focus on the study of precipitating cloud merging associated with vortex merging. The vortex and precipitating cloud merging are simulated by the cloud resolving model from 0000 21 to 1800 23 July 2003. The results show that the model well simulates vortex circulation associated with precipitating clouds. It is also proven that the vortex merging follows the precipitating cloud merging although vortices show the spatial and temporal differences. The convection vorticity vector is introduced to describe the merging processes. Two merging cases are identified during the 42-h simulation and are studied.     

Lifetimes of Excited Levels in ^131Ce

The fusion-evaporation reaction ^116Sn (^19F, p3n)^131 Ce at projectile energy of 95 MeV is used to populate high spin states in ^131Ce. The de-exciting γ-rays are detected in γ-γ coincidence measurement with Compton-suppressed BGO-HPGe detectors. Level lifetimes of ^131 Ce were determined by using the Doppler shift attenuation method.The experimental results indicate that collectivity of ^131 Ce is reduced relative to that of ^130Ce and it follows that deformation decreases with increase of the neutron number on the basis of systematic comparison of transition quadrupole moments for the light cerium isotopes.     

156Tm核的高自旋态实验研究

利用122.5MeV的¹⁹F束流, 通过¹⁴²Nd(¹⁹F,5n)¹⁵⁶Tm熔合蒸发反应布居了¹⁵⁶Tm核的高自旋态, 测量了γ-γ符合及DCO比值, 建立了一个有29条能级, 33条γ跃迁的能级纲图. 新增加了20条γ跃迁, 18条能级. 将能级自旋推高到(34^－).     

171Ta高自旋态能级寿命测量

在中国原子能科学研究院的HI 13串列加速器上通过157Gd(19F,5n)171Ta重离子熔合蒸发反应布居了171Ta的高自旋态,以多普勒移动衰减法的峰形分析法分析了171Tah9/2质子1/2[541]转动带的6条能级的寿命,得到了这6条能级的平均寿命值. The high spin states of~(171)Ta have been populated via heavy ion fusion evaporation reaction~(157)Gd(~(19)F, 5n)~(171)Ta at the HI-13 tandem accelerator in China Institute of Atomic Energy. The lifetimes of the high spin states in~(171)Ta have been measured by using the Doppler Shift Attenuation Method (DSAM). Six levels of its h_(9/2) proton 1/2\ band have been analyzed and their lifetimes have been deduced from the experimental data.     

Nitrogen Adatom Diffusion on a Ga－Rich GaN （0001） Surface

The diffusion of N adatoms on a Ga-rich GaN(O001) surface has been studied using density-functional theory.The configuration of Ga adatoms on a Ga-rich GaN surface has been identified. The first adlayer Ga adatoms are on top of the terminating substrate Ga atoms, and the outmost adlayer Ga adatoms exist randomly at the T4 or H3 sites. A very different diffusivity of N adatoms on a Ga-rich GaN(0001) surface has been found. The excess Ga adatoms on a GaN(0001) surface reduce the diffusion barrier by 0.75eV and influence the migration path. It seems that bilayer Ga adatoms are helpful for N atom diffusion.     

利用LNG冷(火用)的准零CO2排放循环探析

本文研究利用LNG冷(火用)来完善燃用它的热机性能,既提高了效率,又能回收用LNG燃料热机的唯一主要排放-CO2.这种系统的温度区间横跨大气温度,会有很多新的特点值得探索.作为前期研究,本文建议了两种新循环,分别基于Brayton循环与超临界Rankine循环,且分别适用于LNG超临界及亚临界汽化过程.文中对此两种循环进行了分析计算与讨论,说明建议是可行的,热机效率可达60%以上,且同时基本回收所有燃烧产生的CO2.