全文获取类型
收费全文 | 239篇 |
免费 | 9篇 |
国内免费 | 14篇 |
专业分类
化学 | 177篇 |
力学 | 32篇 |
综合类 | 15篇 |
数学 | 7篇 |
物理学 | 31篇 |
出版年
2022年 | 2篇 |
2021年 | 13篇 |
2020年 | 7篇 |
2019年 | 6篇 |
2018年 | 4篇 |
2017年 | 11篇 |
2016年 | 7篇 |
2015年 | 4篇 |
2014年 | 6篇 |
2013年 | 18篇 |
2012年 | 7篇 |
2011年 | 8篇 |
2010年 | 7篇 |
2009年 | 12篇 |
2008年 | 14篇 |
2007年 | 11篇 |
2006年 | 15篇 |
2005年 | 10篇 |
2004年 | 13篇 |
2003年 | 10篇 |
2002年 | 7篇 |
2001年 | 13篇 |
2000年 | 15篇 |
1999年 | 3篇 |
1998年 | 6篇 |
1997年 | 2篇 |
1996年 | 6篇 |
1995年 | 5篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 7篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1984年 | 1篇 |
1980年 | 1篇 |
排序方式: 共有262条查询结果,搜索用时 15 毫秒
31.
This research provides a fundamental understanding of the early stage hydration of Portland cement paste, tricalcium aluminate
(C3A) paste at water to cement ratio of 0.5 and C3A suspension at water to cement ratio of 5.0 modified by 2 or 4 mass% of sodium carbonate. A high conversion of unreacted
clinker minerals to gel-like hydration products in the cement-Na2CO3 pastes takes place rapidly between 1st to 24th h. Contrary the Ca(OH)2 formation within the same time interval is retarded in the excess of CO32− ions due to intensive rise and growth of CaCO3 crystals in hydrated cement. Later, the conversion of clinker minerals to the hydrate phase is reduced and higher contents
of calcite and vaterite relative to that of Ca(OH)2 in comparison with those found in the Portland cement paste are observed. As a consequence a decrease in strength and an
increase in porosity between hardened Portland cement paste without sodium carbonate and those modified by Na2CO3 are observed. C3A hydrates very quickly with sodium carbonate between 1st and 24th h forming hydration products rich in bound water and characterized also by complex salts of (x)C3A·(y)CO2·(zH2O type, whereas C3A-H2O system offers C3AH6 as the main hydration product. Higher content of the formed calcium aluminate hydrates in C3A-Na2CO3-H2O system also contributes to early strength increase of Portland cement paste. 相似文献
32.
Sulphate resistance and passivation ability of the mortar made from pozzolan cement with zeolite 总被引:1,自引:0,他引:1
Sulphate resistance and passivation ability of the mortars made from pozzolan cement of CEM IV/A (P) type according to European
Standard EN 197-1 (zeolite blended cement with 60.82 mass% of PC clinker, 35.09 mass% of zeolite and 4.09 mass% of gypsum
abbreviated as ZBC) and ordinary Portland cement (abbreviated as PC) are introduced. Resistance tests were performed in water
and 5% sodium sulphate solution (both 20°C) for 720 days. The increased sulphate resistance of pozzolan cement relative to
that of PC was found. The key quantitative insight into the hydrate phase behaviour is given by thermal analysis. This is
due to pozzolanic reaction of zeolite with PC resulting in reduction of the formed Ca(OH)2 opposite to the reference PC. Ability of pozzolan cements with 15 to 50 mass% of zeolite to protect steel against corrosion
was verified in 20°C/85% RH-wet air within 180-day cure. Steel was not corroded in the mortars made with pozzolan cement containing
up to 35 mass% of zeolite. Pozzolan cement of CEM IV/A (P) type containing 35 mass% of zeolite is a suitable cementitious
material for concrete structures exposed to sulphate attack. Steel is protected against corrosion by this pozzolan cement
in the same measure as the reference PC. 相似文献
33.
