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101.
102.
《Analytical letters》2012,45(13):2641-2652
ABSTRACT A simple, rapid and sensitive spectrofluorimetric method for the determination of floctafenine I (FL) in the presence of its degradation product floctafenic acid II (FLA) is developed. The method involves measuring the fluorescence intensity of FL in acetonitrile and in the presence of triethylamine (TEA) at an emission wavelength of 470 nm (excitation at 360 nm) by direct spectrofluorimetry and at an emission 465 nm (excitation 355 nm) by synchronous spectrofluorimetry. At these conditions FLA does not interfere. FLA is determined alone by measuring the fluorescence intensity of its solution in acetonitrile, without addition of TEA, at emission wavelength 460 nm (excitation 355 nm). The proposed method has been used for the assay of FL in tablets, plasma, urine and in mixtures with FLA. It gave highly accurate results for recovery of FL in the presence of its related acid. 相似文献
103.
《Analytical letters》2012,45(3):633-644
ABSTRACT A new spectrofluorimetric method for determination of germanium traces based on its reaction with 1,2,4-Trihydroxyantraquinone, at an apparent pH 8.8 provided by an ammonia/ammonium chloride buffer, in a 80:20(v/v) ethyleneglycol water medium is proposed. The calibration graph is linear over the range 70–725 ng/ml and features a detection limit of 2.5 ng/ml. The effect of potential major interferences has been investigated and the proposed method was successfully applied to the determination of germanium in synthetic samples and industrial concentrates, after extraction with CCl4, in an 9 M HCl medium. 相似文献
104.
《Analytical letters》2012,45(2):333-342
Abstract A flow injection system for the fluorescence determination of low level of ascorbic acid is proposed. The method is based on the rapid oxidation of ascorbic acid by thallium(I). The fluorescence signal at 419 nm is proportional to the amount of ascorbic acid in the range of (1.4–28.0) × 10?7 mole. The relative standard deviations for ten replicate measurements of 1.4 × 10?6 mole of ascorbic acid was 1.3%. The sample rate of 45 ± 5 sample per hour was achieved. The usefulness of the method was tested in the determination of ascorbic acid in fruit juices and vitamin C tablets. 相似文献
105.
本文研究了磷,砷钼杂多酸-罗丹明6G荧光猝灭反应,以P-矩阵计算混合体系中痕量磷和砷。本法灵敏度高,选择性好,简便快速,应用于铜合金中的痕量磷和砷测定,获得满意结果。 相似文献
106.
The reactions of 4-chloro-7-nitrobenzofurazan (NBD-Cl) with glyphosate (GLY) and with its main metabolite, aminomethylphosphonic acid (AMPA), have been studied. The resolution of binary mixtures of glyphosate and aminomethylphosphonic acid has been accomplished by partial least squares (PLS) multivariate calibration. The method of determination is based on the fluorescence emission of the derivatives formed in presence of NBD-Cl at 90 °C, in methanol and in basic medium. The dynamic ranges of the methods were comprised between 10 and 150 μg l−1 for GLY and between 10 and 200 μg l−1 for AMPA, being the detection limits 2 and 5.4 μg l−1 for GLY and AMPA, respectively. The total luminiscence information of the derivatives has been used to optimize the spectral data set to perform the calibration, by analysis of the three-dimensional excitation-emission matrices. A comparison between the predictive ability of the multivariate calibration method, partial least squares type 1 (PLS-1), on two spectral data sets, emission and synchronous spectra, has been performed. The PLS-1 method, applied to the emission spectra, has been selected as optimum. The proposed method has been applied to the simultaneous determination of GLY and AMPA in river water. For concentrations ranging from 100 to 600 μg l−1 of each compound in the samples, analytical recoveries range from 83 to 94% for GLY and from 104 to 120% for AMPA. 相似文献
107.
108.
109.
Spectrofluorimetric determination of aliphatic amines using a new fluorigenic reagent: 2,6-dimethylquinoline-4-(N-succinimidyl)-formate 总被引:1,自引:0,他引:1
A new amino fluorescence probe, 2,6-dimethylquinoline-4-(N-succinimidyl) formate (DMQF-OSu) has been synthesized. Based on the selective reaction of DMQF-OSu with primary and secondary aliphatic amines to yield strong fluorescence, a new spectrofluorimetric method for the determination of total aliphatic amines has been developed. At λex/λem=324.4/416 nm, the linear calibration range was 6×10−8-6×10−6 mol l−1 with the detection limit (3σ) of 1.94×10−10 mol l−1 for the determination of aliphatic amines in weak basic media. The proposed method has been applied to the determination of aliphatic amines in tap water and lake water with the recoveries of 99-104%. Compared with the reported methods, the method presented here is rapid, simple, sensitive and feasible. 相似文献
110.
A novel spectrofluorimetric method using vanillin-8-aminoquinoline (VAQ) as fluorescent probe was developed for the determination of superoxide anion radical (O2−). The new fluorescent probe was characterized by elemental analysis and IR spectra. Under the optimum conditions of the determination, the linear calibration range and the detection limit of the developed method for superoxide anion radical were in the range (0.0-1.0)×10−5 and 2.0×10−8 mol l−1, respectively. The effect of interferences was studied. The proposed method was applied to determine the generation rate of superoxide anion radical in the course of aging in red sage successfully. 相似文献