全文获取类型
收费全文 | 34052篇 |
免费 | 1356篇 |
国内免费 | 368篇 |
专业分类
化学 | 18096篇 |
晶体学 | 445篇 |
力学 | 1592篇 |
综合类 | 2篇 |
数学 | 5789篇 |
物理学 | 9852篇 |
出版年
2024年 | 18篇 |
2023年 | 338篇 |
2022年 | 344篇 |
2021年 | 755篇 |
2020年 | 721篇 |
2019年 | 513篇 |
2018年 | 831篇 |
2017年 | 1013篇 |
2016年 | 1142篇 |
2015年 | 1201篇 |
2014年 | 1579篇 |
2013年 | 2253篇 |
2012年 | 2532篇 |
2011年 | 2812篇 |
2010年 | 2211篇 |
2009年 | 2044篇 |
2008年 | 2274篇 |
2007年 | 2180篇 |
2006年 | 2126篇 |
2005年 | 1654篇 |
2004年 | 1388篇 |
2003年 | 1329篇 |
2002年 | 1017篇 |
2001年 | 932篇 |
2000年 | 622篇 |
1999年 | 698篇 |
1998年 | 336篇 |
1997年 | 155篇 |
1996年 | 165篇 |
1995年 | 112篇 |
1994年 | 60篇 |
1993年 | 44篇 |
1992年 | 53篇 |
1991年 | 44篇 |
1990年 | 33篇 |
1989年 | 45篇 |
1988年 | 23篇 |
1987年 | 22篇 |
1986年 | 6篇 |
1985年 | 42篇 |
1984年 | 14篇 |
1983年 | 19篇 |
1982年 | 22篇 |
1981年 | 13篇 |
1980年 | 9篇 |
1979年 | 7篇 |
1978年 | 7篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1970年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
131.
In this paper we study a double phase problem with an irregular obstacle. The energy functional under consideration is characterized by the fact that both ellipticity and growth switch between a type of polynomial and a type of logarithm, which can be regarded as a borderline case of the double phase functional with -growth. We obtain an optimal global Calderón–Zygmund type estimate for the obstacle problem with double phase in the borderline case. 相似文献
132.
Ye Linglong Li Xueshan Cai Yunhao Ryu Hwa Sook Lu Guangkai Wei Donghui Sun Xiaobo Woo Han Young Tan Songting Sun Yanming 《中国科学:化学(英文版)》2020,63(4):483-489
Benzo[1,2-b:4,5-b′]dithiophene(BDT) has been widely used to construct donor-acceptor(D-A) copolymers in organic solar cells(OSCs). However, benzo[1,2-b:4,5-b′]difuran(BDF), an analogue of BDT, has received less attention than BDT. The photovoltaic performance of BDF copolymers has lagged behind that of BDT copolymers. Here, we designed and synthesized two BDF copolymers, PBF1-C and PBF1-C-2Cl. PBF1-C-2Cl, which is composed of BDF and benzo[1,2-c:4,5-c′]dithiophene-4,8-dione connected by a chlorinated thiophene π-bridge, displays a low-lying highest occupied molecular orbital energy level,which helps in yielding a high open-circuit voltage(V_(oc)) in OSCs. As a result, when blended with Y6, PBF1-C-2Cl-based devices showed a high V_(oc) of 0.83 V and a power conversion efficiency(PCE) of 13.10%. To the best of our knowledge, the PCE of 13.10% is among the highest efficiency values for OSCs based on BDF copolymers. 相似文献
133.
