荧光素二聚体荧光探针测定卡那霉素的研究

基于卡那霉素对荧光素二聚体具有良好的荧光增强作用,以现场形成的荧光素二聚体作为荧光探针,建立了卡那霉素定量分析的新方法。在碱性条件下（pH=9.0）,当溴化十六烷基三甲基铵（CTAB）浓度为0.4-1.0 mmol/L时,荧光素（FL）在CTAB作用下形成弱荧光现场二聚体,导致荧光猝灭。加入卡那霉素,体系荧光明显增强,且荧光强度与卡那霉素浓度呈良好的线性关系。在优化条件下,卡那霉素的测定线性范围为2.5×10^-3 - 0.1 g/L,检出限（3σ/K）为1.4×10^-4g/L。用于实际样品分析,测定回收率为101%-116%,RSD为1.9%-2.6%。     

树脂法水处理进展(上)

工业应用离子交换树脂是从水处理开始的。现在,在树脂的应用中水处理仍是最大的领域,其用量占树脂年耗的90％以上。随着科学技术的进步,各行各业对水质的要求不断提高,因此,水处理用的新型树脂不断出现,应用范围也日益扩大,工艺流程及再生方法也不断地改进。现仅就树脂法水处理的几个方面的进展作一评述。     

Investigation of neutron induced reactions on ^23Na by using Talys1.4

The neutron induced reactions on ^23Na are investigated by using the Talys1.4 program. The calculated results for the ^23Na（n, 2n）22Na reaction are found to agree with the experimental results. The cross sections of the residues of the（n, n）,（n, γ）,（n, p）, and（n, np） channels in the reactions are presented, and at the same time, the neutron induced reactions on22 Ne are also investigated.     

Investigation of neutron induced reactions on ~(23)Na by using Talys 1.4

The neutron induced reactions on23 Na are investigated by using the Talys1.4 program. The calculated results for the23Na(n, 2n)22Na reaction are found to agree with the experimental results. The cross sections of the residues of the(n, n),(n, γ),(n, p), and(n, np) channels in the reactions are presented, and at the same time, the neutron induced reactions on22 Ne are also investigated.     

氟橡胶O型圈低压气体密封黏滞摩擦特性实验

开展了低气体密封压力条件下的氟橡胶O型圈低压黏滞摩擦特性实验研究.对氟橡胶O型圈与不锈钢2Cr13摩擦副的摩擦力的时变曲线进行测量,重点分析了密封压力、O型圈压缩率和滑动速度对O型圈黏滞摩擦力的影响规律.结果表明:随压缩率的增加,氟橡胶O型圈摩擦力增加,并呈现出明显的回弹特征,即滞后摩擦力增加且释放时间增加;随着密封压力的增加,其所受最大静摩擦力、滑动摩擦力与滞后摩擦力均呈现非线性变化,且存在一极大值;减小往复运动速度,摩擦力数值增大,但摩擦力极值对应的密封压力值变小.     

New experimental measurement of natSe(n, γ) cross section between 1 eV to 1 keV at the CSNS Back-n facility

The ⁷⁴Se is one of 35 p-nuclei, and ⁸²Se is a r-process only nucleus, and their (n, γ) cross sections are vital input parameters for nuclear astrophysics reaction network calculations. The neutron capture cross section in the resonance range of isotopes and even natural selenium samples has not been measured. Prompt γ-rays originating from neutron-induced capture events were detected by four C₆D₆ liquid scintillator detectors at the Back-n facility of China Spallation Neutron Source (CSNS). The pulse height weighting technique (PHWT) was used to analyze the data in the 1 eV to 100 keV region. The deduced neutron capture cross section was compared with ENDF/B-VIII.0, JEFF-3.2, and JENDL-4.0, and some differences were found. Resonance parameters were extracted by the R-matrix code SAMMY in the 1 eV-1 keV region. All the cross sections of ^natSe and resonance parameters are given in the datasets. The datasets are openly available at http://www.doi.org/10.11922/sciencedb.j00113.00019.     

A discrete algorithm for complex frequency-domain convolutions

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基于强制进化随机游走算法的质量交换网络综合

针对现有质量交换网络优化方法存在的不足, 提出一种适用于质量交换网络综合的强制进化随机游走算法。通过随机增大或减小质量交换器的传质负荷、分流比以及贫流股的流量, 并设置最小阈值实现网络连续和整型变量的同步优化; 通过以较小概率接受差解, 增强结构变异, 使算法更好地兼顾质量交换网络的全局和局部搜索。在2个质量交换网络实例中的应用表明, 优化结果优于文献最优结果, 算法保持了个体的独立进化且具有良好的全局和局部搜索能力。     

聚乙烯的表面光接枝改性研究进展

综述了紫外光引发接枝改性聚乙烯表面的研究进展,包括光接枝聚合机理,改性方法,接枝链的结构和形态,影响因素等。     

荧光光度法测定土壤岩石中有机物的发光强度判断地下石油分布干扰因素的探讨

１引言 用荧光光度法测定地表面中有机物的总发光强度来判断地下石油的分布情况。作者通过对大西北某沙漠地区２０００多个样品（１．８ｍ深处的岩石或土壤）的荧光光谱分析。着重探讨了严重干扰样品荧光光谱测定的诸种因素,并寻找了消除其干扰因素的方法。本方法采用石油醚处理样品,固定激发波长为２６５．０ｎｍ,荧光扫描范围：２３３．０ｎｍ至５００．０ ｎｍ。２实验部分２．１主要仪器和试剂ＲＦ－５４０荧光分光光度计（日本岛津公司）。经３．２（１）处理后的石油醚,分析纯。２．２样品处理取某沙漠地下 １．８ ｍ深处的土壤或…