全文获取类型
收费全文 | 1590篇 |
免费 | 388篇 |
国内免费 | 227篇 |
专业分类
化学 | 841篇 |
晶体学 | 33篇 |
力学 | 99篇 |
综合类 | 36篇 |
数学 | 54篇 |
物理学 | 1142篇 |
出版年
2024年 | 5篇 |
2023年 | 20篇 |
2022年 | 72篇 |
2021年 | 71篇 |
2020年 | 88篇 |
2019年 | 53篇 |
2018年 | 56篇 |
2017年 | 81篇 |
2016年 | 104篇 |
2015年 | 101篇 |
2014年 | 128篇 |
2013年 | 135篇 |
2012年 | 103篇 |
2011年 | 130篇 |
2010年 | 102篇 |
2009年 | 100篇 |
2008年 | 81篇 |
2007年 | 96篇 |
2006年 | 93篇 |
2005年 | 76篇 |
2004年 | 61篇 |
2003年 | 74篇 |
2002年 | 54篇 |
2001年 | 37篇 |
2000年 | 46篇 |
1999年 | 31篇 |
1998年 | 26篇 |
1997年 | 29篇 |
1996年 | 31篇 |
1995年 | 22篇 |
1994年 | 14篇 |
1993年 | 17篇 |
1992年 | 17篇 |
1991年 | 9篇 |
1990年 | 8篇 |
1989年 | 4篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1982年 | 4篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1975年 | 1篇 |
排序方式: 共有2205条查询结果,搜索用时 15 毫秒
51.
Theoretical analysis of the radiation effect on transient behavior of an optoelectronic integrated device composed of a heterojunction phototransistor and a light emitting diode is studied theoretically. First, the transient behavior and the rise time of this device before radiation are investigated based on the frequency response of the constituent devices and the optical feedback inside the device. Second, the effect of neutron irradiation flux on the transient behavior of this device is theoretically studied. The results show that, by increasing the optical feedback inside the device, the rise time in the amplification mode is increased along with an increasing output, while that in the switching mode can be reduced effectively, and the neutron irradiation reduces the transient response and the rise time in both the amplification and switching modes. This type of model can be exploited as optical amplifier, optical switching device, and other applications. 相似文献
52.
《Operations Research Letters》2019,47(5):417-420
We analyse the point availability of Gaver’s parallel system supervised by a safety device. For safety reasons, no unit is allowed to operate without supervision. The entire system is attended by two heterogeneous repairmen. Our methodology is based on the theory of sectionally holomorphic functions combined with the notion of dual transforms. As an application we consider Coxian repair time distributions. 相似文献
53.
Dr. Chandan Kumar Karan Sourav Mallick Prof. Dr. C. Retna Raj Prof. Dr. Manish Bhattacharjee 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(65):14775-14779
A zinc containing metal–organic gel (Zn-MOG) with embedded free ions, which exhibits self-healing properties, has been synthesized for application in supercapacitors. The activated carbon-based flexible supercapacitor device with the MOG electrolyte has a broad potential window of 2.1 V, with high retention of specific capacitance compared to the traditional polyvinyl alcohol (PVA)-based gel. The Zn-MOG does not require an additional electrolyte. The sodium and sulphate ions embedded in the MOG are sufficient enough for the charge storage. 相似文献
54.
2,3-Disubstituted Fluorene Scaffold for Efficient Green Phosphorescent Organic Light-Emitting Diodes
Jia-Jia Wei Yong-Jian Yang Dr. Xiang-Yang Liu Dr. Runlai Li Prof. Dr. Shu-an Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(39):e202200756
Fluorene is a classic three-membered polycyclic aromatic hydrocarbon, and it has been widely used in optoelectronic devices. Here we explore a simple and efficient strategy for the derivatization at the 2- and 3- positions in fluorene unit. By introducing different types of substituents, we design two pairs of 2,3-disubstituted fluorene isomers and use them as host materials for phosphorescent organic light-emitting diodes (PHOLEDs). The green PHOLEDs hosted by these fluorene derivatives realize high external quantum efficiencies (EQE) over 20 % with low efficiency roll-off. Particularly, the devices hosted by 2TRz3TPA and 2TPA3TRz achieve nearly 24 % EQE and 104 lm W−1 power efficiency. These results clearly demonstrate that the 2,3-disubstituted fluorene platforms are potentially useful for constructing host materials. 相似文献
55.
Majorana fermions induced fast-and slow-light in a hybrid semiconducting nanowire/superconductor device 下载免费PDF全文
We investigate theoretically Rabi-like splitting and Fano resonance in absorption spectra of quantum dots(QDs)based on a hybrid QD-semiconducting nanowire/superconductor(SNW/SC)device mediated by Majorana fermions(MFs).Under the condition of pump on-resonance and off-resonance,the absorption spectrum experiences the conversion from Fano resonance to Rabi-like splitting in different parametric regimes.In addition,the Fano resonances are accompanied by the rapid normal phase dispersion,which will indicate the coherent optical propagation.The results indicate that the group velocity index is tunable with controlling the interaction between the QD and MFs,which can reach the conversion between the fast-and slow-light.Fano resonance will be another method to detect MFs and our research may indicate prospective applications in quantum information processing based on the hybrid QD-SNW/SC devices. 相似文献
56.
