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A series of 1-naphthanilides (1) and 2-naphthanilides (2) with varied substituents at the para- or meta-position of anilino phenyl ring were prepared and their absorption and fluorescence spectra in a nonpolar solvent cyclohexane were investigated. An abnormal long wavelength emission assigned to the charge transfer (CT) state was found for all of the prepared naphthanilides in cyclohexane. A linear free energy correlation between the CT emission energies and the Hammett constants of the substituent was found within series 1 and 2. The value of the linear slope with 1 (0.42 eV) was higher than that with 2 (0.32 eV) being close to that of the substituted benzanilides 3 (0.31 eV) The higher slope value suggested higher charge separation extent in the CT state of 1 than that of 2. It was found that the corresponding linear slope of anilino-substituted benzanilides remained unchanged when para-, meta-, ortho-, or ortho, ortho-methyls were introduced into the anilino moiety, which ruled out the possible contribution of the difference in the steric effect and the electron accepting ability of the naphthoyl acceptor in 1 and 2. Compared with the early reported N-substituted-benzoyl-aminonaphthalene derivatives 4 and 5, it was considered that 1-naphthoyl enhanced the charge transfer in 1 and the proximity of its ^1La and ^1Lb states was suggested to be responsible. It was shown that 1- and/or 2-substituted naphthalene cores acting as either electron acceptor (naphthoyl) or electron donor (aminonaphthalene) were different in not only electron accepting (donating) ability but also shaping the charge transfer pathway. 相似文献
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利用计算机视觉技术,对HL-2A偏滤器放电X点进行了识别研究。首先根据HL-2A偏滤器放电图的分析需求,基于直观的等离子体标准下单零放电位形下的边缘可见光辐射模型建立了Canny边缘检测的处理模型,主要对图像中等离子体边缘进行了预处理。结合Harris角点检测的算法,在提取出图像特征点后,利用多边形逼近的方式确定了特征点在图像中的坐标值。分别拟合出强、弱场侧的等离子体边界曲线及其渐近线,渐近线交点近似为X点,边界曲线向中心逼近所包围的区域可近似为X点存在区域。通过实际的HL-2A装置第37638次放电偏滤器放电图验证,经过简化条件后,拟合出的X点与EFIT反演对比误差范围在3cm以内。 相似文献
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The nonradiative charge-transfer cross sections for protons colliding with Rb(5s) atoms are calculated by using the quantum-mechanical molecularorbital close-coupling method in an energy range of 10 3 keV-10 keV.The total and state-selective charge-transfer cross sections are in good agreement with the experimental data in the relatively low energy region.The importance of rotational coupling for chargetransfer process is stressed.Compared with the radiative charge-transfer process,nonradiative charge transfer is a dominant mechanism at energies above 15 eV.The resonance structures of state-selective charge-transfer cross sections arising from the competition among channels are analysed in detail.The radiative and nonradiative charge-transfer rate coefficients from low to high temperature are presented. 相似文献
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非相干激光汤姆逊散射诊断只需要假设电子速度满足Maxwell分布,测量得到的等离子体电子温度与电子密度的数据准确可靠,是托卡马克和其他磁约束核聚变研究装置上重要的诊断工具,并朝着高可靠性、高空间分辨和高重复测量频率的方向发展,其中高可靠性是前提。电子的汤姆逊散射截面很小,其总截面为σT=6.65×10-25 cm2,通常使用电光调Q的 Nd∶YAG激光器作为散射光源,激光脉冲宽度约10 ns、脉冲能量约3 J,用5~8通道的光谱仪对散射光谱进行测量与分析。如何对光电探测模块输出的散射脉冲进行数据采集,是激光散射诊断的关键问题之一。以前使用电流积分式的数据采集器(Q-ADCs,如CMC080模块),在一个确定的时间宽度(如50 ns)将散射脉冲信号积分在采样电容器上,从而得到散射信号的强度值,这种方法很难排除电路噪声和外来干扰。该研究通过使用高速数据采集器(纵向分辨率≥10 bits、采样频率f≥1 GS·s-1,如V1742B模块)在包含散射信号在内的时间段(如300~500 ns)进行采集,获得散射脉冲信号、等离子体发光的扰动与背景噪声等叠加在一起的数据序列。利用最小二乘法,用高斯函数对散射脉冲的波形进行拟合,然后在50 ns时间宽度对散射波形脉冲进行数值积分,就得到散射信号的强度值。结果表明,高速同步采集技术的使用,能够用数字滤波技术排除大部分的干扰,从而提高信噪比,其幅度可以达到10倍左右。提取到更加准确可靠的光谱数据后,以置信水平95%、误差权重的最小二乘法开展数据处理,用A.C. Selden散射谱表达式对电子温度进行参数估计,得到了电子温度的测量值,其统计误差为3%左右,优于以前的10%左右。 相似文献
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强激光非线性条件下分子的多光子电离过程呈现出较为明显的强场效应.由于这种效应不能用传统的量子微扰论来处理。“缀饰态”模型方法提供了物理图象清晰的处理光与物质相互作用的方案.本文基于含时波包动力学的基本理论,将激光场看作经典场,利用“缀饰态”模型研究了强场下双原子分子(NO、RbI等)的多光子电离过程.研究表明,激光场的强度、泵浦-探测脉冲延迟时间等对多光子电离光电子能谱的形状有着重要的影响。而这种影响是由光诱导势引起的.另外,在研究具有两个连续态的Rbl体系时,自电离现象的发生也与势能面的交叉密切相关,并受外场强度的影响.本文计算模拟外场中分子的光电子能谱时所得到的强场效应对理解和实现原子分子过程的激光搛控具有重要的意义. 相似文献
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建立了超高效液相色谱-串联质谱法(UPLC-MS/MS)同时检测莲雾中氯吡脲等16种植物生长调节剂。莲雾样品经改进的QuEChERS方法进行前处理,UPLCMS/MS法测定。氯吡脲等16种植物生长调节剂的质量浓度在5.0~500.0ng/mL范围内线性良好,相关系数均大于0.9,检出限在0.10~1.50μg/kg之间,平均加标回收率在71.0%~124%之间,相对标准偏差在0.6%~11.2%之间。该方法具有简便、快速、准确度高、成本较固相小柱萃取低廉等优点,可用于莲雾中氯吡脲等16种植物生长调节剂的检测。 相似文献
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本论文研究了原子转移自由基聚合法(ATRP)在纳米二氧化硅(SiO2)表面接枝聚丙烯酸丁酯(PBA)以及其对聚甲醛(POM)进行改性。红外光谱(FTIR)、透射电镜(TEM)及凝胶渗透色谱(GPC)等测试表明:采用ATRP法可制备均匀分散的SiO2-g-PBA纳米复合粒子。力学性能、扫描电子显微镜(SEM)及透射电子显微镜(TEM)等测试表明:纳米SiO2在POM中团聚明显,而SiO2-g-PBA纳米复合粒子POM中分散均匀,导致POM/SiO2-g-PBA纳米复合材料的缺口冲击强度明显高于POM及POM/SiO复合材料,当SiO2-g-PBA纳米复合粒子的质量分数为2%时,POM/SiO2-g-PBA复合材料的冲击强度是POM的8倍多,同时拉伸强度有一定的增加。 相似文献
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