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31.
N-(5-三氟甲基-1,3,4-噻二唑-2-基)-N''-芳酰基脲的合成、晶体结构及生物活性 总被引:4,自引:3,他引:4
通过2-氨基-5-三氟甲基-1,3,4-噻二唑与芳酰基异氰酸酯反应,合成了10种新的芳酰基脲.它们的结构经元素分析、红外光谱、核磁共振氢谱进行了表征.并用X射线单晶衍射法测定了化合物2j的晶体结构,结果表明,该化合物晶体属三斜晶系,空间群为P-1,a=0.54191(15)nm,b=0.7766(2)nm,c=1.7161(5)nm,α=98.668(5)°,β=95.103(5)°,γ=101.070(5)°,V=0.6955(3)nm3,Z=2,Dc=1.653g/cm3,F(000)=352,μ=0.289mm-1.初步的生测试验结果表明一些目标化合物具有良好的植物生长调节活性. 相似文献
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We apply the generalization of the Parikh–Wilczek method to the tunneling of massive particles from noncommutative inspired
Schwarzschild black holes. By deriving the equation of radial motion of the tunneling particle directly, we calculate the
emission rate which is shown to be dependent on the noncommutative parameter besides the energy and mass of the tunneling
particle. After equating the emission rate to the Boltzmann factor, we obtain the modified Hawking temperature which relates
to the noncommutativity and recovers the standard Hawking temperature in the commutative limit. We also discuss the entropy
of the noncommutative inspired Schwarzschild black hole and its difference after and before a massive particle’s emission. 相似文献
34.
Huo SJ Xue XK Yan YG Li QX Ma M Cai WB Xu QJ Osawa M 《The journal of physical chemistry. B》2006,110(9):4162-4169
Surface-enhanced infrared absorption spectroscopy (SEIRAS) in the attenuated-total-reflection configuration (ATR-SEIRAS) has been applied for the first time to Ni electrodes. SEIRA-active Ni electrodes were obtained through initial chemical deposition of a 60-nm-thick Au underlayer on the reflecting plane of an ATR Si prism followed by potentiostatic electrodeposition of a 40-nm-thick Ni overlayer in a modified Watt's electrolyte. The Ni nanoparticle film thus obtained exhibited exceptionally enhanced IR absorption for the surface probe molecule CO while maintaining unipolar and normally directed bands. With the advantages of ATR-SEIRAS, free H2O molecules coadsorbed with CO at the Ni electrode were revealed, and their role in the electrooxidation of the CO adlayer at the Ni electrode is discussed. In addition, the conversion of bridge to linearly bonded CO at Ni electrode in a neutral solution was clearly identified upon electrooxidation of the CO adlayer. ATR-SEIRAS was also used to characterize the adsorption configuration of a pyridine adlayer at the Ni electrode. Both A1 and B1 modes of adsorbed pyridine were detected with comparably large intensities, essentially maintaining the spectral feature of pyridine molecules rather than that of "alpha-pyridyl species", which strongly suggests an "edge-tilted pyridine" configuration present at the Ni electrode, a configuration intermediate between the "end-on pyridine" and "edge-on alpha-pyridyl" adsorption modes reported in the literature. 相似文献
35.
The conduction mechanism of stress induced leakage current through ultra-thin gate oxide under constant voltage stresses 总被引:1,自引:0,他引:1 下载免费PDF全文
The conduction mechanism of stress induced leakage current (SILC) through 2nm gate oxide is studied over a gate voltage range between 1.7V and stress voltage under constant voltage stress (CVS). The simulation results show that the SILC is formed by trap-assisted tunnelling (TAT) process which is dominated by oxide traps induced by high field stresses. Their energy levels obtained by this work are approximately 1.9eV from the oxide conduction band, and the traps are believed to be the oxygen-related donor-like defects induced by high field stresses. The dependence of the trap density on stress time and oxide electric field is also investigated. 相似文献
36.
We investigate the kinetics of a nonrelativistic particle interacting with a constant external force on a Lie-algebraic noncommutative space. The structure constants of a Lie algebra, also called noncommutative parameters, are constrained in general due to some algebraic properties, such as the antisymmetry and Jacobi identity. Through solving the constraint equations the structure constants satisfy, we obtain two new sorts of algebraic structures, each of which corresponds to one type of noncommutative spaces. Based on such types of noncommutative spaces as the starting point, we analyze the classical motion of the particle interacting with a constant external force by means of the Hamiltonian formalism on a Poisson manifold. Our results not only include that of a recent work as our special cases, but also provide new trajectories of motion governed mainly by marvelous extra forces. The extra forces with the unimaginable -, and -dependence besides with the usual t-, x-, and -dependence, originating from a variety of noncommutativity between different spatial coordinates and between spatial coordinates and momenta as well, deform greatly the particle’s ordinary trajectories we are quite familiar with on the Euclidean (commutative) space. 相似文献
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Yan-Gang Miao H. J. W. M��ller-Kirsten Jian-Ge Zhou 《The European Physical Journal C - Particles and Fields》2011,71(1):525-531
The gauge invariant theories of the generalized chiral Schwinger model are constructed in terms of two schemes with and without Wess-Zumino terms, respectively. Following the former scheme, we calculate the Wess-Zumino term which cancels the gauge anomaly, and then constitute the gauge invariant theory by adding the Wess-Zumino term to the original Lagrangian of the model. According to the latter, we modify the original Hamiltonian by adding a term composed of constraints of the model. It is so designed that the theory described by the modified Hamiltonian and its corresponding first-order Lagrangian maintains gauge invariance. We show by the canonical Dirac method that each of the two gauge invariant theories has the same physical spectrum as that of the original gauge noninvariant formulation. 相似文献
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The microscopic structure of black holes remains a challenging subject. In this paper, based on the well-accepted fact that black holes can be mapped to thermodynamic systems, we make a preliminary exploration of the microscopic structure of the thermodynamically stable Schwarzschild anti-de-Sitter(SAdS) black hole. In accordance with the number density and thermodynamic scalar curvature, we give the interaction potential among the molecules of thermodynamically stable SAdS black holes and analyze its effectiveness. Moreover, we derive the thermo-correction to the equation of state for such black holes that arises from interactions among black-hole molecules using virial coefficients. 相似文献
40.
Two non-Hermitian PT-symmetric Hamiltonian systems are reconsidered by means of the algebraic method which was originally proposed for the pseudo-Hermitian Hamiltonian systems rather than for the PT-symmetric ones.Compared with the way converting a non-Hermitian Hamiltonian to its Hermitian counterpart,this method has the merit that keeps the Hilbert space of the non-Hermitian PT-symmetric Hamiltonian unchanged.In order to give the positive definite inner product for the PT-symmetric systems,a new operator V,instead of C,can be introduced.The operator V has the similar function to the operator C adopted normally in the PT-symmetric quantum mechanics,however,it can be constructed,as an advantage,directly in terms of Hamiltonians.The spectra of the two non-Hermitian PT-symmetric systems are obtained,which coincide with that given in literature,and in particular,the Hilbert spaces associated with positive definite inner products are worked out. 相似文献