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采用太赫兹时域光谱和拉曼光谱法对L-苏氨酸多晶粉末进行测试研究,获得了样品在0.2—2.8 THz(6.7—93.2 cm-1)波段的特征吸收和10—4000 cm-1波段的拉曼散射谱;分别在6.7—93.2 cm-1和400—4000 cm-1两个波段进行了吸收光谱与拉曼散射光谱的对比,根据晶胞分子所属的空间群,对隶属于分子的极性和非极性振动模式(A, B1,
关键词:
太赫兹光谱
拉曼散射
氨基酸 相似文献
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本文对1,4-萘醌进行了太赫兹时域光谱,远红外吸收光谱及低频拉曼散射谱的测试研究。1,4-萘醌的太赫兹吸收光谱与远红外谱仪测得的光谱取得了在1.75 THz(58.3 cm-1)/1.63 THz(54.3 cm-1)等处吸收峰位基本相同、两者相互佐证和补充的结果。将太赫兹和远红外吸收谱与低频拉曼散射谱进行比较,表明两种选择机制不同的光谱在1.04,1.72和4.59 THz等处的峰位基本重合,结合群论的不可约表示理论分析,表明该样品在低频波段具有拉曼活性和红外活性的振动属性(A1、B1或B2)。采用Gaussi-an03软件的密度泛函理论B3LYP函数和6-311基组模拟单分子红外与拉曼光谱,结合实验分析,对部分分子基团或原子振转模式给与了指认。 相似文献
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The characteristic fingerprints of carnosine from 0.2 to 2.6 THz are first measured by terahertz time-domain spectroscopy at room temperature. For the pure carnosine, the refractive index varies between 1.79 and 1.85 with the average value 1.84, while for the carnosine-polyethylene mixture, four absorption peaks centred at 1.37, 1.56, 1.85 and 2.49 THz are detected. A comparison of the theoretical predictions using the density functional theory with the experimental results shows satisfactory agreement except somewhat blue shift. 相似文献
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In this paper, we propose and study a new evolution model of minority game. Any strategy in minority game can be regarded as composed of sub-strategies corresponding to different histories. Based on the evolution model proposed by Li-Riolo-Savit, in which those agents that perform poorly may update their strategies randomly. This paper presents a new evolution model in which poor agents update their strategies by changing only a part of sub-strategy sets with low success rate. Simulation result shows that the new model with sub-strategy-set updating evolution mechanism may approach its steady state more quickly than the Li-Riolo-Savit model. In the steady state of the new model, stronger adaptive cooperation among agents will appear, implying that the social resource can be allocated more rationally and utilized more effectively compared with the Li-Riolo-Savit model. 相似文献