Hélène Beucher Dr. Sudhir Kumar Dr. Roopender Kumar Dr. Estíbaliz Merino Wei-Hsu Hu Gerrit Stemmler Sergio Cuesta-Galisteo Dr. Jorge A. González Léonard Bezinge Dr. Jakub Jagielski Dr. Chih-Jen Shih Prof. Dr. Cristina Nevado 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(72):17604-17612
Efficient OLED devices have been fabricated using organometallic complexes of platinum group metals. Still, the high material cost and low stability represent central challenges for their application in commercial display technologies. Based on its innate stability, gold(III) complexes are emerging as promising candidates for high-performance OLEDs. Here, a series of alkynyl-, N-heterocyclic carbene (NHC)- and aryl-gold(III) complexes stabilized by a κ3-(N^C^C) template have been prepared and their photophysical properties have been characterized in detail. These compounds exhibit good photoluminescence quantum efficiency (ηPL) of up to 33 %. The PL emission can be tuned from sky-blue to yellowish green colors by variations on both the ancillary ligands as well as on the pincer template. Further, solution-processable OLED devices based on some of these complexes display remarkable emissive properties (ηCE 46.6 cd.A−1 and ηext 14.0 %), thus showcasing the potential of these motifs for the low-cost fabrication of display and illumination technologies. 相似文献
57.
Underground fluids are important natural sources of drinking water, geothermal energy, and oil-based fuels. To facilitate the surveying of such underground fluids, a novel microchannel extraction device was investigated for in-line continuous analysis and flow injection analysis of sulfide levels in water and in oil. Of the four designs investigated, the honeycomb-patterned microchannel extraction (HMCE) device was found to offer the most effective liquid–liquid extraction. In the HMCE device, a thin silicone membrane was sandwiched between two polydimethylsiloxane plates in which honeycomb-patterned microchannels had been fabricated. The identical patterns on the two plates were accurately aligned. The extracted sulfide was detected by quenching monitoring of fluorescein mercuric acetate (FMA). The sulfide extraction efficiencies from water and oil samples of the HMCE device and of three other designs (two annular and one rectangular channel) were examined theoretically and experimentally. The best performance was obtained with the HMCE device because of its thin sample layer (small diffusion distance) and large interface area. Quantitative extraction from both water and oil could be obtained using the HMCE device. The estimated limit of detection for continuous monitoring was 0.05 μM, and sulfide concentrations in the range of 0.15–10 μM could be determined when the acceptor was 5 μM FMA alkaline solution. The method was applied to natural water analysis using flow injection mode, and the data agreed with those obtained using headspace gas chromatography-flame photometric detection. The analysis of hydrogen sulfide levels in prepared oil samples was also performed. The proposed device is expected to be used for real time survey of oil wells and groundwater wells. 相似文献
58.
实验研究了基于以钢丝绳为基本元件的新型柔性防撞装置的防护性能.利用DEWETRON数据采集仪及多通道同步采集传感器的信号,分析得到防撞装置在碰撞中受到的撞击力曲线.实验结果显示:靠近船舶撞击侧最近的非撞击侧位置受到的撞击力最大,属防护重点部位;在承受多次撞击后,防撞装置基本完好,且船舶在碰撞中的损伤也有所减低. 相似文献
59.
《高分子科学杂志,A辑:纯化学与应用化学》2013,50(12):1539-1547
A novel red dye, N, N'-bis[4-(N,N-dimethylamino)-benzylidene]diaminomaleonitrile (BAM), was prepared by reacting diaminomaleonitrile with 4-(N,N-dimethylamino)-benzaldehyde and were characterized by 1H NMR, UV absorption and photoluminescence. The BAM dye showed an absorption peak wavelength of 530 nm and bright photoluminescence with a peak wavelength at 675 nm. It was used as the doped emitter for fabricating a bright scarlet organic electroluminescent (EL) device. The structure of the double-layer EL device consisted of a hole-transport layer and a luminescent layer between ITO glass and magnesium electrodes. The hole-transport layer was a poly(N-vinylcarbazole) (PVK) film. The luminescent layer consisted of a host material, 8-hydroxyquinoline aluminum (Alq3), and BAM dye as the dopant. A bright light with the peak of 620 nm and narrow bandwidth of 50 nm was obtained in the device with a maximum luminance of 6230 cd/m2. The emission spectra almost unchanged as the luminance increased with increasing injection current and the bias voltage. A tentative explanation from both the electronic distribution viewpoint and the molecular geometric analysis for the narrow bandwidth of this red dye was offered. 相似文献
60.