全文获取类型
收费全文 | 1933篇 |
免费 | 189篇 |
国内免费 | 137篇 |
专业分类
化学 | 468篇 |
晶体学 | 9篇 |
力学 | 245篇 |
综合类 | 43篇 |
数学 | 841篇 |
物理学 | 653篇 |
出版年
2023年 | 28篇 |
2022年 | 45篇 |
2021年 | 52篇 |
2020年 | 50篇 |
2019年 | 65篇 |
2018年 | 53篇 |
2017年 | 84篇 |
2016年 | 77篇 |
2015年 | 56篇 |
2014年 | 99篇 |
2013年 | 136篇 |
2012年 | 144篇 |
2011年 | 99篇 |
2010年 | 78篇 |
2009年 | 121篇 |
2008年 | 124篇 |
2007年 | 109篇 |
2006年 | 109篇 |
2005年 | 83篇 |
2004年 | 78篇 |
2003年 | 79篇 |
2002年 | 74篇 |
2001年 | 70篇 |
2000年 | 49篇 |
1999年 | 38篇 |
1998年 | 30篇 |
1997年 | 39篇 |
1996年 | 22篇 |
1995年 | 25篇 |
1994年 | 28篇 |
1993年 | 22篇 |
1992年 | 11篇 |
1991年 | 11篇 |
1990年 | 8篇 |
1989年 | 10篇 |
1988年 | 8篇 |
1987年 | 10篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1982年 | 4篇 |
1980年 | 2篇 |
1977年 | 4篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有2259条查询结果,搜索用时 15 毫秒
21.
The ionic transport process in polymer electrolytes (such as polyethylene oxide) wassimulated numerically on a two dimensional square lattice where charge carriers areaccommodated by the lattice sites connected randomly with available bonds to represent theamorphous chain configuration. Following the dynamic bond percolation theory(DBPT),the chainmotion contribution to the ionic conduction was incorporated via periodical renewal of the randombond configuration. To check and extend the prediction made by DBPT employing global abruptbond renewal,spatial correlation of the bond reassignment was introduced to the system by: 1)regional bond renewal and 2) organized bond motion. It is found that the difference between thediffusivities simulated involving regional bond renewal and those of DBPT becomes negligiblewhen the bond renewal rate approaches the carrier hopping rate. 相似文献
22.
本文报道了在不可逆电极过程的强催化体系中,当采用快速方波扫描时,正、逆向电流将出现峰形。依据实验结果,提出了“迁出-进入”的等浓度面理论模型,推导了并讨论了电流方程式。结果表明,文中提出的理论能较好地说明实验结果。 相似文献
23.
Let X
1, X
2, ..., X
n be independent observations from an (unknown) absolutely continuous univariate distribution with density f and let % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiiYdd9qrFfea0dXdf9vqai-hEir8Ve% ea0de9qq-hbrpepeea0db9q8as0-LqLs-Jirpepeea0-as0Fb9pgea% 0lrP0xe9Fve9Fve9qapdbaqaaeGacaGaaiaabeqaamaabaabcaGcba% GabmOzayaajaGaaiikaiaadIhacaGGPaGaeyypa0Jaaiikaiaad6ga% caWGObGaaiykamaaCaaaleqabaGaeyOeI0IaaGymaaaakmaaqadaba% Gaam4saiaacUfadaWcgaqaaiaacIcacaWG4bGaeyOeI0Iaamiwamaa% BaaaleaacaWGPbaabeaakiaacMcaaeaacaWGObGaaiyxaaaaaSqaai% aadMgacqGH9aqpcaaIXaaabaGaamOBaaqdcqGHris5aaaa!5356!\[\hat f(x) = (nh)^{ - 1} \sum\nolimits_{i = 1}^n {K[{{(x - X_i )} \mathord{\left/ {\vphantom {{(x - X_i )} {h]}}} \right. \kern-\nulldelimiterspace} {h]}}} \] be a kernel estimator of f(x) at the point x, \s-<x<, with h=h
n
(h
n
O and nh
n
, as n) the bandwidth and K a kernel function of order r. Optimal rates of convergence to zero for the bias and mean square error of such estimators have been studied and established by several authors under varying conditions on K and f. These conditions, however, have invariably included the assumption of existence of the r-th order derivative for f at the point x. It is shown in this paper that these rates of convergence remain valid without any differentiability assumptions on f at x. Instead some simple regularity conditions are imposed on the density f at the point of interest. Our methods are based on certain results in the theory of semi-groups of linear operators and the notions and relations of calculus of finite differences.This research was supported in part by grants from the Natural Sciences and Engineering Research Council of Canada and the University of Alberta Central Research Fund. 相似文献
24.
