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11.
Since a few years, the interest in negatively-curved fused polycyclic aromatic hydrocarbons (PAHs) has significantly increased. Recently, the first chiral negatively-curved PAH with the topology of a monkey saddle was introduced. Herein the synthesis of its triaza congener is reported. The influence of this CH↔N exchange on photophysical and electrochemical properties is studied as well as the isomerization process of the enantiomers. The aza analogue has a significantly higher inversion barrier, which makes it easier to handle at room temperature. All experimental results are underpinned by theoretical DFT calculations.  相似文献   
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13.
卓峻峭  夏爽 《化学教育》2022,43(1):115-117
介绍了利用曲率定理计算富勒烯结构的方法,证明了富勒烯结构中五元环数恒为12,与传统的欧拉定理法进行了对比,凸显了曲率定理法在研究多面体结构时直观形象的特点,强调了数学方法对解决化学问题和认识化学模型的重要性。  相似文献   
14.
CR geometry studies the boundary of pseudo-convex manifolds.By concentrating on a choice of a contact form,the local geometry bears strong resemblence to conformal geometry.This paper deals with the role conformally invariant operators such as the Paneitz operator plays in the CR geometry in dimension three.While the sign of this operator is important in the embedding problem,the kernel of this operator is also closely connected with the stability of CR structures.The positivity of the CR-mass under the natural sign conditions of the Paneitz operator and the CR Yamabe operator is discussed.The CR positive mass theorem has a consequence for the existence of minimizer of the CR Yamabe problem.The pseudo-Einstein condition studied by Lee has a natural analogue in this dimension,and it is closely connected with the pluriharmonic functions.The author discusses the introduction of new conformally covariant operator P-prime and its associated Q-prime curvature and gives another natural way to find a canonical contact form among the class of pseudo-Einstein contact forms.Finally,an isoperimetric constant determined by the Q-prime curvature integral is discussed.  相似文献   
15.
In the present paper, a two-component Camassa-Holm (2CH) system with vorticity is studied as a geodesic flow on a suitable Lie group. The paper aims at presenting various details of the geometric formalism and a major result is the computation of the sectional curvature K of the underlying configuration manifold. As a further result, we show that there are directions for which K is strictly positive and bounded away from zero.  相似文献   
16.
《Mathematische Nachrichten》2017,290(16):2708-2713
Recently, Andrews and Clutterbuck [1] gave a new proof of the optimal lower eigenvalue bound on manifolds via modulus of continuity for solutions of the heat equation. In this short note, we give an alternative proof of Theorem 2 in [1]. More precisely, following Ni's method (Section 6 of [5]), we give an elliptic proof of this theorem.  相似文献   
17.
We prove that on a smooth metric measure space with m ?Bakry–Émery curvature bounded from below by ?(m ? 1)K for some constant K ≥0 (i.e., Ricf ,m ≥?(m ? 1)K ), the following degenerate elliptic equation (0.1) has no nonconstant positive solution when p > 1 and constant λ f ,p satisfies Our approach is based on the local Sobolev inequality and the Moser's iterative technique and is different from Cheng‐Yau's method, which was used by Wang‐Zhu in 2012 to derive a same Liouville theorem when 1 < p ≤2, Ricf ,m ≥?(m ? 1)K and the sectional curvature is bounded from below. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
18.
We prove some sharp isoperimetric type inequalities in warped product manifolds, or more generally, multiply warped product manifolds. We also relate them to inequalities involving the higher order mean-curvature integrals. Applications include some sharp eigenvalue estimates, Pólya-Szegö inequality, Faber-Krahn inequality, Sobolev inequality and some sharp geometric inequalities in some warped product spaces.  相似文献   
19.
气相爆轰波在90矩形弯管中传播时胞格结构的演化   总被引:2,自引:0,他引:2  
利用烟迹技术实验获得气相爆轰波在90矩形弯管中传播时留下的胞格图案,详细分析了胞格结构在矩形弯管中的演化规律。同时分析了90矩形弯管的曲率半径和预混气体初始压力对胞格结构演化的影响。实验所采用的预混气体初始压力为33.3、26.7、24.0、16.0、10.7 kPa,90矩形弯管的曲率半径分别为100、50 mm。研究爆轰波胞格结构在弯管中的演化过程有助于深入了解气相爆轰波绕射机理和石油天然气等管道设计。  相似文献   
20.
The paper proposes a numerical-analytic approach to studying the free vibrations of orthotropic shallow shells with double curvature and rectangular planform. The approach is based on the spline-approximation of unknown functions. Calculations are carried out for different types of boundary conditions. The influence of the mid-surface curvature and variable thickness on the behavior of dynamic characteristics is studied __________ Translated from Prikladnaya Mekhanika, Vol. 43, No. 6, pp. 102–115, June 2007.  相似文献   
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