Synthesis and gelation behaviors of five new dimeric cholesteryl derivatives

Five new diacid amides of di-cholesteryl L-glycinates were designed and prepared.The compounds with linkers containing 0,1, 2,3,or 4 methylene units are denoted as 1,2,3,4,and 5,respectively.Their gelation behaviors in 25 solvents were tested as novel low-molecular-mass organic gelators(LMOGs).It was shown that the length of the linker connecting the two-cholesteryl residues in a gelator plays a crucial role in the gelation behavior of the compound.1 gels 11 of the 25 solvents tested at a concentration lowe...     

CHCl3电子吸附速率常数的离子迁移谱

利用电晕放电离子迁移谱, 使用高纯氮气作为载气和迁移气体, 研究了电场强度在200～500 V/cm变化时CHCl₃的解离电子吸附速率常数, 得到样品所对应的电子吸附速率常数为1.26×10^-8～8.24×10^-9 cm³/(molecules s)．利用该装置测量了固定电场下,样品的电子吸附速率常数与样品浓度之间的关系．此外利用所获得的离子迁移谱图得到了不同电场强度下Cl^-与CHCl₃之间的离子分子反应速率常数.     

非单特征值的广义分歧定理

讨论了抽象算子方程F(λ,u)=0的局部分歧问题,其中F:R×X→Y是一个C2微分映射,λ是参数,X,Y为Banach空间.利用Lyapunov-Schmidt约化过程及偏导算子Fu(λ*,0)的有界线性广义逆,在dim N(Fu(λ*,0))≥codim R(Fu(λ*,0))=1的条件下,证明了一个广义跨越式分歧定理.当参数空间的维数等于值域余维数时,应用同样的方法又得到了多参数方程的抽象分歧定理.     

阴离子分散剂对酸化膨润土流变性的影响

研究了阴离子分散剂聚丙烯酸钠对质量分数为10%的酸化膨润土分散体系流变性的影响. 结果表明, 添加0.4%分散剂的分散体系的剪切应力、表观黏度和屈服应力最低. 其它体系流体均表现为从假塑型到胀流型流体的转变, 而含0.4%分散剂的体系始终表现为胀流型流体. 采用Herschel-Bulkley模型对各体系的流变曲线进行了拟合, 得到较好的拟合曲线, 同时探讨了酸化膨润土分散体系的流变机理.     

机场任务指派问题的优化方案研究

本文研究了机场任务指派问题,该问题是指将具有特殊属性的任务指派给有限数量的班次。由于机场任务和班次属性的多样性,机场任务指派问题是一个复杂的组合优化问题,属于NP-完全问题。本文以任务完成产生的效益总和最大化为目标建立数学优化模型,提出有效不等式,应用CPLEX软件对实际数据进行求解,结果表明,CPLEX可以在较短时间内对一定规模的算例求得最优解。同时对影响目标函数的四个因素:任务数量、班次数量、班次工作时长和任务属性分别进行分析,通过实际算例测试对比,得出具有指导意义的结论,即根据机场特征分别调整四个因素不仅能够提高机场资源的有效利用率,而且能够提高机场的运行效率和服务水平。     

Two New Diterpene Alkaloids from the Roots of Spiraea japonica var. Acuta

Spiraea japonica L. (Rosaceae) is widely distributed in Yunnan Provence, P. R. China. Previous chemical investigations on S. japonica and its varieties have led to the report of 7 new atisane-type diterpenoids and 38 new diterpene alkaloids of atisine- and hetisine-type1-11. This paper describes the isolation and structure elucidation of two new diterpene alkaloids named spiratines A and B (1-2). Their structures were elucidated on the basis of 1D and 2D NMR experiments (HMQC, HMBC, 1…     

Crystal and Molecular Structure of N-(1-Ethoxycarbonyl- ethyl)1-Ethoxycarbonylmethyl-3-ethyl-1,2,3,4- tetrahydro-4-oxo-1,3,2-benzodiazaphosphorin- 2-carboxamide 2-Oxide

1 INTRODUCTIONOrganophosphorus compounds are ubiquitous in nature and they have broad applications in the fields of agriculture and medicine. During the past two decades, (-ketophosphonates and their derivatives have attracted considerable attention because these compounds are endowed with special physical, chemical and pharmacological properties due to the proximity of the carbonyl and the phosphoryl groups[1～6]. For example, it is well known that phosphonoformic acid (PFA) is effectiv…     

Two New Steroidal Saponins from Diuranthera inarticulata

There are only three species in the genus Diuranthera (Liliaceae), which is endemic in the southwest of China1. Four steroidal saponins, diuranthosides A-C and chloromalo-side A were isolated from the fresh roots of D. major. This paper deals with the structure elucidation of two new steroidal saponins, diuranthosides D and E, which were isolated from the methanolic extract of whole plant of D. inarticulata Wang et K. Y. Lang.Diuranthoside D (1), [(]-38 (c 0.08, pyridine), afforded galac…     

Study on Phase Equilibrium Properties for CO_(2+) Cosolvent Binary Systems

Recently, the application of supercritical fluid technology is very interested, and it is applied in many areas for its special properties. The performance of supercritical fluid (SCF) as a solvent can be greatly affected by addition of an entrainer to the system. An entrainer can be added to a supercritical fluid to enhance its solvent strength and/or selectivity. Critical point data for these dilute supercritical fluid-cosolvent systems are imperative for the design of efficient separation …