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31.
The cycloaddition reactions of NH to different bonds on C70 have been studied by the first-principles calculations.The results indicate that the reactivity of cycloaddition reactions is determined by the directional curvature,KD,and the larger binding energy of Eb on the bond C5-C'5 can be ascribed to the unique bond which can be treated as the shortest bond of(5.5)-SWCNT in the four [6,6] ring fusion bonds.This work also discloses that the energy gap of different spin states is decided by the electronic density,and that of the frontier obitals for the bond C5-C'5 is larger than the value for the C4-C'4 bond.Furthermore,the transition state investigation of the two bond addition reactions provides a reaction barrier of 11.10 kcal/mol for the NH cycloaddition to the C5-C'5 bond;whereas,the addition reaction on C4-C'4 is a spontaneous pathway.Herein,the dynamics effect illustrates the [2+1] cycloaddition reaction on the equatorial C5-C'5 bond to be unfavorable. 相似文献
32.
基于菱形编码和修改量化表的DCT域图像隐写 总被引:1,自引:0,他引:1
为了提高离散余弦变换(DCT)域隐写的嵌入容量,提出一种基于菱形编码和修改量化表的DCT域图像隐写.首先将载体图像进行8×8的DCT变换后,对变换得到的DCT系数采用修改的8×8量化表进行量化,从而提高了嵌入容量和载密图像的视觉质量.同时通过改进的菱形编码将8进制的秘密信息嵌入到载体图像量化DCT系数的中频部分,从而进一步提高了嵌入容量.实验结果表明:该隐写算法不但与JPEG压缩标准兼容,而且有效地提高了嵌入容量. 相似文献
33.
提出一种基于支持向量机(SVM)及遗传算法(GA)的集成电路版图光刻热点检测方法.首先对版图样本进行离散余弦变换(DCT)以提取样本的频域特征,然后基于这些样本训练SVM分类器以实现对光刻热点的检测.为了提高光刻热点检测的精度及效率,采用遗传算法(GA)对频域特征进行选择,并同时优化SVM参数.实验结果表明,基于SVM及版图频域特征并结合遗传算法进行优化的光刻热点检测方法可以有效提高版图光刻热点的检测精度. 相似文献
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