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Reactivity of fly ash in cement paste studied by means of thermogravimetry and isothermal calorimetry
Authors:G Baert  S Hoste  G De Schutter  N De Belie
Institution:(1) Magnel Laboratory for Concrete Research, Ghent University, Ghent, Belgium;(2) Laboratory for Inorganic and Physical Chemistry, Ghent University, Ghent, Belgium
Abstract:Four paste mixtures with varying replacement level of the cement content by fly ash have been studied. Due to fly ash, the acceleration period decreased and a third hydration peak was noticed with isothermal calorimetry. The total heat after 7 days increased with increasing fly ash content. From 1 to 7 days, thermogravimetry showed a higher chemically bound water and Ca(OH)2-content for the pastes with fly ash. Between 7 and 14 days the calcium hydroxide started to be depleted due to the pozzolanic reaction. A unique relation was found between calcium hydroxide and total heat development.
Keywords:cement hydration  fly ash cement paste  pozzolanic reaction
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