Analysis of Dα（Hα） spectrum emitted in front of the limiter in HT-7^＊

In order to understand the recycling and emission processes of hydrogen atoms in HT 7, spectral profiles of the Dα（Hα） line emitted in front of the limiter have been observed with a high-resolution spectrometer and simulated by using the neutral particle transport code DEGAS 2. The results show that four processes are necessary to interpret the Dα（Hα） line shape： 1） atom desorption, 2） molecular dissociation, 3） particle reflection, and 4） charge-exchange. The products of the first two processes are cold atoms which emit photons near the peak of Dα（Hα） line shape, and those from the last two are warm atoms contributing to the blue side of the spectrum. For a typical ohmic discharge （shot 68520 ne（0） ≈ 3× 10^19 m^-3. these components contribute 32%, 15%, 32% and 21%, respectively. Dα（Hα） line shapes under different plasma parameters are also discussed in this paper.     

"化学与人类"网络课程的设计与开发

简要阐述了“化学与人类”网络课程的选题来源、系统设计和开发等问题。     

二氧化硅凝胶玻璃基质中原位合成镍酞菁的动力学研究

实现酞菁材料化进而器件化的一个重要途径是将其引入到固相基质制备酞菁掺杂的复合材料。文章以邻苯二腈和可溶性镍盐为反应试剂,通过一定温度的热处理,采用原位合成技术在二氧化硅凝胶玻璃基质中原位合成镍酞菁,制备了复合凝胶玻璃材料, 并用紫外-可见吸收光谱表征了其制备过程。由于镍酞菁在可见光区域有明显吸收,以镍酞菁物理掺杂的复合凝胶玻璃作为参照,用670 nm处的吸光度来计算原位合成镍酞菁的量。研究了原位合成动力学,拟合出原位合成NiPc的量与加热时间的关系曲线。拟合曲线呈“S”形,与Avrami-Erofeev公式相符。由此推导出在180, 185, 190, 195和200 ℃时的反应级数分别是4.5, 4.5, 3.7, 3.2, 1.9。     

线性指数分布参数的经验Bayes检验问题：φ混合样本情形

讨论了弱平稳φ混合样本下线性指数分布参数的经验Bayes(EB)双侧检验问题,利用概率密度函数的核估计构造了参数的经验Bayes检验函数,在适当的条件下证明了所提出的经验Bayes检验函数的渐近最优(a.o.)性,并获得了它的收敛速度.     

分层半空间表面非线性瑞利波的激发*

针对非线性瑞利波在均匀分层半空间结构中的激发和传播规律进行研究。根据摄动理论和模态分解将分层半空间结构中瑞利波的二次谐波声场表示为二倍频瑞利波模式的线性组合,经由互易关系得到各模式的展开系数表达式。对不同分层半空间结构中瑞利波二次谐波的激发和传播特性进行讨论,结果表明相速度匹配的瑞利波模式其二次谐波分量随传播距离线性增长,非匹配模式的二次谐波分量则沿传播方向周期震荡传播。此外,文中定义非线性参数表征瑞利波模式产生的非线性程度,这有利于选择出具有明显非线性效应的匹配点,为后续检测工作提供理论依据,具有指导意义。     

Analysis of asymmetry of the Dαemission spectra under the Zeeman effect in boundary region for D-D experiment on EAST tokamak

