60K大冷量同轴型脉冲管制冷机的设计与优化

针对红外、超导应用的迫切需求,本文对工作温度为60 K的同轴型脉冲管制冷机进行优化设计。对调相机构的不同组合进行实验研究,获得了该脉冲管制冷机的最佳调相方式;对蓄冷器内丝网的填充方式进行研究,确定了60 K制冷机中蓄冷器丝网的填充方式。制冷机在输入功率250 W,热端温度310 K时,在60 K可以获得5.71 W的冷量,相对卡诺效率达到9.52%。     

[Cu(1,10-phen)(L-Ile)(H2O)]·NO3的合成、结构及其表征

合成了三元混配配合[Cu(1,10-phen)(L-Ile)(H2O)]NO3(1,10-phen=1,10-邻菲咯啉,L-Ile=L-异亮氨酸),并用元素分析、X射线衍射、摩尔电导、红外、紫外等手段对混配配合物进行了表征.晶体结构分析表明配合物晶体的空间群为P21,晶胞参a=1.1835(5)nm,b=0.6775(5)nm,c=1. 3328(5)nm,β=90. 745(5)°,V=1.0686(10)mm3,μ=1. 062mm-1,Dc= 1.411g/cm3,F(000)=470,R=0.0551,Rw=0.0469.分子中Cu(Ⅰ)离子与一个L-Ile(N,O)配体、一个1,10-phen(N,N)配体及H2O(O)配位形成五配位的变形四方锥构型.     

粘性耗散及变物性对多孔介质中对流换热的影响研究

本文通过理论分析、数值模拟与实验研究的综合,研究了粘性耗散及变物性对多孔介质中对流换热的影响。发现：用理想的等热流边界条件可以较好地数值模拟等热流边界条件下多孔介质中的对流换热;在实际可实现的参数条件下,粘性耗散对多孔介质中对流换热的影响不大;油的变物性对换热的影响很大—热流密度越高,对流换热越强。     

H8Si8O12和H8Si7TiO12 团簇的几何构型和电子结构的从头算研究

应用ＨＦ、ＭＰ２和杂化的Ｂ３ＬＹＰ方法,使用３－２１Ｇ基组,对Ｈ２Ｓｉ８Ｏ１２和Ｈ８Ｓｉ７ＴｉＯ１２团簇的几何构型,总能进行了计算,并在Ｂ３ＬＹＰ／３－２１Ｇ的水平上对硅原子的核磁共振化学位移进行了研究,得到的几何构型,以及核磁共振化学位移与实验结果进行了比较,发现吻合得很好。计算了Ｈ８Ｓｉ８Ｏ１２和Ｈ８Ｓｉ７ＴｉＯ１２团簇的Ｍｕｌｌｉｋｅｎ布居数的大小。并对Ｓｉ原子被Ｔｉ原子取代前后的Ｈ８ＳｉＯ１２体系的几何构型、Ｍｕｌｌｉｋｅｎ布居数的变化进行了比较和研究。     

脉冲管制冷机中惯性管的数值模拟研究

本文利用Fluent软件对惯性管进行数值模拟,计算采用二维层流的数值模型,得到惯性管入口处质量流量与压力波之间的相位及惯性管内部的压力波幅值和质量流量幅值的变化,给出不同频率及惯性管尺寸对惯性管入口处压力波与质量流量之间的相位的影响.通过分析并计算得到脉冲管冷端质量流量,进行设计计算.     

Unusual Threshold Anomaly in the ^6Li＋^208Pb System

The angular distributions of elastic scattering for the ^6Li ＋^208Pb system have been measured at several energies around the Coulomb barrier. The parameters of optical potential are extracted by means of a phenomenological optical model analysis. It is found that the real and imaginal potentials show a pronounced energy dependence. The behaviour of the potential at the nearly especially sub-barrier energies in the ^6Li＋^208Pb system is quite different from the results of some previous reports observed in other systems, such as ^19F＋^208Pb and ^16O＋^208Pb. This unusual threshold phenomenon indicates that breakup channel is strongly coupled with the elastic channel and has obvious effects on optical potential.     

Mediator模式下基于语义映射的多本体融合机制研究

针对现有本体融合机制的不足，提出了一种基于Mediator模式的多本体融合机制．首先定义了基于语义相似性的语义映射概念，然后探讨了基于复杂映射的多本体融合机制，并详细介绍了多本体融合的步骤和算法，最后介绍了这种机制在OBSA信息集成系统中的实现．     

激光光热折射光谱法测量毛细管内液体样品的微弱吸收

本工作采用毛细园柱管为样品池，证实在激光束通过毛细管不发生衍射的情况下，可采用激光光热折射光谱进行“在线”检测。我们还提出了一种通过监测第二针孔光栏产生的菲涅尔衍射条纹，提高检测灵敏度的新方法。检测了内径为３００μｍ毛细管内１．８×１０＾－＾１＾６ｍｏｌ的结晶紫，相应的最小吸光度为３×１０＾－＾７。     

A STUDY ON THE STRUCTURE AND PROPERTIES OF POLYBUTYLALDEHYDE FORMED IN LOW TEMPERATURE PLASMA

The polybutylaldehyde obtained by plasma polymerization was investigated by means of IR, X-ray diffraction, GC-MS, elementary analysis, TEM, electron diffraction and contact angle measurements etc. The results showed that the polymer formed in plasma is amorphous crosslinked polymer, and its backbone is made of carbon atoms. The surface energy of the polymer film is independent of the polymerization conditions. No addition reaction has taken place in the carbonyl group of butylaldehyde in the plasma condition. The result of the wettability measurements showed that the polymer film is generally hydrophobic and the surface energy of the film is about 41 dyn/cm, in which the dispersion force contribution is the majority. The electron diffraction proved that some crystal substance, even the single crystals were present in the polymer. X-ray diffraction also proved the presence of crystal and showed about 15% crystaUinity fraction.     

Ce^3＋—Gd^3＋在某些稀土硼酸盐体系中的能量传递

Ce~(3 )离子有一个宽而强的4f-5d吸收带,它能有效地吸收能量。Ce~(3 )离子的荧光寿命非常短,能将能量有效地传递给其它离子起敏化作用。对于Ce~(3 )→Tb~3 ),Ce~(3 )→EU~(3 )和Ce~(2 )→Mn~(3 )的敏化作用已有许多报导,并在灯用发光材料上获得应用。Blasse等提出在Ce~(3 )敏化Tb~(3 )时。用Gd~(3 )作中间体能获得高效发光材料。由于Ce~(3 )的5d能级强烈地依赖于基质,其发射波长可以从紫外到红区,而Gd~(3 )的4f-4f跃迁的激发和发射峰值随基质的变化改变不大,因此将有可能呈现不同的Ce~(3 )-Gd~(3 )的能量转移过程。