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91.
We measured FT-IR spectra of intact Acholeplasma laidlawii cells grown at 37 °C on palmitic acid (C16:0) or on binary palmitic acid-d31/oleic acid (C16:0-d31/C18:1(9)) at an initial mole ratio of 2:3, which have been previously reported to produce significant fluctuations in CH2 symmetric stretching (νsCH2) and CD2 asymmetric stretching (νaCD2) frequencies (Biochim. Biophys. Acta 1279 (1996) 49). Time courses for acyl chain νsCH2 and νaCD2 frequencies determined from fourth derivative spectra are presented. Fluctuations were detected with the C16:0 enriched cells at temperatures above 40 °C as well as with the cells enriched in 2:3 C16:0-d31/C18:1(9). These observations at temperatures above 40 °C for the C16:0 enriched cells were not in agreement with the conclusion in the previous work by Moore et al. Our results have suggested that the 2850 cm−1 νsCH2 band comprises two components arising from trans and gauche conformations, and that the fluctuations in νsCH2 frequency are caused by random temporal changes in the relative intensities of these two components. 相似文献
92.
Nitric oxide (NO) is an important mediator responsible for numerous physiological phenomena. Transient levels of NO in biological systems usually range from nanomolar to micromolar concentrations, with a rapid return to basal levels normally seen following these increases. Because NO can diffuse only over a local area in limited time due to such low levels of production and due to its short life-time prior to degradation, high spatial and temporal resolutions are required for direct and continuous NO measurement if the physiological role of NO is to be investigated in any system. For such purposes, analytical methods based on bio-imaging and electrochemical techniques for the measurement of NO are useful. In this paper, we describe the successful application of these methods to a number of biological systems. Specifically, complementary application of these methods demonstrate that it is possible to detect real-time NO production from nervous tissue with high spatial and temporal resolutions. 相似文献
93.
94.
固体氧化物电解池是一种高效、环境友好型的能量转换器件,可以直接将电能转化为化学能. 本文介绍了近年来作者课题组在固体氧化物电解池直接用于CO2还原的研究进展,并以阴极材料为主着重讨论了金属陶瓷电极和混合导电型钙钛矿氧化物电极的研究工作,最后展望了未来固体氧化物电解池直接电解CO2的研究思路和方向. 相似文献
95.
Difference in Conversions Between Dimethyl Sulfide and Methanethiol in a Cold Plasma Environment 总被引:1,自引:0,他引:1
Cheng-Hsien Tsai Wen-Jhy Lee Chuh-Yung Chen Perng-Jy Tsai Guor-Cheng Fang Minliang Shih 《Plasma Chemistry and Plasma Processing》2003,23(1):141-157
This study compared the conversion of two malodorous substances, dimethyl sulfide (CH3SCH3, DMS) and methanethiol (CH3SH) in a cold plasma reactor. The DMS and CH3SH were successfully destroyed at room temperature. DMS decomposed less than CH3SH at the same conditions. In oxygen-free condition, CS2 and hydrocarbons were the major products, while SO2 and COx were main compounds in oxygen-rich environments. The DMS/Ar plasma yielded more hydrocarbons and less CS2 than that of CH3SH/Ar plasma. In the CH3SH/O2/Ar plasma, rapid formation of SO and CO resulted in the yields much more amounts of SO2 and CO2 than those in the DMS/O2/Ar plasma; and remained only a trace of total hydrocarbons, CH2O, CH3OH, CS2, and OCS. The major differences between the reaction mechanisms of DMS and CH3SH were also proposed and discussed. 相似文献
96.
Summary The retention, selectivity and elution order of fluorescent 1,N6-etheno derivatives of diadenosine polyphosphates and their enzymatic degradation products on octadecyl and phenyl-bonded
silica columns have been studied as a function of mobile phase pH, ionic strength and organic modifier content. Good separations
of the compounds of interest were achieved using mobile phases of around 0.1M potassium phosphate buffers at neutral pH containing
approximately 10% methanol or 4% acetonitrile for C18 columns and 5% methanol or 1.5% acetonitrile for phenyl columns. The data obtained were used to establish isocratic assays
for diadenosine polyphosphate cleaving activities from chromaffin cells using Di(1,N6-ethenoadenosine) polyphosphates as fluorogenic substrate analogues followed by fluorescence detection. 相似文献
97.
5-Hydroxytryptamino-induced calcium sparks in cultured rat stomach fundus smooth muscle cells 总被引:1,自引:0,他引:1
With the imaging fluorescence probe of Ca2+ (fluo-3) and a laser scanning confocal micro-scope, the spontaneous localized calcium release event was first discovered in resting rat cardiac myocytes by Cheng[1] in 1993. A mathematical simulation is developed with computer in order to reveal the effect, which is immediately suggested that these events are likely to reflect the local-ized release of Ca2+ from a small cluster of ryanodine-sensitive Ca2+ release channels in sar-coplasmic reticulum … 相似文献
98.
La0.8Sr0.2Ga0.8Mg0.2O2.8的电化学性质及其在SOFC中的应用 总被引:3,自引:0,他引:3
采用凝胶浇注法制备具有较高氧离子电导率的固体电解质La0.8Sr0.2Ga0.8Mg0.2O2.8粉料.X射线衍射结果表明,于1400℃焙烧后即形成了钙钛矿结构,无杂相存在.探讨了粉料压制坯体的致密化和导电性能在1450℃下与烧结时间的关系,发现烧结时间为18h时其相对密度达98.3%,而在24h的情况下,样品具有最佳的氧离子导电性.采用Ni-Ce0.8Gd0.2O1.9作为阳极,La0.8Sr0.2Ga0.6Ni0.4O2.7作为阴极,组装了平板型固体氧化物燃料电池(SOFC).阳极和阴极分别通入含3%H2O的氢气和空气,750℃时的开路电压为1.04V,最大输出功率密度(P)达252mW/cm2(U=0.48V,J=525mA/cm2). 相似文献
99.
The electrode behavior and microstructure of freshly prepared (La0.8Sr0.2)0.9MnO3 (LSM) electrodes were investigated under various polarization conditions. The original, large agglomerates in freshly prepared LSM electrodes were broken down into sphere-shaped grains when exposed to cathodic or anodic current passage of 200 mA cm–2 at 800 °C in air for 3 h. Microstructural changes under cathodic polarization could be related to the pronounced diffusion and migration of oxygen vacancies and Mn ions on the LSM surface and lattice expansion, while lattice shrinkage under oxidation conditions most likely contributes to the structural changes under anodic polarization. Such morphological changes were irreversible and were found to be beneficial to the performance of freshly prepared LSM electrodes. Freshly prepared LSM electrodes behaved very differently with respect to the cathodic and anodic current passage treatment. 相似文献
100.
Laurent Griffe Dr. Mary Poupot Dr. Patrice Marchand Dr. Alexandrine Maraval Dr. Cédric‐Olivier Turrin Dr. Olivier Rolland Pascal Métivier Dr. Gérard Bacquet Dr. Jean‐Jacques Fournié Dr. Anne‐Marie Caminade Dr. Rémy Poupot Dr. Jean‐Pierre Majoral Dr. 《Angewandte Chemie (International ed. in English)》2007,46(14):2334-2334