4种儿茶素类化合物电喷雾质谱裂解规律的研究

利用离子阱飞行时间质谱仪的高质量精度、高分辨率及多级测定性能, 对儿茶素类化合物(二组对映异构体)质谱裂解进行研究, 并利用氢/氘交换法对裂解方式进行确证. 发现儿茶素对映异构体间具有相同的质谱裂解途径, 多级质谱无明显区别. 在二级质谱中, 表儿茶素/儿茶素(EC/C)丢失的CO₂发生在A环, 丢失的C₂H₂O发生在B环. ^1,4A^-, ^1,3A^-, ^1,2A^-和[M-H-B环]^-4个碎片离子为EC/C特征离子, 通过这4个离子质量数变化, 推测A环上的取代情况. 因表儿茶素没食子酸酯/儿茶素没食子酸酯(ECG/CG)结构上都含有没食子酸取代基, 在二级质谱中均可见m/z169特征峰, 此离子可用于ECG/CG和EC/C区分.     

Conductivity reconstruction algorithms and numerical simulations for magneto–acousto–electrical tomography with piston transducer in scan mode

Conductivities tomography with the interactions of magnetic field, electrical field, and ultrasound field is presented in this paper. We utilize a beam of ultrasound in scanning mode instead of the traditional ultrasound field generated by point source. Many formulae for the reconstruction of conductivities are derived from the voltage signals detected by two electrodes arranged somewhere on tissue＇s surface. In a forward problem, the numerical solutions of ultrasound fields generated by the piston transducer are calculated using the angular spectrum method and its Green＇s function is designed approximately in far fields. In an inverse problems, the magneto-acousto-electrical voltage signals are proved to satisfy the wave equations if the voltage signals are extended to the whole region from the boundary locations of transducers. Thus the time-reversal method is applied to reconstructing the curl of the reciprocal current density. In addition, a least square iteration method of recovering conductivities from reciprocal current densities is discussed.     

CoBx/Co3O4电催化剂的制备及其氧析出性能

采用NaBH4溶液处理经水热、热处理步骤制得Co3O4纳米棒,得到表面富含氧空位以及无定型CoBx的Co3O4(CoBx/Co3O4)氧析出(OER)电催化剂。利用X射线衍射(XRD)、场发射扫描电镜(FESEM)、透射电镜(TEM)、X射线光电子能谱仪(XPS)等技术表征了催化剂的物相、微观形貌、元素组成以及表面化学键结构等。通过电化学工作站测试了电极材料的OER活性、稳定性、电化学阻抗等。结果表明,经NaBH4处理后,Co3O4表面高价态Co被还原至低价态Co,最终其表面有无定型CoBx的生成,并含有大量氧空位,有效提升了OER性能。在1.0 mol·L^-1 KOH电解质溶液中,达到10 mA·cm^-2的电流密度时,CoBx/Co3O4所需的过电位由Co3O4的346 mV降至298 mV。     

三光束激光干涉光刻的实现方法

分析了多光束空间分布产生的误差对图形的影响,通过计算优化得到三光束产生的干涉图形在整个面内有着更好的图形稳定性。利用氦镉激光光源通过特定的光学系统形成空间分布近似旋转对称的三束光, 对光致抗蚀剂进行干涉曝光,制作出了周期600 nm、高度350 nm的蜂窝状点阵,测量结果表明该系统具有很好的图形重复性和稳定性,同时降低了对于光学光路的精密性要求。     

聚1,5-二氨基蒽醌二次锂电池正极材料研究

采用化学氧化方法合成了聚1,5-二氨基蒽醌(PDAAQ)并用于二次锂电池.借助红外光谱确定其分子结构,实验测得材料的平均粒径为7.9μm,比表面积为8.9 m2.g-1,具有0.8 S.cm-1的电导率,符合作为电极材料使用的基本要求;电化学测试表明,作为二次锂电池正极材料使用时,聚合物重复单元中除了醌基团与Li+所发生的电化学氧化还原反应外,聚苯胺导电骨架也对PDAAQ的能量密度和循环性产生贡献.充放电曲线则进一步确定了聚苯胺骨架与醌基团协同作用的存在,实验表明,在Li(CF3SO2)2N/PC+DGDM电解液中,基于活性材料PDAAQ的首次放电容量达到221 mAh.g-1,经过40次充放电循环,容量保持率为80%,因此聚1,5-二氨基蒽醌具有较大应用潜力.     

