排序方式: 共有56条查询结果,搜索用时 15 毫秒
21.
利用紫外吸收光谱法、等温滴定量热法、1H NMR法等研究了麦穗宁与瓜环Q[n](n=6,7,8)的超分子相互作用,讨论了瓜环/麦穗宁超分子体系的形成对麦穗宁的pKa及抑菌活性的影响.实验结果表明,麦穗宁与Q[n](n=6,7,8)均形成1∶1的主客体配合物,瓜环/麦穗宁超分子体系的形成使麦穗宁的pKa发生了明显移动,且对麦穗宁有助溶作用;Q[6]、Q[7]的加入减弱了麦穗宁对小麦赤霉的抑菌活性,而Q[8]的加入则增强了麦穗宁对小麦赤霉的抑菌活性. 相似文献
22.
正煤层气的产出要经过排水―降压―解吸—扩散—渗流—产出的过程,因此伴随着煤层气生产井的日常开采,有大量的生产水产出~([1])。产出水主要来自煤层及其围岩,在漫长的地质历史时期及地下水系统的循环过程中,煤层水常与煤层及其围岩进行各种物理化学作用,产出水中的可溶性二氧化硅含量及动态变化可以反映地下水的封存、补给状况 相似文献
23.
八元瓜环与抗癌药物甲氨蝶呤的超分子相互作用 总被引:1,自引:0,他引:1
利用紫外吸收光谱法考察了八元瓜环(Q[8])与抗癌药物甲氨蝶呤(MTX)的相互作用;同时研究了甲氨蝶呤的不同质子化形式及体系温度对相互作用的影响;计算了相应的稳定常数及热力学参数等.实验结果表明,Q[8]与MTX作用比为1∶1,包结平衡常数为(7.64±1.52)×104 L/mol;龄前热力学参数测定结果表明,上述主... 相似文献
24.
Phenolic hydroxyl-terminated polysiloxanes were incorporated into epoxy resins to reducethe internal stress owing to the mismatch in coefficient of thermal expansion (CTE).Polysiloxane-epoxy resin block copolymers were made by a pre-reaction step prior to thecuring. In the cured resin, the domain size of the polysiloxane phase depended on thestructure of the phenolic hydroxyl-terminated polysiloxane. It was found that the modulus ofthe cured resin depended largely on the level of the modifier, while the CTE was affectedgreatly by the structure of the polysiloxane. By means of incorporating a few percent ofmethylphenylsiloxane unit into the polydimethylsiloxane chain, or by introducing morecompatible end-capping groups, the compounds of more effective low stress modifiers weresynthesized. 相似文献
25.
26.
27.
28.
黄英 《数学年刊A辑(中文版)》1991,(4)
考虑拟线性双曲型方程组的非局部初边值问题,得到C~1解的存在唯一性。 本文的结果不仅可将(局部)初边值问题的理论作为特例包含,而且还能应用于很多重要的问题,如人口问题、细胞分裂问题、传染病问题和Lagrange内弹道问题等。 相似文献
29.
MQ silicone resins were prepared through hydrolytic condensation of ethyl polysilicate ortetraethoxysilane and hexamethyl disiloxane. The unit ratio of the MQ resins was determined by ~(29)Si-NMR.The relationship of the unit ratio of the product resins with that in the feed was studied. When the reactionwas catalyzed by aqueous hydrochloric acid, and the unit ratio of M to Q in the feed was more than 1, the unitratio of the product was usually lower than that of the feed. The MQ silicon with an unit ratio of M/Q>2could not be obtained. However, if the reaction was catalyzed by concentrated sulfuric acid and the reversehydrolysis process was employed, MQ silicone resin with very high M/Q ratio was successfully prepared. 相似文献
30.
酸蚀对微通道板电性能的影响 总被引:3,自引:1,他引:2
采用扫描电镜(SEM)、卢瑟福背散射谱(RBS)、原子力显微镜(AFM)、能量色散谱仪(EDS)、照度计、微通道板测试台等分析表征手段,从微通道板皮料玻璃表面的成分、形貌和结构上,研究了酸蚀时间对微通道板电子增益、体电阻、噪声电流和电子图像等电性能的影响。研究结果表明:酸蚀时间显著影响微通道板的电性能,经酸蚀120min后微通道板的电子增益和图像亮度达到最高值;随着酸蚀时间的增加,噪声电流相应增加,而体电阻降至一定值后保持相对的稳定。 相似文献