《Arabian Journal of Chemistry》2020,13(4):4895-4903
The CaCu3Mn4O12 (CCMO) ceramic was successfully synthesized through the chemical route. The phase formation was confirmed by the X-ray diffraction pattern. Thermogravimetric (TGA), FT-IR, SEM, TEM, EDX, and XPS analysis were performed for investigation of the thermal behavior, phase identification, microstructural analysis, elemental analysis and oxidation state of the CCMO ceramic respectively. FT-IR spectra confirmed the existence of MnO6 octahedral in body-centered cubic (BCC) complex perovskite oxide that resembles the CaCu3Ti4O12 structure. The average particle size was observed by TEM in the range between 100 and 200 nm. AFM shows the average roughness of the surface was found to be in the range of 30 ± 5 nm. XPS and EDX studies confirmed the purity and oxidation state of the CCMO ceramic. The synthesized material shows very interesting unique Griffith’s phase (TG) results that arise disorder in magnetic susceptibility in which ferromagnetic transition was to be observed in the paramagnetic region. 相似文献
134.
Kim Jong-Hwan Mun Seung Uk Kim Ki-Hwan Park Jeong-Yong Cheon Jin-Sik 《Journal of Radioanalytical and Nuclear Chemistry》2020,324(2):451-457
Journal of Radioanalytical and Nuclear Chemistry - A preliminary study on the fabrication of transmutation fuels was carried out using an injection casting technique. Melts of binary U–Zr, a... 相似文献
135.
Lee Byung-Chul Kim Seon-Byeong Moon Jei-Kwon Park Sang-Yoon 《Journal of Radioanalytical and Nuclear Chemistry》2020,323(1):91-103
Journal of Radioanalytical and Nuclear Chemistry - Complete sets of reaction mechanisms are proposed in the acidic and reductive dissolution of magnetite, nickel ferrite, and chromite using the... 相似文献
136.
Obtaining superhydrophobic surfaces for their application in electronics and flexible wearable devices remains a significant challenge. Most previously reported methods for obtaining superhydrophobic surfaces involve complex and expensive preparation techniques and thus cannot be used for practical applications. Ion-beam irradiation is a simple and promising method for fabricating superhydrophobic nanostructures on large areas at a low cost. Ion-beam irradiation using argon and oxygen gases was used to prepare silica nanorod structures on glass substrates. This study is not just a modification of the surface of nanoparticles, but a change in nanoparticle shape. The nanorods were subsequently treated with perfluorooctyltriethoxysilane to obtain superhydrophobicity. The surface of the silica nanorods exhibited a static water contact angle of 153°, indicating superhydrophobicity. The combination of rough structures of silica nanorods and low surface energy resulted in superhydrophobicity. The surface properties were evaluated in detail using Fourier-transform infrared spectroscopy, field-emission scanning electron microscopy, and X-ray photoelectron spectroscopy. The proposed method is facile, inexpensive, and can be used for the large-scale production of nanorod structures for potential industrial applications. 相似文献
137.
Oh Maengkyo Lee Keunyoung Kim Kwang-Wook Foster Richard I. Lee Chang-Ha 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(6):2495-2501
Journal of Radioanalytical and Nuclear Chemistry - Applicability of uranium peroxide ((UO2)(O2)·4H2O; UO4) precipitation to remove uranium from secondary wastewaters, generated as part of a... 相似文献
138.
Akerke Shakirbay Jeong Sik Choi Dong Chul Kim Hyo Soon Shin Dong Hun Yeo Joon Hyung Lee 《Magnetic resonance in chemistry : MRC》2022,60(9):877-883
In this paper, we evaluated the particle dispersion degree of alumina slurry containing a dispersant by solvent nuclear magnetic resonance (NMR) relaxation and compared it with conventional dispersion evaluation methods such as viscosity, particle size, and sedimentation height measurements. The dispersion of slurry was evaluated via numerical analysis of the transverse relaxation time (T2). The effect of the changes in different parameters of the experiment in terms of milling time, solid loading, and dispersant amount was investigated by NMR relaxation as well as conventional methods. The results of NMR relaxation measurements revealed that T2 correlates well with other dispersion evaluation methods; thus, it is an efficient technique to evaluate the dispersion of alumina slurry, specifically, when studying the effect of the change in milling time and dispersion amount. 相似文献
139.
140.