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排序方式: 共有1246条查询结果,搜索用时 296 毫秒
31.
用CeO2修饰炭粉做载体,使用有机溶胶法还原PdPt二元合金的方法制备了一系列PdPt/CeO2-C催化剂.借助电化学测试,探讨催化剂中不同Pd与Pt原子比例的PdPt二元合金和不同含量的CeO2对于甲酸电氧化催化活性的影响.不断减少PdPt合金中Pt的比例可以促使甲酸氧化的起始电位前移,当Pd:Pt=15:1时氧化电流出现极值;同时,随着催化剂中CeO2含量的增加,催化剂对于HCOOH氧化的电流密度增加,当含量为15%时达到最大值.相对于Pd/C催化剂,在Pd15Pt1/15CeO2-C催化剂表面的甲酸氧化反应起始电位负移至少0.1V,氧化的电流密度提高60%以上.结合X射线衍射(XRD),X射线光电子能谱(XPS),透射电镜(TEM)和热重(TG)等测试数据可以发现,当极少量的Pt与Pd形成合金,Pt与Pd之间产生电子效应,使得合金表面HCOOH氧化的过电位降低;而CeO2的添加不仅有助于PdPt二元合金的分散,更有可能改变甲酸在PdPt表面的氧化反应路径,发挥双功能机理. 相似文献
32.
Jiaxi Zhang Longhai Zhang Li Du Huolin L. Xin John B. Goodenough Zhiming Cui 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(40):17641-17646
A group of newly reported antiperovskite nitrides CuxIn1−xNNi3 (0≤x≤1) with tunable composition are employed as electrocatalysts for the hydrogen evolution reaction (HER). Cu0.4In0.6NNi3 shows the highest intrinsic performance among all developed catalysts with an overpotential of merely 42 mV at 10 mA cmgeo−2. Stability tests at a high current density of 100 mA cmgeo−2 show its super-stable performance with only 7 mV increase in overpotential after more than 60 hours of measurement, surpassing commercial Pt/C (increase of 170 mV). By partial substitution, the derived antiperovskite nitride achieves a smaller kinetic barrier of water dissociation compared to the unsubstituted InNNi3 and CuNNi3, revealed by first-principle calculations. It is found that the partially substituted CuxIn1−xNNi3 possesses a thermal neutral and desirable Gibbs free energy of hydrogen for HER, ascribed to the tailoring of the energy of d-band center arose by the A-site (A=Cu or In) substitution and a resulting optimization of adsorbate interactions. 相似文献
33.
Using rubber to toughen polylactide (PLA) is always accompanied by the sharp reduction in stiffness. Herein, PLA/poly (methyl methacrylate) grafted natural rubber (NR-PMMA) thermoplastic vulcanizates (TPVs) with balanced stiffness-toughness were fabricated. With the addition of 40 wt % NR-PMMA, the impact strength and tensile toughness of PLA/NR-PMMA TPV significantly improved to about 102.7 kJ/m2 and 66.1 MJ/m3, respectively, compared with those of 2.7 kJ/m2 and 2.4 MJ/m3 for the pure PLA. Meanwhile, the yielding stress was maintained at 34.5 MPa. Fourier transform infrared spectroscopy (FTIR) confirmed the formation of in-situ interfacial compatibilization between PLA and rubber phases. Both tensile and impact toughening mechanism were studied and deduced as considerable energy dissipation provided by the continuous rubber phase. Instrumented notched impact tests demonstrated that the energy dissipating in crack propagation process contributed to the main part of impact toughness. In addition, a novel toughening model based on bicontinuous structure was incorporated, which showed good applicability in predicting the impact strength of PLA/NR-PMMA TPVs. 相似文献
34.
35.
A Q-switched mode-locking femtosecond all-fiber laser based on a 2 cm long homemade Er3+/Yb3+ codoped phosphate glass fiber has been reported. By using the nonlinear polarization evolution technique, a nearly 100% modulation
depth of mode-locking pulse train is achieved. At a pump power of 410 mW, the energy of each Q-switched envelope, whose width
is about 220 μs, is 10 μJ, while the duration of mode-locking pulse within the Q-switched envelope is 318-fs. 相似文献
36.
Zhang G. Zhang Q. Shen Y. L. Zhou Q. L. Hu L. L. Qiu J. R. Chen D. P. 《Laser Physics》2011,21(2):410-413
Two compact fiber lasers based on the gain medium of Nd-doped phosphate glass multicore fiber (MCF), of length no more than
10 cm, have been demonstrated experimentally for the first time. A stable phase-locked laser beam at 1055 nm emitted from
a three-core fiber that is 8.5 cm in length has been achieved, with a maximum output power of 20 mW. The properties of similar
seven-core fiber laser also have been investigated. 相似文献
37.
《Communications in Nonlinear Science & Numerical Simulation》2011,16(3):1107-1113
Family of equations, which is the generalization of the K(m, m) equation, is considered. Periodic wave solutions for the family of nonlinear equations are constructed. 相似文献
38.
This paper deals with the problems of consistency and strong consistency of the maximum likelihood estimators of the mean and variance of the drift fractional Brownian motions observed at discrete time instants. Both the central limit theorem and the Berry-Ess′een bounds for these estimators are obtained by using the Stein’s method via Malliavin calculus. 相似文献
39.
40.
根据分数阶线性系统的稳定理论,将混沌系统分成稳定的线性部分和相应的非线性部分.设计主动控制器,对非线性部分进行补偿,从而将分数阶混沌系统控制到平衡点.为了提高主动控制器的补偿能力,提出基于反馈的多最小二乘支持向量机(M-LS-SVM)拟合模型.通过减聚类方法将输入空间划分为一些小的局部空间,在每个局部空间中用LS-SVM建立子模型.为解决子模型相互之间的严重相关问题,提高模型的精度和鲁棒性,各个子模型的预测输出通过主元递归(PCR)方法连接.仿真实验表明该方法有助于提高补偿精度和系统响应指标.
关键词:
分数阶
混沌系统
多最小二乘支持向量机
反馈 相似文献