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51.
52.
Determination of Organophosphorus Pesticides in Soil by MMSPD-GC-NPD and Confirmation by GC-MS 总被引:1,自引:0,他引:1
A novel method, modified matrix solid-phase dispersion (MMSPD), has been developed for quantitative analysis of organophosphorus
pesticide residues in soil. It was based on matrix solid-phase dispersion (MSPD) and continuous liquid-solid extraction (continuous
LSE), using Florisil as sorbent and dichloromethane as the recycling solvent. Two soils with different texture and physicochemical
properties were studied to validate the method. The effect of residence time of pesticides in soil was also studied. MMSPD
was compared with MSPD and continuous LSE respectively. Determination was carried out by gas chromatography with nitrogen-phosphorus
detection (GC-NPD). The method gave recoveries ranging from 72–105% with relative standard deviations (RSDs) lower than 15%
for the pesticides studied. The limits of detection (LODs) ranged from 0.1 to 0.6 ng g−1. Two pesticide residues have been detected in real soil samples from Fujian, China, using MMSPD. The pesticides were confirmed
by gas chromatography-mass spectrometry (GC-MS) in a selected-ion monitoring (SIM) mode.
Revised: 4 and 9 April 2006 相似文献
53.
J. Howard Rytting Danny R. McHan Takeru Higuchi David J. W. Grant 《Journal of solution chemistry》1986,15(8):693-703
Henry's law constants have been determined for -butyrolactone (BL), ethyl acetate (EA), and 2-methyl-3-pentanol (MEP) in mixtures of iso-octane (ISO) and toluene (TOL), for BL, EA, TOL, and ISO in cinnamaldehyde (CIN) and for TOL and ISO in each other and in BL. From these data and published vapor pressures, the activity coefficients at infinite dilution and the standard molar Gibbs free energy of transfer, G
2
0
of the solutes from dilute solution in ISO to dilute solution in each solvent medium have been calculated. The different behavior patterns of BL and EA are attributed to differences in their abilities to exist in different conformations possessing different dipole moments. For polar solutes, G
2
0
decreases with increasing polarizability of the solvent and with increasing dipole moment of the solute, suggesting increased contributions from dipole-induced dipole (Debye) interactions. The sigmoidal plot of G
2
0
against the change in pair potential energy calculated from the classical expressions suggests that G
2
0
seriously underestimates the strength of the Debye interactions in comparison with the London interactions. 相似文献
54.
55.
用气相流动吸附法制备复合载体,用浸渍法制备WO3/(TiO2-S iO2)催化剂.应用LRS和TPR技术研究WO3在复合载体TIO2-S iO2表面的分散状态,发现TiO2在S iO2表面的分散可增强WO3与载体之间的相互作用,提高WO3在载体表面的分散阈值.另外TPR实验证明,TiO2的存在不仅大大改善WO3的分散状态,而且使WO3在TiO2-S iO2的还原温度升高,WO3与载体之间的作用增强.负载于经TiO2调变的S iO2上的催化剂其HDS、HYD、BHD活性高于负载于单纯S iO2上的催化剂的活性. 相似文献
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58.
聚合物共混物脆韧转变性能研究 Ⅲ.分散相形态参数之间的关系 总被引:4,自引:2,他引:4
为了研究形态(特别是分散状态)对聚合物共混物韧性的影响,建立了准网络形态模型,定义了分散相分布系数(ξ,0<ξ1),并给出其物理意义,推导了基体层厚度的计算公式,研究了形态参数的变化对基体层厚度的影响.对于常见的无规形态,ξ≈1.对于准网络形态,ξ<1,并且不是常数.计算结果表明,减小ξ和分散相粒径及其分布、增大其体积分数有利于减小基体层厚度.从理论上证明了准网络形态比无规形态更有利于减小基体层厚度. 相似文献
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60.
Taking soil colloid and hydrated silica (quartz sand) as the experimental material, the comparative study has been made on the kinetics of ion diffusion and ion exchange in charged colloid and charged coarse disperse systems. The results showed that ion exchange kinetics in the two systems conform to the kinetic law of ion diffusion. Besides, through this comparative study on the kinetics of ion exchange and ion diffusion, a method has been advanced theoretically to estimate the quantity of adsorbed ion that is located in the inner of the Helmholtz layer. As far as hydrated silica is concerned , there were about 33 per cent of the total adsorbed quantity of Mg2+that were located in the inner of the Helmholtz layer under the given experimental conditions, bu tfor soil colloid the percentage was only 7.5. 相似文献