明日叶黄酮类化合物清除羟基自由基活性研究

为了研究明日叶黄酮类化合物对羟基自由基的清除作用,以明日叶（主要取叶片）为原料,用体积分数为65％乙醇提取明日叶总黄酮,测定其总黄酮含量.通过Fenton反应体系产生羟基自由基,利用明日叶提取液中的功能成分黄酮类化合物对羟基自由基的清除作用进行研究.结果表明：明日叶提取物总黄酮质量分数为10.18％,且黄酮类化合物对羟基自由基有较强清除效力,当提取物总黄酮浓度在0.1～1.0 mg/mL范围内,其与清除率呈正相关.明日叶中黄酮类化合物对羟基自由基有较强清除效力,作为天然抗氧化产品开发具有一定价值.     

芳基碘鎓盐促进芳基化反应的应用

二芳基碘鎓盐属于有机高价碘化合物,具有无毒、反应条件温和以及良好的选择性等优点,在有机合成中具有重要地位,受到广大化学工作者的关注。近年来,利用二芳基碘鎓盐在金属催化下进行的芳基化反应为一些难以合成的杂环化合物的合成提供了简便、高效的方法;同时,二芳基碘鎓盐在无催化剂下进行的芳基化反应,为C—C偶联反应开辟了新的绿色合成路线。本文综述了近年来二芳基碘鎓盐在有机合成中促进芳基化反应的最新进展,着重介绍了利用二芳基碘鎓盐作为芳基化试剂与有机金属试剂、烯烃和炔烃类以及杂环化合物进行芳基化反应的研究;总结了二芳基碘鎓盐与杂环化合物反应中钯催化和铜催化下芳基化反应的机理,最后对二芳基碘鎓盐在今后有机合成中的应用作出了展望。     

基于激光点云多条件约束的相机检校方法

为了克服相机检校对二维/三维检校场的依赖,提出一种基于激光点云多条件约束的相机检校方法。该方法通过对相机获取的多视影像进行光束法平差获得初始相机参数;利用影像点云与其最邻近的激光点云之间的位置关系,以共线方程为基础模型,建立多条件约束的相机检校数学模型;使用不等式约束的最小二乘方法平差迭代解算相机参数。将本文方法与基于三维控制场的检校精度进行了实验对比分析,结果表明本文方法与基于三维控制场的检校精度相当,两者反投影平均误差相差小于0.1 pixel,验证了本文方法在没有传统检校场的情况下进行相机检校的可行性。     

Applicability of ~9Be global optical potential to reactions of ~(7,10,11,12)Be

Elastic scattering angular distributions and total reaction cross-sections of ~(7,10,11,12)Be projectiles are predicted by the systematic ~9 Be global phenomenological optical model potential for target mass numbers ranging from24 to 209. These predictions provide a detailed analysis by their comparison with the available experimental data.Furthermore, these elastic scattering observables are also predicted for some targets out of the mass number range.The results are in reasonable agreement with the existing experimental data, and they are presented in this study.     

Free-space propagation of autofocusing Airy vortex beams with controllable intensity gradients

Vortex splitting is one of the main causes of instability in orbital angular momentum(OAM) modes transmission. Recent advances in OAM modes free-space propagation have demonstrated that abruptly autofocusing Airy vortex beams(AAVBs) can potentially mitigate the vortex splitting effect. However, different modes of vortex embedding will affect the intensity gradients of the background beams, leading to changes in the propagation characteristics of vortex beams. This study presents the unification of two common methods of coupling autofocusing Airy beams with vortices by introducing a parameter(m), which also controls the intensity gradients and focusing properties of the AAVBs. We demonstrate that vortex splitting can be effectively reduced by selecting an appropriate value of the parameter(m) according to different turbulence conditions. In this manner,the performance of OAM-based free-space optical systems can be improved.     

ON INTEGRABILITY UP TO THE BOUNDARY OF THE WEAK SOLUTIONS TO A NON-NEWTONIAN FLUID

This work consider boundary integrability of the weak solutions of a non-Newtonian compressible fluids in a bounded domain in dimension three, which has the constitutive equartions as ■The existence result of weak solutions can be get based on Galerkin approximation. With the linear operator B constructed by BOGOVSKII, we show that the density ■is square integrable up to the boundary.     

Image charge effect on the light emission of rutile TiO_2(110) induced by a scanning tunneling microscope

The plasmon-enhanced light emission of rutile TiO_2(110) surface has been investigated by a low-temperature scanning tunneling microscope(STM). We found that the photon emission arises from the inelastic electron tunneling between the STM tip and the conduction band or defect states of TiO_2(110). In contrast to the Au(111) surface, the maximum photon energy as a function of the bias voltage clearly deviates from the linear scaling behavior, suggesting the non-negligible effect of the STM tip on the band structure of TiO_2. By performing differential conductance( dI/dV) measurements, it was revealed that such a deviation is not related to the tip-induced band bending, but is attributed to the image charge effect of the metal tip, which significantly shifts the band edges of the TiO_2(110) towards the Femi level(E_F) during the tunneling process. This work not only sheds new lights onto the understanding of plasmon-enhanced light emission of semiconductor surfaces, but also opens up a new avenue for engineering the plasmon-mediated interfacial charge transfer in molecular and semiconducting materials.     

元素的起源与0号元素

论述元素的起源是以中子为起点,中子是特殊的0号元素。以中子的衰变特点、核反应的特点、与质子类同的特点、与稀有气体元素类同的特点以及中子星的存在、四中子的发现等论据,提出应当把中子看作元素并纳入元素周期表中。建议给这个特殊的元素命名为"中"。