G. Baert S. Hoste G. De Schutter N. De Belie 《Journal of Thermal Analysis and Calorimetry》2008,94(2):485-492
Four paste mixtures with varying replacement level of the cement content by fly ash have been studied. Due to fly ash, the
acceleration period decreased and a third hydration peak was noticed with isothermal calorimetry. The total heat after 7 days
increased with increasing fly ash content. From 1 to 7 days, thermogravimetry showed a higher chemically bound water and Ca(OH)2-content for the pastes with fly ash. Between 7 and 14 days the calcium hydroxide started to be depleted due to the pozzolanic
reaction. A unique relation was found between calcium hydroxide and total heat development. 相似文献
34.
35.
轻质水泥在油田固井中的广泛应用使得传统测井方式无法有效的对固井水泥胶结质量做出评价。为了研究新的可行的评价方法,本文采用传递矩阵方法对套管中传播的弯曲型Lamb波进行建模,并通过对所建模型进行数值计算研究了套管外水泥等介质的声学参数变化对弯曲型Lamb波衰减率的影响。数值计算的结果表明,弯曲型Lamb波的衰减率与水泥的声学参数以及水泥与套管的胶结状况有较强相关性,据此可对水泥与套管胶结状况进行评价。本文的计算结果与分析对弯曲型Lamb波在水泥胶结评价中的应用具有一定的参考意义。 相似文献
36.
沈定珍 《宁波大学学报(理工版)》2006,19(3):346-349
软土地基中的支护是基础工程的关键,在节约成本的前提下,选择合理的支护结构至关重要.通过对某公司将要开发的2个基坑支护方案的项目进行的相关分析、计算和探讨,总结出了软土地基中的基坑支护方案的选择原则及其相对应的施工措施等. 相似文献
37.
Ibrahim I. A. ElSersy H. H. Abadir M. F. 《Journal of Thermal Analysis and Calorimetry》2004,76(3):713-718
Thermal analysis was first used to investigate the pattern of dissociation of hydrated ordinary Portland cement. Portlandite
(Ca(OH)2) decomposes at about 500°C. This was confirmed by kinetic calculations. Thermal analysis was then performed to establish
the effect of varying the cement content on the percent mass loss associated with the decomposition of Ca(OH)2 in cement mortar cured for 28 days. An increasing relation was obtained. Standard concrete cubes were then prepared with
cement contents ranging from 200 to 450 kg m-3. The loss in mass on heating, up to 750°C, of concrete samples cured for 28 days was then related to the cement content in
concrete. The relation obtained was tested for concrete cubes of known cement content and found to be in better agreement
than the results obtained by conventional chemical analysis. This method can be used for an approximate determination of the
cement content in concrete.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
38.
The majority of previous studies of the hydration of cements using heat flow calorimetry have been carried out isothermally. However, with oilwell cements the slurry is mixed on the surface at ambient temperature and then gradually increases in temperature as it is pumped down the well. A Setaram C-80 calorimeter has been used to simulate the temperature ramp in API oilwell cement test schedules. This approach has enabled cementing reactions to be studied for the first time under conditions approaching those encountered in the field, and has shown that the results obtained from isothermal experiments may be misleading.The permission of the British Petroleum Company PLC to publish this paper is gratefully acknowledged. 相似文献
39.
40.
A mathematical model is presented for the determination of optimal mix of asbestos fibres to satisfy a set of desired pipe properties which vary with pipe size, class, and material availability. The approach utilizes a linear/separable programming model which is aimed at minimizing the total cost of fibres used. The fibre properties, such as reinforcing strength, processability, and length as well as cost and stocks available are taken into account in the model. Also represented are the profile of the ideal mix relative to the required composite strength, processability, and ‘dust content’. Asbestos mixes designed using the model have been implemented in the production of asbestos/cement pipes in one of the asbestos/cement pipe manufacturing plants in the Gulf area. Optimum model mixes have demonstrated significant technical and economic merits over the conventionally designed mixes. 相似文献