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21.
Jian Zhang Yongfang Yang Chuanzhuang Zhao Hanying Zhao 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5329-5338
Polystyrene (PS) and poly(methyl methacrylate) (PMMA) mixed polymer brushes on the surface of clay layers were prepared by using in situ free radical polymerization. Free radical initiator molecules with two quaternary ammonium groups at both ends were intercalated into the interlayer spacing of clay layers. The amount of polymer brushes grafted on the surface of clay layers can be controlled by controlling the polymerization time. Thermogravimetric analysis, X‐ray diffraction, and high‐resolution transmission electron microscope results indicated successful preparation of the mixed polymer brushes on the surface of clay layers. The kinetics of the grafting of the monomers was also studied. The mixed polymer brushes on the surface of clay layers were used as compatibilizers in blends of PS and PMMA. In the blends, the intercalated clay particles tend to locate at the interface of two phases reducing the interfacial tension. In the meanwhile, PMMA homopolymer chains tend to intercalate into clay layers. The driving force for the intercalation is the compatibility between homo‐PMMA chains and PMMA brushes on the surface of clay layers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5329–5338, 2007 相似文献
22.
<正>Organic photovoltaics(OPVs),especially the solutionprocessable organic photovoltaic materials and devices,have attracted great attention in recent years because of the advantages of simple device structure,low cost,light weight and flexibility of the organic solar cells(OSCs).The highest power conversion efficiency of the OSCs has been im- 相似文献
23.
Yongfang Yang Lei Zhang Xiaotian Ji Lixin Zhang Hefang Wang Hanying Zhao 《Macromolecular rapid communications》2016,37(18):1520-1526
A facile and versatile method for the synthesis of Janus graphene oxide (GO) nanosheets with different structures is reported. Based on electrostatic assembly, Janus GO nanosheets can be easily functionalized with a template polymer or be defunctionalized by altering the ionic strength. By using this approach, Janus GO nanosheets are prepared successfully with hydrophobic polystyrene chains on one side and hydrophilic poly(2‐(dimethylamino)ethyl methacrylate) chains on the other side.
24.
Xiaoyu Li Cuiqing Zhang Changyuan Hu Linchong Xu Quanhong Hu Shuwang Duo Wenkui Li Yongfang Kang 《Journal of Cluster Science》2017,28(5):2409-2418
A novel Bi2O4@TiO2 heterojunction was constructed by a simple two-step method. The charges migration between Bi2O4 and TiO2 via the heterojunction improves the electron/hole separation efficiency. Furthermore, Bi2O4@TiO2 heterostructures exhibit better adsorption capability for methyl orange molecular due to their higher specific surface area than pure Bi2O4. As a result, Bi2O4@TiO2 hybrids show an improved visible light photocatalytic activity and photostability for the degradation of methyl orange. 相似文献
25.
Tinghai Yan Haijun Bin Yankang Yang Lingwei Xue Zhi-Guo Zhang Yongfang Li 《中国科学:化学(英文版)》2017,60(4):537-544
The medium band gap donor-acceptor(D-A) copolymer J61 based on bi(alkylthio-thienyl)benzodithiophene as donor unit and fluorobenzotriazole as acceptor unit and thiophene as π-bridge has demonstrated excellent photovoltaic performance as donor material in nonfullerene polymer solar cells(PSCs) with narrow bandgap n-type organic semiconductor ITIC as acceptor.For studying the effect of π-bridges on the photovoltaic performance of the D-A copolymers,here we synthesized a new D-A copolymer J61-F based on the same donor and acceptor units as J61 but with furan π-bridges instead of thiophene.J61-F possesses a deeper the highest occupied molecular orbital(HOMO) level at-5.45 eV in comparison with that(-5.32 eV) of J61.The non-fullerene PSCs based on J61-F:ITIC exhibited a maximum power conversion efficiency(PCE) of 8.24%with a higher open-circuit voltage(V_(oc)) of 0.95 V,which is benefitted from the lower-lying HOMO energy level of J61-F donor material.The results indicate that main chain engineering by changing π-bridges is another effective way to tune the electronic energy levels of the conjugated D-A copolymers for the application as donor materials in non-fullerene PSCs. 相似文献
26.
