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51.
Bo?AndreassonEmail author Jennie?Forsstr?m Lars?W?gberg 《Cellulose (London, England)》2005,12(3):253-265
It has been shown, in the present investigation, that the two methods used to investigate the pore size distribution of unbleached
chemical pulps, i.e. inverse size exclusion chromatography (ISEC) and nuclear magnetic resonance (NMR), give different average
pore radius for the pores inside the fibre wall. This is due to the way in which these experiments are performed and the sensitivity
of the methods to different types of pores in the cell wall. It was also shown that the two methods gave different results
when changing the pH and the ionic strength of the pulp suspension. The pore radius, as detected with ISEC, decreased with
both increasing ionic strength and decreasing pH, indicating a loose structure of the exterior of the fibrillar network. However,
the pore radius as detected with NMR, was virtually unaffected when increasing the ionic strength, indicating a very rigid
structure of the interior of the fibre wall. Decreasing pH though, lead to a decrease in pore radius indicating that upon
protonation of the carboxylic groups in the fibre wall, the electrostatic repulsion is diminished and the average pore radius
decreases. The NMR technique was also used to study wet strength aid penetration into the fibre wall. It was shown that wet
strength aids with a small molecular weight, penetrated the fibre wall, as detected by a decrease in pore radius. It was also
shown that addition of different wet strength aids increased the tensile index of the sheet and decreased the fibre strength,
measured as zero span-strength of the sheets. 相似文献
52.
本底会对光谱分析结果产生很大的干扰作用,为获取特征峰的有效信息,必须首先去除本底。该文提出了一种基于小波变换的本底扣除算法,通过对光谱及后续光谱迭代进行小波变换,利用逼近系数估计本底,直到本底收敛。提出了判断多次估计的本底最大误差是否足够小的收敛准则。利用该算法去除本底后,即可进行特征峰信息的提取。分别利用仿真光谱和实验能量色散X射线荧光光谱对算法进行了验证,并与传统小波变换和多项式拟合法进行了对比。结果表明,该算法能够更准确扣除光谱本底,对其他光谱的本底扣除也具有借鉴意义。 相似文献
53.
Based on the theory of stochastic resonance, a new method carried on the quantitive analysis to weak chromatographic signal of glyburide in plasma, which was embedded in the noise background and the signal-to-noise ratio (SNR) of HPLC-UV is enhanced remarkably. This method enhances the quantification limit to 1 ng ml−1, which is the same as HPLC-MS, and makes it possible to detect the weak signal accurately by HPLC-UV, which was not suitable before. The results showed good recovery and linear range from 1 to 50 ng ml−1 of glyburide in plasma and the method can be used for quantitative analysis of glyburide. 相似文献
54.
《Arabian Journal of Chemistry》2020,13(2):4082-4091
In present study, an investigation was carried out to develop and validate an analytical method for the selective extraction and determination of griseofulvin (GSF) from plasma samples. For this purpose, a rational approach was made to synthesize and characterize the surface molecularly imprinted polymers (SMIPs). The SMIPs were utilized as solid phase extraction (SPE) sorbents. The SMIPs were prepared by using GSF as template molecule on the surface of modified silica particles through a non-covalent technique. The particles demonstrated high adsorption capacity (119.1 µg/mL), fast adsorption equilibrium time (30 min) and good recognition selectivity for the template drug. The scanning electron microscopy and infrared spectroscopy were used to explain the structural and morphological characteristics of the SMIPs and surface non-imprinted polymers. The SPE method was combined with HPLC for plasma analysis. The method validation results demonstrated that the established method possessed good linearity for GSF ranging from 0.1 to 50 µg/mL (R2 = 0.997). The limit of detection for this method was 0.02 µg/mL for rat plasma samples. The recoveries of GSF from spiked plasma samples were (90.7–97.7%) and relative standard deviations were (0.9–4.5%). Moreover, the SMIPs as selective SPE sorbent can be reused more than 8 times which is a clear advantage over commercial SPE sorbents. Finally, the usefulness of the proposed strategy was assessed by extraction and detection of GSF in real rat plasma samples. 相似文献
55.
