Cochran's statistical theorem for outer inverses of matrices and matrix quadratic forms

We extend the matrix version of Cochran's statistical theorem to outer inverses of a matrix. As applications, we investigate the Wishartness and independence of matrix quadratic forms for Kronecker product covariance structures.     

On the Solvability of the Multidimensional Version of the First Darboux Problem for a Model Second-Order Degenerating Hyperbolic Equation

A multidimensional version of the first Darboux problem is considered for a model second-order degenerating hyperbolic equation. Using the technique of functional spaces with a negative norm, the correct formulation of this problem in the Sobolev weighted space is proved.     

Gradient- and Sensitivity-Enhanced TOCSY Experiments

A pulsed field gradient version of the sensitivity-enhanced 2D TOCSY experiment is proposed which yields high-quality spectra with improved sensitivity and a minimum of two scans pert₁increment. For rapid acquisition of 1D TOCSY spectra, the 1D DPFGSE–TOCSY experiment was modified to include phase-encoded multiple-selective excitation followed by a simple spectral editing. Combination of these two building blocks is used in a sensitivity-enhanced 2D analog of the 3D TOCSY–TOCSY experiment which provides an efficient tool for resolving severely overlapped signals of oligomers in short experimental time.     

On a Multivalued Version of the Sharkovskii Theorem and its Application to Differential Inclusions

Motivated by the applications to differential equations without uniqueness conditions, we separately prove multivalued versions of the celebrated Sharkovskii and Li–Yorke theorems. These are then applied, via multivalued Poincaré operators, to Carathéodory differential inclusions. Thus, besides another, infinitely many subharmonics of all integer orders can be obtained. Unlike in the single-valued case, for example, period three brings serious obstructions. Three counter-examples, related to these complications, are therefore presented as well. In a multivalued setting, new phenomena are so exhibited.     

Approximation by Algebraic Polynomials on Rectangles

A direct theorem for approximation by algebraic polynomials in two variables with different degrees in each variable in L_p-metric (1 p ) on rectangles is proved, and the dependence of the constants on various parameters is studied.     

Limit theorems for random processes with random time substitution

In this paper we prove a theorem on sufficient conditions for the convergence in the Skorokhod space D[0, 1] of a sequence of random processes with random time substitution. We obtain almost sure versions of this theorem.     

单板机在气轨实验的在线时间测量

在气轨实验中，采用Z80单板机设计单板数字毫秒仪，精确测量在线时间。     

Synthesis, spectroscopic characterization, DFT studies and biological assays of a novel gold(I) complex with 2-mercaptothiazoline

A new gold(I) complex with 2-mercaptothiazoline (MTZ) with the coordination formula [AuCN(C₃H₅NS₂)] was synthesized and characterized by chemical and spectroscopic measurements, DFT studies and biological assays. Infrared (IR) and ¹H, ¹³C and ¹⁵N nuclear magnetic resonance (NMR) spectroscopic measurements indicate coordination of the ligand to gold(I) through the nitrogen atom. Studies based on DFT confirmed nitrogen coordination to gold(I) as a minimum of the potential energy surface with calculations of the hessians showing no imaginary frequencies. Thermal decomposition starts at temperatures near 160 °C, leading to the formation of Au⁰ as the final residue at 1000 °C. The gold(I) complex with 2-mercaptothiazoline (Au-MTZ) is soluble in dimethyl sulfoxide (DMSO), and is insoluble in water, methanol, ethanol, acetonitrile and hexane. The antibacterial activities of the Au-MTZ complex were evaluated by an antibiogram assay using the disc diffusion method. The compound showed an effective antibacterial activity against Staphylococcus aureus (Gram-positive) and Escherichia coli and Pseudomonas aeruginosa (Gram-negative) bacterial cells. Biological analysis for evaluation of the cytotoxic effect of the Au-MTZ complex was performed using HeLa cells derived from human cervical adenocarcinoma. The complex presented a potent cytotoxic activity, inducing 85% of cell death at a concentration of 2.0 μmol L⁻¹.     

Numerical study of the HP version of mixed discontinuous finite element methods for reaction‐diffusion problems: The 1D case

This article studies the stability and convergence of the hp version of the three families of mixed discontinuous finite element (MDFE) methods for the numerical solution of reaction‐diffusion problems. The focus of this article is on these problems for one space dimension. Error estimates are obtained explicitly in the grid size h, the polynomial degree p, and the solution regularity; arbitrary space grids and polynomial degree are allowed. These estimates are asymptotically optimal in both h and p for some of these methods. Extensive numerical results to show convergence rates in h and p of the MDFE methods are presented. Theoretical and numerical comparisons between the three families of MDFE methods are described. © 2003 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 19: 525–553, 2003     

成组Broyden修正矩阵的紧凑形式与成组记忆修正算法

1 引言 成组型线性方程组 其中,p是适中的数值,由于其有相当的实际应用背景,人们一直在研究有效的数值方法,特别是近年来,实际问题中归结出来的成组型方程组,其规模越来越大,又具有稀疏结构,因而使用迭代法是一种有效的途径,目前使用比较多的是Krylov子空间方法中的Lanczos方法,CG方法,GMRES方法等等。这种成组型算法的建立,其基本出发点是使算法具有较少的计算量和存储量,具体体现在: 1)成组型算法在应用于问题(1.1)的求解时,也具有有限终止性性质,而其终止步数一般要比单个型算法的步数减少了户倍,由于成组型算法每迭代一步的计算量基本上等同于单个型算法使用户次的计算量,如此,算法的计算量会有明显的改善。 2)当A存储在二级(secondary)内存时,在迭代计算时需要不断地进行存取交换,由于成组型算法的迭代步数减少了户倍,如此,用在这种交换的时间也要减少户倍,相当有效。 3)由于在成组型算法中,出现的多是AX的形式,其中,故成组型算法便于计算并行化。 4)即使用于求解单个方程组,当A的少数几个极端特征值分离甚远时,这种成组型算法也有可能改善其收敛速度,如成组型的CG方法。 目前,这种成组型算法已体现出很大的实用计算价值,然而其进一步的理论分析还有待深入研究。