Post‐Treatment of CH3NH3PbI3/PbI2 Composite Films with Methylamine to Realize High‐Performance Photoconductor Devices

Organometallic halide perovskites have attracted great research interest as light‐active materials for use in optoelectronics. Here, we report a high‐performance photoconductor based on a methylammonium lead iodide (MAPbI₃) film that was prepared from a methylamine‐treated MAPbI₃/PbI₂ perovskite film. An ultrahigh responsivity of 3.6 A W^?1 and detectivity of 5.4×10¹² Jones were obtained for the film under 0.5 mW cm^?2 white‐light illumination. In addition, under 420 nm light irradiation, the film exhibited its highest responsivity and detectivity of 30 A W^?1 and 2.4×10¹⁴ Jones, respectively. The excellent photo‐response performance results from the improved electronic quality and suppressed nonradiative recombination channels of the treated perovskite thin film.     

茂金属化合物/Zn/BDGE/MAO催化体系合成aPS-b-P(S-co-E)-b-PE嵌段共聚物的研究

采用单茂钛化合物CpTiCl3,有机环氧化合物1,4-丁二醇二缩水甘油基醚(BDGE),金属锌(Zn)及甲基铝氧烷(MAO)为催化体系,通过自由基聚合和配位聚合机理合成无规聚苯乙烯-b-聚(苯乙烯-co-乙烯)-b-聚乙烯(aPS-b-P(S-co-E)-b-PE).探讨了温度、时间、乙烯压力及Al/Ti摩尔比对共聚合的影响.所得嵌段共聚物采用DSC,WAXD,GPC和13C-NMR等手段进行了表征.结果表明该共聚物是苯乙烯/乙烯嵌段共聚物,聚苯乙烯链段是无规的,聚乙烯链段具有结晶性.     

Quantum tunneling effect in entanglement dynamics

Quantum tunneling effect in entanglement dynamics between two coupled particles with separable Gaussian initial state is investigated using entangled trajectory molecular dynamics method in terms of the reduced‐density linear entropy. It has been presented through showing distinguish contribution of single trajectory to linear entropy between classical trajectory and entangled trajectory with same initial state. We find that quantum tunneling effect makes single trajectory's contribution remarkably decrease under quantum dynamics compared to classical dynamics. The nonlocality of quantum entanglement is presented, and the energy transfer between two coupled particles through quantum correlations and classical ones is also discussed in the end. © 2015 Wiley Periodicals, Inc.     

Developing a wireless sensing method for the measurement of gamma radiation dose based on the polymerization of acrylamide

A wireless sensing method for the measurement of gamma radiation dose has been developed based on the fact that gamma rays can initiate the polymerization of acrylamide, which causes an increase in solution viscosity that can be detected with a wireless magnetoelastic sensor. The magnetoelastic sensor is able to wirelessly detect the resonance frequency shifts of a magnetoelastic foil in response to changes in solution viscosity. There is a linear relationship between the resonance frequency shift and gamma radiation dose in the range of 0–50 Gy (under optimal conditions) with a detection limit of 0.25 Gy. This method has the advantage of providing real-time, continuous measurement in situ. The method has been used successfully to determine the gamma radiation dose in real exposure scenarios, with satisfactory results.     

一般加载规律的弹塑性本构关系

将有关文献给出一般加载规律一维全量理论的简单模型推广到一般加载规律的一维增量理论,进而推广到一般加载规律的多维增量理论,在此基础上,建立了推导一般加载规律的多维增量理论的本构关系的一种途径。应用这种途径,从应力空间的加载函数和应变空间的加载函数出发,推导了等向强化材料和被加热的等向强化材料的一般加载规律的弹塑性本构关系的两种表示形式。理论和实例均表明,这种途径对等向强化材料、随动强化材料和理想弹塑性材料均适用。     

The Crucial Role of Charge Accumulation and Spin Polarization in Activating Carbon-Based Catalysts for Electrocatalytic Nitrogen Reduction

Cost-effective carbon-based catalysts are promising for catalyzing the electrochemical N₂ reduction reaction (NRR). However, the activity origin of carbon-based catalysts towards NRR remains unclear, and regularities and rules for the rational design of carbon-based NRR electrocatalysts are still lacking. Based on a combination of theoretical calculations and experimental observations, chalcogen/oxygen group element (O, S, Se, Te) doped carbon materials were systematically evaluated as potential NRR catalysts. Heteroatom-doping-induced charge accumulation facilitates N₂ adsorption on carbon atoms and spin polarization boosts the potential-determining step of the first protonation to form *NNH. Te-doped and Se-doped C catalysts exhibited high intrinsic NRR activity that is superior to most metal-based catalysts. Establishing the correlation between the electronic structure and NRR performance for carbon-based materials paves the pathway for their NRR application.     

交通事故与汽车驾驶员身体素质的相关性研究

本文首先定性描述了汽车驾驶员必须具备的身体素质，然后用多元统计分析方法对测试结果进行统计分析．文中提出的方法可供制定汽车驾驶员职业适应性标准参考．     

非完整系统Hamilton原理的驻值特性

本文论证了非完整系统的Hamilton原理的驻值特性，指出运用Appell－Chetaev条件的Hamilton原理和不应用appell-Chetaev条件的Hamilton原理都是驻值变分原理．并且，讨论了几个有关问题．     

计算光度滴定法同时测定混合弱酸

1引言 将酸碱指示剂置于滴定剂中进行滴定时，可通过吸收光谱同时监测溶液酸度和滴定剂加入量变化，据此将光度法与滴定分析相结合。并结合化学计量学，研究建立了计算光度滴定法同时测定混合弱酸中各组分的新方法。该方法只需要光谱信息就可得到分析结果，消除了电位滴定等方法中易产生误差的一些因素。方法简便、准确的特点，结果满意。     

一种频域合成房间频率响应的人工混响方法

给出了一种频域合成房间频率响应的方法用于卷积法人工混响,基于频域内房间频率响应的后期部分为高斯随机过程的假设,用自回归滑动平均模型为其自协方差函数和功率谱密度进行参数化描述,在对自回归滑动平均模型中的参数求解后,通过逆滤波得到了房间频率响应后期部分,与房间频率响应前期部分组合后经过傅里叶反变换得到完整的房间脉冲响应。仿真结果表明该方法的混响效果与镜像源法接近,明显优于反馈延迟网络法,但其计算复杂度比镜像源法低,便于实时应用。