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61.
62.
Taranjeet Kaur Ravinder Kumar Wanchoo 《International journal of environmental analytical chemistry》2015,95(6):494-507
Photocatalytic degradation of propiconazole, a triazole pesticide, in the presence of titanium dioxide (TiO2) under ultraviolet (UV) illumination was performed in a batch type photocatalytic reactor. A full factorial experimental design technique was used to study the main effects and the interaction effects between operational parameters in the photocatalytic degradation of propiconazole in a batch photo-reactor using the TiO2 aqueous suspension. The effects of catalyst concentration (0.15–0.4 gL?1), initial pH (3–9), initial concentration (5–35 mg L?1) and light conditions were optimised at a reaction time duration of 90 min by keeping area/volume ratio constant at 0.919 cm2 mL?1. Photocatalytic oxidation of propiconazole showed 85% degradation and 76.57% mineralisation under UV light (365 nm/30 Wm?2) at pH 6.5, initial concentration 25 mg L?1 and constant temperature (25 ± 1 °C). The Langmuir–Hinshelwood kinetic model has successfully elucidated the effects of the initial concentration on the degradation of propiconazole and the data obtained are consistent with the available kinetic parameters. The photocatalytic transformation products of propiconazole were identified by using gas chromatography–mass spectrometry (GC/MS). The pathway of degradation obtained from mass spectral analysis shows the breakdown of transformation products into smaller hydrocarbons (m/z 28 and 39). 相似文献
63.
An on-line solid phase extraction-high performance liquid chromatography-tandemmass spectrometry method for the analysis of perfluoroalkyl substances (PFASs) in water samples was developed. The optimal analytical conditions were obtained through the optimization of the extraction efficiency of online solid phase extraction column, sample loading rate and loading volume, and the concentration of ammonium acetate in mobile phase. Under the optimal condition, the analytical method displayed good linearity (r2 > 0.99) for 12 PFASs (C5-C14 perfluoroalkyl carboxylic acids and C6/C8 perfluoroalkyl sulfonic acids) over a concentration range of 0.5-100 ng/L. The limits of quantitation for samples were between 0.025 ng/L and 0.5 ng/L and the relative standard deviations (RSD) of five consecutive analyses were less than 10% for 1 ng/L standard solution. Satisfactory results were obtained using this analytical method for the analysis of perfluoroalkyl substances in Antarctic ice core samples. The recoveries of all perfluoroalkyl substances were in a range of 73%-117% when the sampleswere spiked with standards at the concentrations of 2.5 ng/L and 25 ng/L. 相似文献
64.
Tetsuo Okada 《Chemical record (New York, N.Y.)》2017,17(4):415-428
Ice has a variety of scientifically interesting features, some of which have not been reasonably interpreted despite substantial efforts by researchers. Most chemical studies of ice have focused on the elucidation of its physicochemical nature and its roles in the natural environment. Ice often contains impurities, such as salts, and in such cases, a liquid phase coexists with solid ice over a wide temperature range. This impure ice also acts as a cryoreactor, governing the circulation of chemical species of environmental importance. Reactions and phenomena occurring in this liquid phase show features different from those seen in normal bulk aqueous solutions. In the present account, we discuss the chemical characteristics of the liquid phase that develops in a frozen aqueous phase and show how novel analytical systems can be designed based on he features of the liquid phase which are predictable in some cases but unpredictable in others. 相似文献
65.
水煤浆喷嘴热冲蚀磨损机理研究 总被引:4,自引:5,他引:4
采用1Crl8Ni9Ti不锈钢、YG8硬质合金和Al2O3/(W,Ti)C陶瓷3种材料制备了水煤浆喷嘴,考察了其在水煤浆雾化和燃烧过程中的热冲蚀磨损机理.结果表明:喷嘴材料的硬度对水煤浆喷嘴的热冲蚀磨损行为具有重要影响;在相同条件下,高硬度的Al2O3/(W,Ti)C陶瓷喷嘴的冲蚀率最低,YG8硬质合金次之,硬度较低的1Crl8Ni9Ti不锈钢喷嘴的冲蚀率最高;在热冲蚀磨损工况下,1Crl8Ni9Ti不锈钢水煤浆喷嘴主要呈现微切削特征,YG8硬质合金水煤浆喷嘴主要呈现晶粒剥落特征,而Al2O3/(W,Ti)C陶瓷水煤浆喷嘴主要呈现研磨损伤和热崩特征. 相似文献
66.
本文对气固冲蚀和浆体冲蚀条件下耐磨环氧胶粘涂层的磨损特性进行了研究。结果表明,这种涂层的冲蚀磨损是由粘结剂的磨损和抗磨填料的磨损所组成;填料粒度和磨料粒度都对涂层的气固冲蚀磨损有影响,但在给定的试验条件下,填料粒度对涂层的浆体冲蚀磨损影响甚微。文章指出,耐磨环氧胶粘涂层在气固冲蚀和浆体冲蚀下的磨损机理相似,但磨损规律却有所不同;耐磨环氧胶粘涂层尤其适用于浆体冲蚀的场合,可以明显地提高机械过流部件的使用寿命。 相似文献
67.
The nonstationary rectilinear motion of an amphibian air-cushion vehicle (AACV) on a water surface covered with finely broken ice is considered for various modes of velocity variation. The influence of
the water depth, flotation parameters, and mode of motion on the wave resistance of the vehicle is analyzed. Maneuvering methods
for increasing or decreasing the wave resistance of AACVs are proposed.
__________
Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 48, No. 1, pp. 97–102, January–February, 2007. 相似文献
68.
69.
V. I. Odinokov A. M. Sergeeva 《Journal of Applied Mechanics and Technical Physics》2006,47(2):266-273
The spatial problem of determining the stress-strain state of an ice plate of finite thickness broken by a patented method
is solved using the theory of small elastoplastic strains and a proven numerical method.
__________
Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 47, No. 2, pp. 139–146, March–April, 2006. 相似文献
70.
斜面结构冰荷载的动荷效应 总被引:2,自引:0,他引:2
利用改进的刚性梁模型进行了斜面结构冰荷载的动荷效应,推导了冰力的动荷系统,算例得到了与模型试验值和数值解相近的结果,依据分析对试验观察到的规律给出了理论上的证明和定性的解释,给出了准静态冰力条件的判别式。 相似文献