The migration of a downsized crescent-shaped dune was investigated in a wind tunnel experiment.Quantified upwind influx and vertical oscillation of the sand bed were introduced to modulate the saturation level of the sand flux above the dune surface to affect dune evolution.The evolution was recorded by top-view photography and then abstracted as the evolution of self-defined characteristic quantities using a digital image processing algorithm.The results showed that,in contrast to the case for spanwise quantities,the evolution of streamwise quantities corresponds to a linear increase in the modulation magnitude more positively and in a monotonic and convergent manner.In contrast with quantities on the windward face,the changes in quantities with respect to the horns were nonmonotonic with time and almost uncorrelated with the variation in modulation strength,which reveals the distinctiveness of leeside evolution. 相似文献
56.
57.
媒体报道对传染病的传播有着一定的影响,但它并不是影响其传播的本质因素.通过建立一个具有分段感染率的传染病模型来刻画媒体报道对传染病传播影响的饱和性.分析了系统各平衡态的局部稳定性,同时利用排除极限环的存在性证明了各平衡态的全局稳定性.最后,通过模拟来验证我们的理论分析. 相似文献
58.
Chitosan/Ce(IV) redox polymerization‐based amplification for detection of DNA point mutation 下载免费PDF全文
Yanjun Cui Tianwei Tan Jing Yang 《Journal of polymer science. Part A, Polymer chemistry》2016,54(13):1929-1937
Polymerization‐based signal amplification, a technique developed for use in rapid diagnostic tests, hinges on the ability to localize initiators as a function of interfacial binding events. We report here a new DNA detection method in which polymer growth in redox‐polymerization is used as a means to amplify detection signals. The introduction of biotin‐labeled chitosan (biotin‐CS) with highly dense amino groups into the polymerization amplification as macromolecular reducing agent, beneficially simplifies amplification operation, as well as, provides a large amount of initiation points to improve the sensitivity of detection. DNA hybridization, SA and biotin binding reactions led to the attachment of CS on a solid surface where specific DNA sequences were located. With the addition of the mixture containing monomer AM, crosslinker PEGDA and oxidant CAN onto the CS location, the growth of polymer films was triggered to render the corresponding spots readily distinguishable to the naked eye. Direct visualization of 0.21 fmol target DNA molecules of interest was demonstrated. Non‐small cell lung cancer p53 sequence was further selected as a proof‐of‐principle to detect DNA point mutation. The proposed method exhibited an efficient amplification performance for molecule detection, and paved a new way for visual diagnosis of biomolecules. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 1929–1937 相似文献
59.
Role of compositional changes on thermal,magnetic,and mechanical properties of Fe-P-C-based amorphous alloys 下载免费PDF全文
Indah Raya Supat Chupradit Mustafa M Kadhim Mustafa Z Mahmoud Abduladheem Turki Jalil Aravindhan Surendar Sukaina Tuama Ghafel Yasser Fakri Mustafa Alexander N Bochvar 《中国物理 B》2022,31(1):16401-016401
This work aimed to tune the comprehensive properties of Fe-P-C-based amorphous system through investigating the role of microalloying process on the crystallization behavior,glass forming ability(GFA),soft magnetic features,and mechanical properties.Considering minor addition of elements into the system,it was found that the simultaneous microalloying of Ni and Co leads to the highest GFA,which was due to the optimization of compositional heterogeneity and creation of near-eutectic composition.Moreover,the FeCoNiCuPC amorphous alloy exhibited the best anelastic/viscoplastic behavior under the nanoindentation test,which was owing to the intensified structural fluctuations in the system.However,the improved plasticity by the extra Cu addition comes at the expense of magnetic properties,so that the saturation magnetization of this alloying system is significantly decreased compared to the FeCoPC amorphous alloy with the highest soft magnetic properties.In total,the results indicated that a combination of added elemental constitutes,i.e.,Fe69Co5Ni5Cu1P13C7 composition,provides an optimized state for the comprehensive properties in the alloying system. 相似文献
60.