Yongfang Zhong Arindom Joardar Zhongping Gu Young-Gil Park Anthony M. Jacobi 《Experimental Thermal and Fluid Science》2005,29(8):957-970
A new method to assess the condensate drainage behavior of the air-side surface of compact heat exchangers—dynamic dip testing—is introduced. The new method is shown to provide highly repeatable data for real-time drainage. Results from experiments with more than 20 flat-tube and round-tube-and-fin heat exchangers are presented, and the data clearly show geometrical effects such as the impact of the tube type on condensate drainage. By comparing the results from dip testing to wind-tunnel experiments for the same heat exchangers, we find dip testing can serve as a powerful tool for assessing the condensate retention behavior. The coils retaining the most and the least condensate in a steady-state wind-tunnel test, likewise held the most and the least in a dip test. However, different amounts of water are retained on the air-side surface during dip tests and wind-tunnel tests. A model based on gravity, surface tension and drag effects is developed to help understand and predict the drainage behavior of heat exchangers. The new model and experimental approach are useful in screening heat exchangers for condensate retention and for assessing off-cycle drainage behavior. 相似文献
27.
该文研究如下的弱奇异边值问题: (p(x)y')'=f(x, y),0b0g(x), 0≤b0<1, 边值条件为y(0)=A,αy(1)+β y'(1)=γ 或y'(0)=0,αy(1)+βy'(1)=γ (R.K.Pandey 和 Arvind K.Singh 给出了一种求解此问题的二阶有限差分方法[1]. 在再生核空间中讨论方程解的存在性, 给出一种新的迭代算法,这种迭代算法是大范围收敛的. 给出数值算例并与R. K. Pandey 和Arvind K.Singh 给出的方法进行比较说明该文方法的有效性. 相似文献
28.
29.
甲基营养细菌No1甲胺脱氢酶是以色氨酸-色氨酰醌为辅基的一种特殊氧化还原酶.粗酶液经纯化后,其比活力和收得率分别为5.1nmol·g-1和28%.该酶的分子量为67000,等电点为8.3和8.5,组成它的大、小两个亚基的分子量分别为37000和15000.甲胺脱氢酶有较好的耐热性,它能催化包括一级甲胺和二胺在内的底物反应,与甲胺反应的Km值为26.6μmol·L-1,最适pH为8.0.其酶催化反应可被Cu2+抑制.该酶的吸收光谱是,在328nm和426nm呈现两个特征峰 相似文献
30.
Yang Yang Xiaodong Sun Guanqun Han Xi Liu Xiangyu Zhang Yongfang Sun Min Zhang Zhi Cao Yujie Sun 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(31):10754-10759
The sluggish hydrogen oxidation reaction (HOR) under alkaline conditions has hindered the commercialization of hydroxide‐exchange membrane hydrogen fuel cells. A low‐cost Ni/NiO/C catalyst with abundant Ni/NiO interfacial sites was developed as a competent HOR electrocatalyst in alkaline media. Ni/NiO/C exhibits an HOR activity one order of magnitude higher than that of its parent Ni/C counterpart. Moreover, Ni/NiO/C also shows better stability and CO tolerance than commercial Pt/C in alkaline media, which renders it a very promising HOR electrocatalyst for hydrogen fuel cell applications. Density functional theory (DFT) calculations were also performed to shed light on the enhanced HOR performance of Ni/NiO/C; the DFT results indicate that both hydrogen and hydroxide achieve optimal binding energies at the Ni/NiO interface, resulting from the balanced electronic and oxophilic effects at the Ni/NiO interface. 相似文献