首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   15233篇
  免费   794篇
  国内免费   3840篇
化学   14081篇
晶体学   290篇
力学   197篇
综合类   129篇
数学   2885篇
物理学   2285篇
  2023年   167篇
  2022年   197篇
  2021年   312篇
  2020年   344篇
  2019年   365篇
  2018年   313篇
  2017年   379篇
  2016年   412篇
  2015年   359篇
  2014年   511篇
  2013年   1139篇
  2012年   754篇
  2011年   948篇
  2010年   804篇
  2009年   1058篇
  2008年   1071篇
  2007年   1083篇
  2006年   947篇
  2005年   878篇
  2004年   852篇
  2003年   714篇
  2002年   701篇
  2001年   583篇
  2000年   511篇
  1999年   411篇
  1998年   378篇
  1997年   359篇
  1996年   309篇
  1995年   307篇
  1994年   304篇
  1993年   285篇
  1992年   276篇
  1991年   209篇
  1990年   190篇
  1989年   219篇
  1988年   176篇
  1987年   176篇
  1986年   179篇
  1985年   147篇
  1984年   146篇
  1983年   93篇
  1982年   46篇
  1981年   50篇
  1980年   34篇
  1979年   36篇
  1978年   32篇
  1977年   19篇
  1976年   22篇
  1975年   14篇
  1974年   21篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
11.
Given a graph Γ, we construct a simple, convex polytope, dubbed graph-associahedra, whose face poset is based on the connected subgraphs of Γ. This provides a natural generalization of the Stasheff associahedron and the Bott-Taubes cyclohedron. Moreover, we show that for any simplicial Coxeter system, the minimal blow-ups of its associated Coxeter complex has a tiling by graph-associahedra. The geometric and combinatorial properties of the complex as well as of the polyhedra are given. These spaces are natural generalizations of the Deligne-Knudsen-Mumford compactification of the real moduli space of curves.  相似文献   
12.
在化学发光分析中,常常要用到碱性条件下鲁米诺与过氧化氢的反应系统,通过催化剂辣根过氧化物酶使反应顺利进行。如果再加入适当的增强剂,则灵敏度提高且发光时间延长,可改善测定的重现性。实验证明,对位酚类衍生物,如:对叔丁基苯酚,对甲苯酚的发光增强作用明显,其发光效率可上升几十倍,发光时间也获得有效延长。  相似文献   
13.
Summary We give a syntactic characterization of (finitary) theories whose categories of models are closed under the formation of connected limits (respectively the formation of pullbacks and substructures) in the category of all structures. They are also those theories whose consistent extensions by new atomic facts admit in each component an initial structure (respectively an initial term structure), and also thoseT for whichM(T) is locally finitely multi-presentable in a canonical way. We also show that these two properties of theories are nonuniform.  相似文献   
14.
Let G=(V(G),E(G)) be a graph. A (n,G, λ)‐GD is a partition of the edges of λKn into subgraphs (G‐blocks), each of which is isomorphic to G. The (n,G,λ)‐GD is named as graph design for G or G‐decomposition. The large set of (n,G,λ)‐GD is denoted by (n,G,λ)‐LGD. In this work, we obtain the existence spectrum of (n,P3,λ)‐LGD. © 2002 Wiley Periodicals, Inc. J Combin Designs 10: 151–159, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/jcd.10008  相似文献   
15.
一种新型可调谐锁模光纤激光器   总被引:2,自引:1,他引:1  
利用法布里-珀罗腔的激光二极管作为调制器件,实现环形腔光纤激光器的主动锁模。并利用法布里-珀罗腔的激光二极管的多纵模特性,把激光二极管当作一梳状滤波器,通过偏振控制器来调整入射到激光二极管内光的偏振态,同时均衡腔内增益,得到波长大范围可调谐的锁模激光,其脉冲宽度约为48ps,脉冲重复速率2GHz。  相似文献   
16.
Novel self-assembled monolayers were obtained on silver using 4,7-diazaheptyl-trimethoxy-silane (SiN) and vinyl-trialkoxy-silane (SiVA, where the alkyl group is 3,6,9,12,15,18,21,24,27,30,33,36,39,42,45,48,51,54,57,60-eicozaoxa- hexaheptaconan). It was shown that thus modified metal surface was protected against electrooxidation. A densely packed monolayer remained stable and did not desorb from the Ag electrode on the potential cycling. The structure of SiN and SiVA as well as their complexes with Li+ cations were calculated and visualised by the AM1d and PM5 semi-empirical methods.  相似文献   
17.
1 INTRODUCTION The self-assembly of organic-inorganic hybrid ma- terials is an intriguing area, which is yielding new generations of supramolecular architectures[1, 2]. Coor- dination by transition metals with multifunctional ligands is one of the main design principles. As a rigid multi-dentate ligand, 5-aminoisophthalic acid (AIP) has received considerable attention owing to the variety of bridging abilities[3~8]. It can engage in three types of intermolecular interactions: (1) M-L b…  相似文献   
18.
A guest-host nanocomposite based on electroconducting polyaniline doped with 12-phosphotungstic acid and V2O5 as well as its bifunctional analog containing not more than 5 mass% nanosized platinum were obtained. A study was carried out on the structure of these nanocomposites, their redox characteristics, and electrocatalytic activity in the reduction of oxygen. These nanocomposites were found to display catalytic properties in the electrochemical reduction of oxygen, while the presence of even a slight amount of nanosized platinum in the bifunctional composite leads to a significant increase in its electrocatalytic activity. __________ Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 5, pp. 307–314, September–October, 2007.  相似文献   
19.
A fiber-optic chemical sensor (FOCS) for detection of nitrogen dioxide (NO2) molecules is reported. The FOCS presents an optropode structure because of the transmission properties of the sensitive material. The NO2 FOCS is activated by using the semiconductor polymer: regioregular head-to-tail poly(3-octylthiophene-2,5-diyl). The operation wavelength of the sensor is 543.5 nm such that a simple LED and detector can be used for the design of this device. The sensor response decreases after each exposure, demonstrating the reduction in sensitivity as well as irreversibility lower than 5%. However, its properties such as rapid response, high selectivity, high sensitivity (0.43 ± 0.01 muW/ppm), hygroscopic properties, and its operation at room temperature make this kind of FOCS a good alternative for NO2 toxic gas detection.  相似文献   
20.
We show the exponential decay of eigenfunctions of second-order geometric many-body type Hamiltonians at non-threshold energies. Moreover, in the case of first-order and small second-order perturbations we show that there are no eigenfunctions with positive energy.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号