Lamb wave signal selective enhancement by an improved design of meander-coil electromagnetic acoustic transducer

In this paper, we investigate a method of selectively enhancing the single mode signal of a Lamb wave by using a meander-coil electromagnetic acoustic transducer(EMAT) with a new magnetic configuration. We use the Lamb antisymmetric(A0) mode and symmetric(S0) mode as an example for analysis. The analytical expression of the magnitude of the spatial Fourier transform of the Lorentz force generated by different meander coils is used to determine the optimal driving frequency for single mode generation. The numerical calculation is used to characterize the new magnetic configuration and the conventional EMAT magnet. Experimental examinations of each meander coil in combination with the conventional and new magnetic configuration show that the Lamb wave signal can be selectively enhanced by choosing the appropriate driving frequency and coil parameters through using the improved meander-coil EMAT.     

Lorentz Force Electrical Impedance Detection Using Step Frequency Technique

Lorentz force electrical impedance tomography(LFEIT) inherits the merit of high resolution by ultrasound stimulation and the merit of high contrast through electromagnetic field detection. To reduce the instantaneous peak power of the stimulating signal to the transducer, the sinusoidal pulse and step-frequency technique is investigated in LFEIT. The theory of application of step-frequency technique in LFEIT is formulated with the direct demodulation method and the in-phase quadrature demodulation method. Compared with the in-phase quadrature demodulation method, the direct demodulation method has simple experimental setup but could only detect half of the range. Experiments carried out with copper foils confirmed that LFEIT using the step-frequency technique could detect the electrical conductivity variations precisely, which suggests an alternative method of realization of LFEIT.     

基于涡流场有旋分量的磁声电导率重建方法*

感应式磁声成像(MAT-MI)是一种融合磁感应技术和超声断层扫描技术的新型生物电阻抗成像方法,兼具电阻抗功能成像和超声技术高空间分辨率的优点。重建涡流场有旋分量的模值可以避免洛伦兹力的散度在边界处的奇异性、能够获得分辨率更好的电导率图像。本文对涡流场有旋分量的方向进行了分析,对格林函数解的积分项进行化简,提出一种基于涡流场有旋分量模值的电导率重建方法。为了验证新方法的正确性,我们使用电导率具有空间分布的两种模型进行了数值模拟,并使用新方法快速地重建得到高精度的电导率分布。     

ZIF-67衍生的花状Ga掺杂Co3O4用于增强三乙胺传感性能

基于Ga³⁺对Co-MOF(ZIF-67)进行掺杂的策略，衍生制备了具有花状结构的Ga掺杂Co₃O₄气敏材料，并应用于三乙胺(TEA)选择性气敏传感。采用X-射线衍射仪表征了气敏材料的晶体构型，结果表明，Ga离子成功地掺杂到Co₃O₄晶格中。采用扫描电镜以及透射电镜对气敏材料的微观形貌进行表征，结果表明，含有1%Ga掺杂比例的Co₃O₄具有更为疏松多孔的花状结构。采用X-射线光电子能谱以及氮气吸脱附测试对材料的氧空位含量以及比表面积进行表征，结果表明，含有1%Ga掺杂比例的Co₃O₄具有丰富的氧空位含量以及较大的比表面积。最后，采用CGS-8气敏测试分析系统对含有不同Ga掺杂比例的Co₃O₄气敏材料进行三乙胺选择性气敏测试，结果表明，Ga掺杂比例为1%的Co₃O₄气敏传感器显示出最优的TEA气敏响应特性，...     

加装印刷电路板的圆孔阵矩形机壳屏蔽效能

 为评估矩形金属机壳抗外部电磁干扰的能力,建立加装印刷电路板(PCB)有圆孔孔阵矩形机壳的波导等效电路模型,导出其电场屏蔽效能的简洁表达式,提出一种简单高效的新方法,对于没有加装印刷电路板的机壳,该方法的简化结果与现有文献结果完全一致;对于加装PCB的机壳屏蔽效能,该方法计算结果与CST仿真结果良好吻合。结果表明:电场极化方向与孔阵长度方向平行,同其与孔阵长度方向垂直比较,前者屏蔽效能显著优于后者;所考虑的频率范围内,加装PCB可以显著提高机壳的屏蔽效能;正交排列孔阵的屏蔽效能优于交错排列孔阵的屏蔽效能;保持孔阵中孔数目不变,孔间距越大,屏蔽效能越高。