Studies on the Refolding of Egg White Lysozyme Denatured by Urea Using ＂Phase Diagram＂ Method of Fluorescence

The refolding of reduced and non-reducing egg white lysozymes in a urea solution was studied by a ＂phase diagram＂ method of fluorescence. The result showed that in the refolding of the reduced egg white lysozyme, an intermediate state of an egg white lysozyme exists at the urea concentrations in a final renaturation solution being about 4.5 mol/L, their refolding follows a three-state model; while in the refolding of the non-reducing egg white lysozyme, two intermediate states exist at the urea concentrations being separately 4.0 and 2.5 mol/L, and their refolding follows a four-state model. Through the comparison between the unfolding and refolding of an egg white lysozyme in the urea solution, it was found that both of the refolding of reduced and non-reducing egg white lysozyme molecules was irreversible to their unfolding in the urea solution. Finally, a suggested refolding was separately presented for the reduced and non-reducing egg white lysozymes in the urea solution.     

茶叶、银杏叶中钾含量的测定

采用原子吸收分光光度法对中国一些常用茶叶和银杏叶中的钾和不同方法冲泡的茶、银杏叶饮料中的钾进行了测定,结果表明,茶叶、银杏叶中的钾含量丰富,为14 035~38 924 mg/kg。饮茶和银杏叶茶对人体健康有益。     

Single Crystalline SnO Nanosheets as Anode Material for Lithium Secondary Battery

Single crystalline SnO nanosheets with high aspect ratios have been synthesized by a simple solution-based chemical route aided with sonication. The dimension and thickness of the SnO nanosheets are controllable by adjusting the amount of cetyltrimethyl ammonium bromide （CTAB） added. The as-prepared SnO nanosheets have loosely packed {001 } surfaces and expanded lattice, thus rendering a high reversible capacity approaching the theoretical value of SnO as anode material in Li secondary battery.     

Synthesis of Polymer-bound Sensitizers and their Applications in the Preparation of Previtamin D3 from Tachysterol

Two kinds of polymer-bound photosensitizers were synthesized, in which anthracene acts as sensitizer moiety,polystyrene (PS) and poly(methyl methylacrylate) (PMMA) serve as solid phase supports, respectively. The photoisomerization of tachysterol to previtamin D3 was carried out with these polymer-bound photosensitizers in ethanol and toluene solutions. The experiment results demonstrate that these solid phase photosensitizers are efficient for the photoisomerization with good recycle property and can be simply separated from the reaction mixtures by filtration.     

汽车尾气净化用钯催化剂的制备及活性考察

制备了一系列用于净化汽车尾气的新型钯催化剂．该催化剂以堇青石蜂窝陶瓷为基体与含助剂的γ-Al2O3涂覆层构成载体，La、Ce、Pr、Sm、Nd、Eu、Mg、Ca、Ba、Sr、Ni、Fe、Mn等的复合氧化物为助催化剂，主活性组分钯，含量为0．05％．在实验室配气条件下，对该系列催化剂进行三效活性的测试，结果显示催化剂对CO．THC．NO的T50分别为188℃，213℃，204℃，经空气中1000℃／4h的快速热老化后(相当于汽车运行5万公里)，T50分别为202℃，231℃，222℃；表明，部分助剂引入涂层，增大了载体的比表面积，提高了载体的抗热冲击能力；以氧化物形式引入的另一部分助剂同时起到分散和稳定贵金属的作用，且钯与其产生协同作用，对改善钯催化剂的三效性能有显著效果．     

对位取代苯基烯丙基醚的烷基化反应

烯丙基醚是一个重要的β-羰基化合物的合成等价物,已有许多应用,它的应用和反应的区域选择性有密切关系.最近,Werstiuk 曾对烯丙基化合物的反应及其在合成上的应用作了综述,并讨论了立体因素对烯丙基化合物反应区域选择性的影响.Evans 等研究了烯丙基烷基醚阴离子和亲电试剂反应中位阻和区域选择性的关系.当亲电试剂是卤代烷时,烯丙基醚中烷基体积增大,γ位烷基化的比例也增大;而亲电试剂为羰     

热交换实验中量热器热损耗的研究

本文对热交换实验中量热器尺寸结构进行分析研究，阐述实验中量热器的最小热损耗只与其设计尺寸有关，而与其它实验值无关。     

科克曼女生问题的一种构造解

科克曼女生问题是数学史上的一道有名的组合命题 ,本文利用图的性质给出了一种构造科克曼问题解的简单方法 .     

一种基于过积分的能量稳定通量重构方法

能量稳定通量重构(Energy Stable Flux Reconstruction,ESFR)方法在求解线性对流方程时具有能量稳定性质.但在求解非线性方程时能量稳定性质的实现需要采用L²投影,否则可能由于存在混淆误差,导致不稳定.本文将ESFR与过积分相结合构造具有良好去混淆效果的高阶通量重构(Flux Reconstruction,FR)方法.采用积分点大于求解点(Q> P)的取点方式,从理论上分析了格式的能量稳定特性.从数值上对比了gDG与gSD两种修正函数,三种不同过积分取点方式,并对比过积分与非过积分形式的ESFR(Q=P).通过对一维非均匀线性对流方程、二维等熵涡及欠解析涡流算例的模拟,结果表明:在g_SD修正函数下,ESFR(Q> P)格式比ESFR(Q=P)格式去混淆效果更好,数值误差更小;对比两种修正函数,g_DG修正函数数值误差更小,更稳定:对比三种过积分通量点分布,选定g_DG修正函数时,通量点取Legendre-GaussLobatto(LGL)点或者通量点基于高斯权重...     

Calderón-Zygmund核的多线性振荡奇异积分算子的Lp-有界性

研究关于Calderón-Zygmund标准核的多线性振荡奇异积分算子,证明了这类算子的L^p-有界性.