Hilbert空间中的紧K-框架

K-框架是框架的一种推广.本文在Hilbert空间将紧框架推广到K-框架上,引入紧K-框架的概念.通过紧K-框架的算子K和合成算子给出紧K-框架的算子刻画,并利用紧K-框架的算子K给出紧K-框架成为紧框架的一个充要条件.还讨论紧K-框架的构造以及两个紧K-框架集的包含与涉及的算子K的相互关系.     

光控CRISPR技术的研究进展

成簇规则间隔短回文重复序列和成簇规则间隔短回文重复序列相关(CRISPR-Cas)系统提供了用于可编程基因组编辑的多功能工具. CRISPR与光遗传学及光化学生物学技术的结合产生了很多新的成果. 光激活的CRISPR-Cas系统能够在空间和时间上更好地调控RNA引导的核酸酶的活性. 近年来, 科学家结合CRISPR和多种光学技术, 开发出了一系列光激活的CRISPR工具. 这些工具让研究人员能够在空间、 时间和基因组坐标上进行高分辨率的生命活动研究. 本文概述了CRISPR系统、 基因编辑技术、 光遗传学和光化学生物学的研究进展, 并对光诱导的CRISPR技术的发展进行了展望.     

新型纳米金修饰玻碳电极对水杨酸的电催化氧化

借助"种子媒介纳米金属生长法"制备新型的纳米金修饰玻碳电极,应用场发射扫描电镜、紫外-可见光谱分析和电化学方法等,研究该电极的表面形貌及其电化学性能.结果表明,该修饰电极对水杨酸的电化学氧化有明显的电催化作用,电极响应灵敏度是裸玻碳电极表面的1.8倍.其氧化峰电流与水杨酸浓度在5.0×10-7~8.0×10-5mol/L范围内呈良好的线性关系,可用于水中痕量水杨酸的检测.     

纳米无机巨簇分子的红外、拉曼光谱研究

本文报道了用红外、拉曼光谱对四类纳米无机巨簇分子进行了比较研究。     

Synthesis and structural characterization of a novel dimolybdenum(Ⅰ) compound with mixed-tribridging ligands:[Bu_4N][Mo_2(μ-SPh)_2(μ-Cl)(CO)_6]

A novel mixed-trib ridged dimolybdenum(Ⅰ) compound [Bu4N][Mo2(n-SPh)2(u-Cl)(CO)6] (1) has been synthesized from the reaction of Mo2 (CO)8 (SPh)2 with ButNCl.Compound 1 was characterized by IR,UV-Vis and 1H,13C,95Mo NMR spectroscopic analyses.The electrochemical behavior was measured by cyclic voltammetry,indicating a quasi-reversible two-electron transfer in one step.The crystal structure determined by X-ray crystallography shows that 1 contains a [Mo2(u-S)2(u-Cl)]- core with a planar Mo2S2 unit and a Cl bridge.The Mo-Mo distance is 0.28709(7) nm,and the Mo-Cl-Mo angle is 66.44(4).A newface-sharing bioctahedral structure is discussed.     

Optical band gap of zinc nitride films prepared by reactive rf magnetron sputtering

Polycrystalline Zn₃N₂ films are prepared on Si and quartz glass substrates by RF magnetron sputtering at room temperature. The structural and optical properties are studied by X‐ray diffraction and double beam spectrophotometer, respectively. X‐ray diffraction indicates that the Zn₃N₂ films deposited on Si and quartz glass substrates both have a preferred orientation in (321) and (442), also are cubic in structure with the lattice constant a=0.9847 and 0.9783 nm, respectively. The absorption coefficients as well as the film thickness are calculated from the transmission spectra, and their dependence on photon energy is examined to determine the optical band gap. Zn₃N₂ is determined to be an indirect‐gap semiconductor with the band gap of 2.11(2) eV. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

An MP2 study on pre-reactive complexes (CH_2)_2O … XY (X,Y = H,F,Cl,Br,I)

The structures, energies, atomic chaiges and IR spectra of complexes (CH2)2O…XY (X, Y = H, F, Cl, Br, and I) have been examined by means of ab initio molecular orbital theory at the second-order level of Moller-Plesset perturbation correction. It is found that the hydrogen bond O…H-X is non-linear. The attraction between X and the H atoms in oxirane ring causes O…H-X bond bending. The hydrogen bond slighdy weakens the bond strength of C-O, and leads the bending and stretching mode of IR to shift to the red. The calculation results show that there is no evidence of a significant extent of proton transfer to give (CH2)2OH …X- in the isolated complexes.     

大口径相机主镜/次镜结构动力减振的研究

本文对大口径相机结构次镜相对主镜的振动进行了分析,并提出了次镜动力减振的减振方式,且对动力减振系统进行了分析。最后对某相机的动力减振结构进行了优化设计,并计算了一定冲击激励下原结构与带动力减振结构的响应时间历程。结果表明动力减振具有一定的减振效果,对相机高成象质量的保证具有一定的应用意义.     

外遮光罩工程分析及其结构动力优化

本文利用有限元方法对某遮光罩进行了静力、动力及热应力分析,提出了改善遮光罩瓶颈环节的有力措施-结构优化设计的最大刚度化。本文以结构基频的最高化为优化目标函数,对遮光罩进行了动力优化设计,设计结果对遮光罩的基频有一定的提高,并降低了遮光罩在发射升空过程中的最大冲击应力。     

Comparisons of recollements and tilting modules

The purpose of this paper is to provide the TTF-theories and investigate the comparisons of recollements(one-sided recollements) both induced by the BB-tilting modules.