两个基于苯并噻唑-2-硫酮的银(Ⅰ)配合物的合成、晶体结构和光谱性质

合成了2个含有杂环硫酮的银(Ⅰ)配合物, [AgCl(PPh₃)₂(BTZT)]₂ (1), [Ag(PPh₃)₂(BTZT)₂](NO₃)CH₃OH (2)(PPh₃=三苯基膦; BTZT=苯并噻唑-2-硫酮), 并通过红外光谱、X射线单晶衍射、荧光光谱和核磁共振氢谱进行分析和表征。杂环硫酮存在化学活性基团-N(H)-C(=S)-在平衡中, 与其硫醇形式可以相互转化。2个配合物是在含有2-巯基苯并噻唑(MBT)的甲醇与二氯甲烷混合溶液中, AgCl或AgNO₃与三苯基膦反应得到的。配合物1的每个不对称单元中包含2个相同的分子结构, 但是它们具有不同的键长和键角。配合物2是一个简单的单核杂配配合物, 它的主体结构通过氢键作用连接游离的CH3OH和NO₃-离子。配合物1和2发射峰的红移源于配体中的π-π^*跃迁。     

Waveguides Induced by Screening-Photovoltaic Solitons in Biased Photorefractive-Photovoltaic Crystals

We investigate theoretically waveguides induced by screening-photovoltaic solitons in biased photorefractive-photovoltaic crystals. We show that the number of guided modes in a waveguide induced by a bright screening photovoltaic soliton increases monotonically with the increasing intensity ratio of the soliton, which is the ratio between the peak intensity of the soliton and the dark irradiance. On the other hand, waveguides induced by dark screening-photovoltaic solitons are always single mode for all intensity ratios and the confined energy near the centre of a dark screening-photovoltaic soliton increases monotonically with the increasing intensity ratio. When the bulk photovoltaic effect is neglectable, these waveguides are those induced by screening solitons. When the external field is absent, these waveguides predict those induced by photovoltaic solitons.     

Finsler流形间调和映射的第2变分

给出了Finsler流形间非蜕化映射的能量泛函的第1和第2变分公式, 并利用变分公式得到了从Finsler流形到Riemann流形的非常值稳定调和映射的若干不存在性定理.     

北洋2#制冷剂循环性能试验研究

研究了一种双元混合物——北洋2#,它具有优于R22的环保性能和良好的循环性能。在同机型标准空调工况下检测,其性能(COP)较R22低1.7%,但其制冷量较R22高14.6%;其COP较R410A和R32均高8%。在低温区的检测试验证明:其COP稍低于R22,但是其能达到比R22更低的温度。并且北洋2#的制冷速度比R22快35.9%。所以,北洋2#可以作为R22有潜力的替代制冷剂。     

鱼鳔膜为基质的生物传感器测定葡萄糖的研究

以鱼鳔膜为基质同定葡萄糖氧化酶,偶联氧电极,构建了葡萄糖生物传感器,通过测定溶解氧浓度的变化定量测定葡萄糖.考察了酶浓度、pH值、缓冲液浓度对传感器的影响,优化了实验条件:即酶浓度为1 mg,pH 7.0,缓冲液浓度为100 mmol/L.此传感器具有较宽的线性范围(0.016～1.2 mmol/L),较短的响应时间(...     

基于菲涅尔反射的液体浓度精确测量系统

利用菲涅尔反射定律提出了一种测量液体浓度的新方法。整个实验装置结构简单,主要由一个激光光源、三个光耦合器、两个光电探测器组成。光源所发出的光经过三个光耦合器后传输至光纤-液体表面发生反射,反射回的光由两个光电探测器接收。在测量过程中引入参考光路,利用相对技术,使得被测液体的浓度值仅由相对接收光强R决定,从而很好地解决了光源稳定性、环境干扰等测量难题。实验以食盐溶液和蔗糖溶液为测量对象,实验结果与理论分析十分吻合。整个实验装置结构简单,测量精度高,易于操作,测量稳定性能够达到99%以上。     

NaY(Mo/WO4)2∶Eu3+红色荧光粉的合成和发光性能

利用固相法合成了Eu3+掺杂的NaY(Mo/WO4)2红色荧光粉,并用对所获得的样品进行了XRD和激发-发射光谱表征.研究发现随着Eu3+掺杂量逐渐增加,发光强度随之变化.当Eu3掺杂浓度为30mo1;,荧光粉具有最强的发光强度.荧光粉能被395 nm波长紫外光有效激发,发射光谱主要体现为Eu3+的5 D0→7F2电偶极跃迁的红光发射,因此适合于解决白光LED缺乏红光成分而导致的显色性差问题.研究发现适量的W6+取代Mo6+,不但可以提高荧光粉的发光强度,而且有利于改善材料的色纯度.W6的最佳掺杂浓度为10at;.在395 nm激发下,NaY(Mo0.9W0.1O4)2∶Eu3+荧光粉的色度坐标为(0.666,0.331),优于传统商业红色荧光粉Y2O2S:Eu3+.     

Up-conversion Properties of Er~(3+)/Yb~(3+) Co-doped Li_3Ba_2Gd_3(MoO_4)_8 Phosphors

Er~(3+)/Yb~(3+)co-doped Li_3Ba_2Gd_3(Mo O_4)_8 phosphors were synthesized by conventional solid state reaction method,and their structure and spectral properties were investigated.The diffuse reflectance spectra showed that the ~4I_(15/2)→~4I_(11/2) transition of Er~(3+)and the ~2F_(7/2)→~2F_(5/2)transition of Yb~(3+)ions were highly overlapped.Under the excitation of 980 nm,three up-conversion(UC)luminescence bands around 530,555 and 660 nm were observed,corresponding to the~2H_(11/2)→~4I_(15/2),~4S_(3/2)→~4I_(15/2) and ~4F_(9/2)→~4I_(15/2) transitions of Er~(3+)ions,respectively.The effects of the concentration and pumping power on the UC intensities of Li_3Ba_2Gd_3(Mo O_4)_8:Er~(3+)/Yb~(3+)phosphors were investigated,and the possible UC mechanism was proposed based on the results.     

有向Kirkman填充设计的谱

§ 1　IntroductionLet X be a set of v points.A packing(directed packing) of X is a collection of subsets(ordered subsets) of X(called blocks) such that any pair(ordered pair) of distinct pointsfrom X occur together in atmostone block in the collection.A packing(directed packing)is called resolvable ifitsblock setadmitsa partition into parallel classes,each parallel classbeing a partition of the pointset X.A Kirkman triple system KTS(v) is a collection Tof3 -subsets of X(triples) suchthat …     

Magmatism and deformation times of the Xidatan rock series, East Kunlun Mountains

The Xidatan rock series consist of mylonite, gneiss and granite. The U-Pb age showsthat the granite was formed at 206 Ma, and the ~(40)Ar/~(39)Ar ages of the biotite display that the my-lonite was formed at 145 Ma when the Xidatan ductile shear zone occurred. At about 110-100 Mathe Xidatan Fault reactivated again. As a result, the biotite and muscovite of Xidatan rock seriesopened their argon isotope system.