In 2015 campaign,deuterium atomic emission spectra(D_α)under the Zeeman effect in boundary region had been measured by a high resolution optical spectroscopic multichannel analysis(OSMA)system based on passive spectroscopy during the deuterium plasma discharge on EAST tokamak,and part of the works about the Zeeman effect on D_αspectra had already been done.However,the asymmetric phenomena of D_αemission spectra under the Zeeman effect were observed in process of analyzing the spectral data.To understand the asymmetric phenomena and acquire the useful local plasma information,an algorithm was proposed and used to analyze the asymmetry of the emission spectra under the Zeeman effect with all polarization components(πand±σ).In the algorithm,the neutral atoms were considered to follow the Maxwell distribution on EAST,and I+σ=I-σwas considered and set.Because of the line-averaged spectra along the viewing chord,the emission spectra were considered from two different regions:low-field side(LFS)and high-field side(HFS).Each spectral line was classified into three energy categories(the cold,warm,and hot)based on different atomic production processes in boundary recycling.The viewing angleθ(between the magnetic field B and the viewing chord),magnetic field B at two spectral emission positions(HFS and LFS)and the Doppler shift of all three energy categories of each spectral line were all considered in the algorithm.The effect of instrument function was also included here.The information of the boundary plasma were acquired,the reason for the asymmetric phenomena was discussed,and the boundary recycling during the discharge were studied in the paper.Based on fitting a statistical data of acquired fitting results,an important conclusion was acquired that the ratio of the spectral line intensity in HFS and LFS was proportional to the square of that of the corresponding magnetic field.     

φ混合样本下帕累托分布参数的经验贝叶斯分析

在弱平稳φ混合样本下,讨论了Pareto分布参数的经验Bayes（EB）单边检验问题,构造了参数的经验Bayes检验函数,证明了它具有渐近最优（a.o.）性,并且获得了收敛速度。     

CdX(X=Se,Te,Te/ZnS)量子点脂质体的制备及毒性比较

在水相中以巯基乙酸(mercaptoacetic acid, MA)为稳定剂合成了CdSe、CdTe、CdTe/ZnS量子点及谷胱甘肽(glutathione, GSH)为稳定剂合成了CdTe量子点,然后通过卵磷脂和胆固醇修饰制得相应的量子点脂质体。溶血实验证实GSH修饰量子点的溶血率低于MA修饰的量子点45%;脂质体修饰后,量子点的溶血率＜5%,达到生物医用材料要求。不同表面修饰的量子点对小鼠毒性存在明显差异,荧光显微镜观察组织切片证实量子点在小鼠体内主要分布在肺、肾、胸腺等组织中,而脂质体量子点在脑组     

水相合成CdX (X＝Te, Te/CdS, Te/ZnS)红色量子点及毒性效应

分别以巯基乙酸(Mercaptoacetic Acid, MA)、还原型谷胱甘肽(Glutathione, GSH)为稳定剂在水相中直接合成了巯基乙酸CdTe (CdTe-MA)、红色巯基乙酸CdTe/CdS (CdTe/CdS-MA)、巯基乙酸CdTe/ZnS (CdTe/ZnS-MA)及谷胱甘肽CdTe (CdTe-GSH)量子点. 其中, CdTe-GSH量子点的量子产率可达47.3%. 体外溶血实验证实CdTe/ZnS-MA和CdTe-GSH量子点的溶血率较CdTe-MA和CdTe/CdS-MA低, 浓度为0.05 mmol/L的量子点溶血率＜5%, 达到了生物医用材料的要求. 活体实验证实: 通过尾静脉方式把量子点注入小鼠体内后, 荧光显微镜观察发现高剂量的量子点(0.4 mmol/10 g)在体内主要在心、肝、脾、肾组织中分布较多, 且引起不同程度的组织病变.     

光谱法测HT-7托卡马克诊断中性束的束成分

 实验测量了诊断中性束(DNB)中H0的4种主要能量成分(全能量，半能量，1/3能量，1/18能量)，运用光谱法来分析中性束的束成分所占百分数。根据多普勒效应，中性束中的氢粒子发出的Ha波长偏离本底的Ha波长，波长偏移量与氢粒子的能量相关，从而在光谱仪上得到多峰Ha谱线。通过编写程序并以此对实验的原始谱线进行了初步和精确拟合，最终准确有效地分析出中性束的束成分和束能量。实验测得DNB束流的中性氢粒子的全能量、半能量、1/3能量和1/18能量4种成分分别占15%,42%,35%,8%。