《Arabian Journal of Chemistry》2022,15(12):104330
The present study was carried out to design and synthesize a number of novel aromatic carboxamide derivatives of dehydroabietylamine. The preliminary antifungal assay indicated that most of title compounds displayed moderate to good antifungal activity toward the six fungal strains in vitro. Compounds 3i, 3q, 4b and 4d showed significant antifungal activity against Sclerotinia sclerotiorum, with EC50 values ranging from 0.067 ~ 0.393 mg/L. Compounds 3i, 4b and 4d also showed pronounced mycelial growth inhibition activities against B. cinerea and A. solani. Furthermore, in the in vivo assay, compound 4b exhibited brilliant protective activity against S. sclerotiorum-infected rape leaves. Meanwhile, the in vivo bioassay on tomato plants infected by B. cinerea showed that compound 3i and 4d displayed excellent protective activity at 200 mg/L, which were near to boscalid. Primary mechanistic study revealed that 4b could inhibit sclerotia formation as well as reduce the exopolysaccharide level. SEM and TEM analysis indicated that 4b possessed a strong ability to destroy the surface morphology of mycelia, cell structure and seriously interfere with the growth of the fungal pathogen. In addition, 4b exhibited good inhibitory activity (IC50 = 23.3 ± 1.6 μM) toward succinate dehydrogenase (SDH). Molecular modeling study confirmed the binding modes between compound 4b and SDH. The above antifungal results and fungicidal mechanism study revealed that this class of dehydroabietylamine derivatives could be potential SDH inhibitors and lead compounds for novel fungicides development. 相似文献
25.
受限条件下水的介电性质因测量极具挑战,其在诸多电化学过程与反应输运过程中如何扮演关键角色从未被定量地澄清.本工作利用平衡态分子动力学模拟和受限体系介电性质计算方法,系统性地探索了0.65 nm限域尺寸、5×108 Pa限域压强、不同温度条件下单分子受限冰和受限水的介电性质.详细比较了恒定偶极矩SPC/E水分子模型和可极化的SWM4-NDP水分子模型在描述受限冰、水结构与介电性质上的优劣势,包括统计分析SWM4-NDP模型模拟的单分子层受限水和受限冰的瞬时分子偶极矩概率密度分布,计算每个模拟体系的静态结构因子、静态偶极空间关联函数、静态介电常数、体系偶极时间关联函数和德拜弛豫时间.首次发现了极化水分子模型描述的低维度受限水和受限冰的奇异分子极性变化,并观察到两种模型描述静态结构性质的效果相当, SWM4-NDP模型对于静态介电常数描述的优势会因受限条件的增强而被大幅削减.但在受限水介电极化弛豫动力学性质描述上SWM4-NDP模型明显优于SPC/E模型.我们推断SWM4-NDP模型在探索受限水结构相变动力学以及受限体系离子输运和溶剂化动力学等过程的模拟研究中是比SPC... 相似文献
26.
27.
28.
Liping Yang Hanbang Liu Jiacheng Xing Dr. Danhua Yuan Prof. Dr. Yunpeng Xu Prof. Dr. Zhongmin Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(20):6187-6190
Xylene isomer separation is considered one of the seven separation challenges that changed the world. In addition, the high-energy demand of xylene separation highlights the need for efficient novel adsorbents. Herein, the liquid-phase separation potential of the anion-pillared hybrid material SIFSIX-1-Cu was studied for preferential adsorption of o-xylene and m-xylene over p-xylene, which was inspired by a previous complexation crystallization method for separating m-xylene. We report detailed experimental liquid-phase adsorption experiments, yielding selectivities of 3.0 for o-xylene versus p-xylene and 2.6 for m-xylene versus p-xylene. Our theoretical calculations thus provide a reasonable explanation that the xylene adsorption selectivity is attributed to the C−H⋅⋅⋅F interaction, and the host–guest interaction order agrees with the adsorption priority: o-xylene > m-xylene > p-xylene. 相似文献
29.
30.
在校正大气湍流畸变波前相差的自适应光学系统中,利用基于Levenberg-Marquardt学习算法的非线性反向传播神经网络技术(LMBP)对变形镜控制电压进行预测。以对受横向风影响的大气湍流畸变波前斜率数据为研究对象,通过数值仿真方法,研究了基于LMBP算法的自适应光学系统变形镜电压非线性预测控制算法。通过实验发现,预测电压和变形镜实际控制电压拟合效果良好。讨论了回溯帧数对预测效果的影响,并与基于递推最小二乘(RLS)算法的线性预测算法进行比较。对比结果表明,基于LMBP算法的非线性电压预测方法比基于递推最小二乘法的线性电压预测方法能更有效地降低系统由伺服延迟引起的误差。
相似文献