Accurate and straightforward symplectic approach for fracture analysis of fractional viscoelastic media

An accurate and straightforward symplectic method is presented for the fracture analysis of fractional two-dimensional(2D) viscoelastic media. The fractional Kelvin-Zener constitutive model is used to describe the time-dependent behavior of viscoelastic materials. Within the framework of symplectic elasticity, the governing equations in the Hamiltonian form for the frequency domain(s-domain) can be directly and rigorously calculated. In the s-domain, the analytical solutions of the displacement ...     

Enzyme-free and multiplexed microRNA detection using microRNA-initiated DNA molecular motor

In this work, we have developed a sensitive, simple, and enzyme-free assay for detection of microRNAs (miRNAs) by means of a DNA molecular motor consisting of two stem-loop DNAs with identical stems and complementary loop domains. In the presence of miRNA target, it can hybridize with one of the stem-loop DNA to open the stem and to produce a miRNA/DNA hybrid and a single strand (ss) DNA, the ssDNA will in turn hybridize with another stem-loop DNA and finally form a double strand (ds) DNA to release the miRNA. One of the stem-loop DNA is double-labeled by a fluorophore/quencher pair with efficiently quenched fluorescence. The formation of dsDNA can produced specific fluorescence signal for miRNA detection. The released miRNA will continuously initiate the next hybridization of the two stem-loop DNAs to form a cycle-running DNA molecular motor, which results in great fluorescence amplification. With the efficient signal amplification, as low as 1 pmol/L miRNA target can be detected and a wide dynamic range from 1 pmol/L to 2 nmol/L is also obtained. Moreover, by designing different stem-loop DNAs specific to different miRNA targets and labeling them with different fluorophores, multiplexed miRNAs can be simultaneously detected in one-tube reaction with the synchronous fluorescence spectrum (SFS) technique.     

Efficient fluorescence resonance energy transfer between upconversion nanophosphors and graphene oxide: a highly sensitive biosensing platform

Graphene oxide can act as an ultrahighly efficient quencher for upconversion nanophosphors and thus, an extraordinarily sensitive biosensing platform is constructed.     

The pyrolysis of cigarette paper under the conditions that simulate cigarette smouldering and puffing

The combustion properties and pyrolysis behavior of cigarette paper under the pyrolysis conditions of cigarette smouldering were investigated by micro-scale combustion calorimetry (MCC), thermogravimetric analysis coupled to Fourier transform infrared spectrometer (TG-FTIR), respectively. MCC results demonstrated that the combustion and pyrolysis behavior are influenced by heating rate obviously. TG-FTIR results illustrated that the composition of the gaseous products were mainly composed of CO₂, H₂O carbonyl compounds, CO, and methanol. Flash pyrolysis experiment in combination with high performance liquid chromatography (FPy-HPLC) was used to study the pyrolytic formation of eight carbonyl compounds (i.e., formaldehyde, acetaldehyde, acetone, acrolein, propionaldehyde, crotonaldehyde, methyl ethyl ketone, and butyraldehyde) during the pyrolysis of cigarette paper under the pyrolysis conditions of cigarette puffing. Moreover, the solid char formed after the flash pyrolysis experiments were studied by X-ray photoelectron spectroscopy (XPS). It had been found that the pyrolysis temperature influenced the formation of carbonyl compounds and the composition of char greatly.     

Compound Finishing of Bombyx mori Silk: A Study of Cold Oxygen Plasma/Titania Sols Treatments and Their Influences on Fiber Structure and Performance

Degummed Bombyx mori (B. mori) silk fabrics modified by cold oxygen plasma (COP) and/or titania sols (TSs) were investigated by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction, field emission scan electronic microscopy (FE-SEM), thermo-gravimetric and differential thermal analysis, and ultraviolet (UV) transmittance methods in this study. FT-IR analysis demonstrated that titania particles were associated with B. mori silk fibers by forming organic?Cinorganic hybrid blends. Processing sequences of COP and TSs, and curing conditions showed significant impacts on the crystalline, thermal, micro-morphological, and UV resistant characteristics of silk fabrics. Crystallinity index by both area and height methods, and crystallite sizes of silk fabrics were calculated as well. Results showed that crystallinity index of finished samples approximate to that of degummed silk fabric could be obtained by applying TSs and curing at 160?°C for 2?min prior to COP treatment, or vice versa with lower temperature of 140?°C for 3?min, whereas the crystallite sizes of treated samples increased slightly. The initial decomposition temperatures of finished samples were elevated by 23?C35?°C with increased char residues at 600?°C, while the transmittance of UVA and UVB of finished samples decreased by 11.7, 17.7%, respectively. FE-SEM analysis revealed that titania particles were associated on the fiber surfaces with different smoothness.     

