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本文提出了Si3N-Y2O3-La2O3三元系统的亚固(固相线下)相图。在此系统中,形成四个含固溶体的两相区和八个三相区。在富Si3N4区,发现存在一个新相:0.4Y2O3·0.6La2O3·3Si3N4,它于1550℃开始生成,随着温度升高,生成量增大,然而极难获得其纯单相。钇黄长石Y2O3·Si3N4可被La2O3取代形成有限固溶体,其固溶限为55mol%La_2O3,即0.45Y2O3·0.55La2O3·Si3N4。在Y-La-Si-O-N系统中,实验测得,具有同结构的三类含氮稀土硅酸盐,都分别形成连续取代固溶体。它们是:J相连续固溶体——2(Y,La)2O3·Si2N2O,K相连续固溶体——(Y,La)2O3·Si2N2O和H相连续固溶体——(Y,La)10(SiO_4)6N2。 相似文献
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Subsolidus phase relationships in the system Ln2O3-Si3N4-AlN-Al2O3, where Ln represents Nd, Sm and Dy, were summarized, with emphasis on the region involving α-sialon, β-sialon and AlN-polytypoid phases. This information is further used in designing the compatible matrix phases of sialon materials with desirable properties. Examples were provided to illustrate the advantage of such a basic approach to materials design. 相似文献