排序方式: 共有49条查询结果,搜索用时 109 毫秒
11.
流动注射在线富集火焰原子吸收测定痕量砷 总被引:1,自引:0,他引:1
本文在比较各种柱材料对砷的富集效果的基础上,选用活性氧化铝作柱材料的进行在线富集流动注射火焰原子吸收测定砷的研究。实验溶液含砷1.25μg/ml,PH=6,当流速为16ml/min时,富集倍数为进样1分钟富集48倍;当峰高为0.1吸光度时,宽仅为1.5秒。该方法用于环境水样中砷一的测定,结果较满意。 相似文献
12.
烷基膦酸类萃取剂与喹啉类萃取剂N_(601)协萃锗(Ⅳ)的研究 总被引:1,自引:0,他引:1
研究了盐析剂浓度和水相pH值对分配比D的影响。研究了烷基膦酸萃取剂P507和喹啉类萃取剂N601协萃锗的机理,并对萃取平衡常数和热效应进行了估算。 相似文献
13.
1 INTRODUCTION Owing to their biological activities and chemical/industrial versalities, considerable attention has been continually attracted to metal-hydrazine complexes. For instance, Schiff base hydrazine and its analogues have been well studied in order to better understand the action mechanism of Vitamin B6-containing enzymes[1~3]. Six-coordinated copper(Ⅱ) complexes are of considerable interest, mainly due to their coordination geometry and spectroscopic properties[4]. Due to th… 相似文献
14.
超声雾化空气—氩ICP—AES的检出限 总被引:3,自引:1,他引:2
医用超声雾化强器改装后的ICP-AES进样装置,在高频功率3.8×0.80kW载气流量0.80L.min^-1,观察高度1.0cm的折衷条件下,测定了28种元素的检出限,15种稀土元素中Dy,Eu,Ho,Y和Yb的检出限低于1μg.L^-1。 相似文献
15.
16.
A novel compound, {[Y(HPIDC)(OX)1/2(H2O)]·2H2O}n (1, H3PIDC = 2-(pyridin-4- yl)-1H-imidazole-4,5-dicarboxylic acid, H2OX = oxalic acid), has been synthesized under hydrothermal conditions and characterized by thermal analysis (TGA), powder X-ray diffraction (PXRD), and single-crystal X-ray diffraction. Complex 1 crystallizes in monoclinic space group P21/c with a = 8.342(8), b = 14.61(1), c = 11.487(1), β = 90.78(9)°, V = 1400.4(2)3, Z = 4, C11H11N3O9Y, Mr = 418.14, Dc = 1.983 g/cm3, F(000) = 836, Rint = 0.0509, T = 293(2) K, μ = 4.240 mm-1, the final R = 0.0477 and wR = 0.1125 for 2770 observed reflections with I > 2σ(I). Compound 1 exhibits a 3D framework and generates the 1D open channels filled with free water molecules. The structure of 1 can be rationalized as a diamondoid network when the atom yttrium is regarded as a 4-connected node linking four surrounding yttrium atoms. The luminescent property of compound 1 is also investigated. 相似文献
17.
18.
从师生互动、生生互动、与人工教学制品互动3个维度调查了目前高中化学教学互动现状,分析了存在的主要问题及其原因,提出了充分认识教学互动功能、优化教学互动策略、提升教学互动技能、完善评价方式等解决问题的对策。 相似文献
19.
本文描述了两个具有相似阴离子骨架的化合物,犤Na2(H2O)10(NH4)4犦犤V10O28犦(1)和犤Na2(H2O)10(NH4)4犦犤V9MoO28犦(2)。化合物1的阴离子是一个常见的钒十骨架,而化合物2与化合物1是同晶异质体,化合物2的阴离子是混有一个钼原子的钒十骨架。X-射线晶体结构测定表明,这两个化合物均属于三斜晶系,P1珔空间群。晶胞参数分别为化合物1:a=0.86024(4)nm,b=1.04561(5)nm,c=1.12828(4)nm,α=68.833(1)°,β=87.158(1)°,γ=67.065(1)°;化合物2:a=0.86511(3)nm,b=1.04549(5)nm,c=1.12446(5)nm,α=69.071(1)°,β=87.145(1)°,γ=66.982(1)°。 相似文献
20.
1INTRODUCTIONThepolyoxomolybdateshavebeenwidelyresearchedinmanyfieldssuchascatalysis,biology,medicineandmaterialsciencebecauseoftheirrichphysicalandchemicalproperties[1].Thoughmanypolyoxomolybdateshavebeenreported[2],furtherresearchisstillnecessaryforthestudyof搑eduction-oxidation-reconstitution?self-assemblyprocesses[3,4].Polyoxomolybdatesarenormallybuiltupundersuitableconditionsbyafewbuildingblockssuchas{Mo2},{Mo8}and{Mo9}inself-assemblyway[5,6].The{Mo18}clustershaveseveralstructuralty… 相似文献