Investigations of the barbell ultrasonic transducer operated in the full-wave vibrational mode

In this paper, the resonance frequency equation and expression of displacement amplitude magnifications of a full-wave barber ultrasonic horn are obtained. By discussing the relationships between the displacement amplitude magnifications and the geometrical dimensions, the optimized design of the horn for the largest magnification is proposed, which is helpful to improve the radiation power and the transfer efficiency of the acoustic energy of the ultrasonic oscillatory system. Based on the optimized design of the horn, we introduced a barbell ultrasonic transducer operated in the longitudinal full-wave vibrational model and obtained the resonance frequency equations. For comparison, the resonance frequencies of the full-wave barbell horn and the full-wave barbell transducer are also analyzed by finite element method (FEM). It is shown that the values obtained by theoretical analysis and FEM are in good agreement with experimental observations. We hope that the research of this paper is helpful for the use of the barbell horn and transducer in the applications such as ultrasonic liquid processing.     

Electro-optic Q-switched intracavity optical parametric oscillator at 1.53 μm based on KTiOAsO4

An eye-safe, high peak power optical parameter oscillator (OPO) intracavity pumped by electro-optic Q-switched Nd:YAG laser is presented. This OPO is based on a 20 mm length KTiOAsO₄ crystal with non-critical phase matching (θ = 90°, ?=0°) cut. An aperture ∅3 mm acted as limiting diaphragm to get good beam quality of pumping laser. The output energy of 25 mJ at the signal wavelength 1.53 μm was obtained with repetition rate of 1 Hz. The highest peak power intensity was up to 88 MW/cm² with pulse width of 4 ns. Without diaphragm, the maximum output energy of 90 mJ was achieved with area of light spot (∅6 mm) four times larger, but the peak power intensity was lower.     

超声波作用下气泡的非线性振动

Flynn方程在引入泡内气体的压缩性修正后能够更好地描述超声波作用下液体内气泡的非线性振动。我们以此为基础通过数值分析得到了不同初始半径的气泡在同一声场中的振动位移时间图像和相轨迹,发现气泡的运动行为对其初始状态有很强的依赖关系,在频率为26.5 kHz,幅度为1.35 atm的声波作用下,初始半径小于1 μm的气泡作小幅受迫振动,大于200 μm的气泡作小幅准本征振动,不具备空化气泡特征。声场中的小气泡对声波强度变化的反应更为激烈,当增加声强度时,可将一定范围内的小幅受迫振动气泡转化为空化气泡,并且,当驱动声波压力幅值增加时,初始半径越小的气泡的最大位移增加幅度越大。驱动声波频率同样影响气泡的振动。随着声波频率的升高,空化气泡的初始半径取值区间越来越小,空化振荡也越来越弱。本文还通过高速摄影系统对换能器作用于未除气的自来水所引起的变化进行了实验研究,结果表明,超声波作用下液体内的气泡场是一个混合场,场内气泡尺寸呈一定的分布状态,不仅有空化气泡,还有毫米级的大气泡。气泡的运动行为直接影响空化效果。超声空化场是一个复杂的物理场,场内除了有气泡的振动外,还有气泡间的相互吸引、碰撞和结合。      

产生蓝色相干辐射和实现Nd:YAG 1.0642μm倍频90°非临界相位匹配的Nb:KTiPO4

本文报道了用熔盐顶部籽晶法生长Nb浓度(0～13)mol%的Nb:KTP晶体的倍频的Ⅱ型相位匹配的截止波长和Nd:YAG1.0642μm及Nd:YA1O₃1.0795μm激光在这些晶体中倍频的最佳相位匹配角的测量结果.从中可看出,由于Nb⁵⁺的引入使KTP晶体倍频的Ⅱ相位匹配的截止波长有效蓝移,目前已使截止波长蓝移至937nm且有效产生468.5nm的倍频蓝光.同时Nb⁵⁺的引入使Nd:YAG1.0642μm激光和Nd:YA1O₃倍频的最佳相位匹配方向产生很大的变化,目前已使Nb:KTP晶体倍频的最佳相位匹配方向为θ=88.32°、Φ=0°,非常接近于90°非临界相位匹配方向.