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41.
We have investigated the free energy of formation for AgxIn1-x and AgxSn1-x liquid binary alloys at temperatures 1173 and 1250 K, respectively. A microscopic theory based on the first order perturbation has been applied. The interionic interaction and a reference liquid are the fundamental components of the theory. The interionic interaction is described by a local pseudopotential. A liquid of hard spheres (HS) of two different effective diametres and charges is used to describe the reference system. The results of the calculations for energy of formation agree very well with the available experimental data. Our calculations also reveal that a simple perturbative approach along with appropriate effective pair potentials can produce nearly quantitative results for the concerned alloys. 相似文献
42.
功能性丙烯酸/MBAM体系共聚产物的研制 总被引:2,自引:0,他引:2
以丙烯酸和MBAM为主要原料,经聚合,合成了一种高性能的具有良好保水性能的聚合产物,其保水量达到750~1000倍.50℃以下有良好的保水性能,28℃以下有极好的保水性能,并研究了工艺条件对该产品性能的影响因素. 相似文献
43.
Franck D'Agosto Marie‐Thrse Charreyre Christian Pichot Robert G. Gilbert 《Journal of polymer science. Part A, Polymer chemistry》2003,41(9):1188-1195
A method is described for synthesizing latex particles with anchored hairs by the grafting of hydrophilic chains, synthesized by reversible addition–fragmentation chain transfer, onto functionalized latex particles. These have the potential to bind biologically active species. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1188–1195, 2003 相似文献
44.
The enthalpies of formation of simple nonmetal or metalloid oxyanions in aqueous solution are discussed. Archival values are cited and estimates are made. Trends prove evasive. 相似文献
45.
A simple method of determining ultra-trace Au in natural water was presented by using graphite furnace atomic absorption spectrophotometry (GFAAS) after in situ enrichment with thiol cotton fiber (TCF). The sample solution was adjusted to pH 1.5-2.0 with HCl, then the water sample was passed through a column packed with 0.10-0.20 g TCF and the flow rate was controlled at 20-40 ml min−1. The effects of interferences, such as complexing and oxidizing agents and other elements adsorbed on TCF were overcome by chemical treatments prior to the desorption of Au. The adsorbed Au was adsorbed with 2.0 ml hot acid, then it was extracted with 1.00 ml methyl isobutylketone (MIBK). For a 5 l water sample, the detection limit of Au is 0.02 ng l−1. The relative standard deviation (R.S.D.) for the determination of 1.44 ng l−1 Au was 9.4%.The method was applied to determine ultra-trace Au both in suspended phase and soluble phase in natural water, the concentrations of total Au in natural water samples range from 0.51 to 67.82 ng l−1. The recovery of added 0.50-6.00 ng l−1 Au was 80-95%. The method is useful in prospecting for Au deposits by means of hydrogeochemical methods. The enrichment is carried out in the field, and then the determination of Au is completed later in the laboratory. 相似文献
46.
S. S. Andreev A. D. Akhsakhalyan M. A. Bibishkin N. I. Chkhalo S. V. Gaponov S. A. Gusev E. B. Kluenkov K. A. Prokhorov N. N. Salashchenko F. Schafers S. Yu. Zuev 《Central European Journal of Physics》2003,1(1):191-209
We present research investigations in the field of multilayer optics in X-ray and extreme ultra-violet ranges (XUV), aimed
at the development of optical elements for applications in experiments in physics and in scientific instrumentation. We discuss
normal incidence multilayer optics in the spectral region of “water window”, multilayer optics for collimation and focusing
of hard X-ray, multilayer dispersing elements for X-ray spectroscopy of high-temperature plasma, multilayer dispersing elements
for analysis of low Z-elements. Our research pays special attention to optimization of multilayer optics for projection EUV-lithography
(ψ-13nm) and short period multilayer optics. 相似文献
47.
Thomas Wanner 《Transactions of the American Mathematical Society》2004,356(6):2251-2279
Many interesting and complicated patterns in the applied sciences are formed through transient pattern formation processes. In this paper we concentrate on the phenomenon of spinodal decomposition in metal alloys as described by the Cahn-Hilliard equation. This model depends on a small parameter, and one is generally interested in establishing sharp lower bounds on the amplitudes of the patterns as the parameter approaches zero. Recent results on spinodal decomposition have produced such lower bounds. Unfortunately, for higher-dimensional base domains these bounds are orders of magnitude smaller than what one would expect from simulations and experiments. The bounds exhibit a dependence on the dimension of the domain, which from a theoretical point of view seemed unavoidable, but which could not be observed in practice.
In this paper we resolve this apparent paradox. By employing probabilistic methods, we can improve the lower bounds for certain domains and remove the dimension dependence. We thereby obtain optimal results which close the gap between analytical methods and numerical observations, and provide more insight into the nature of the decomposition process. We also indicate how our results can be adapted to other situations.
48.
溃坝问题的间断有限元方法 总被引:2,自引:0,他引:2
本文研究90年代初提出的Runge-Kutta间断Galerkin有限元方法,给出该方法的精度分析,通过经典算例验证该方法处理间断问题、捕捉锐利波形的能力,并将其推广到求解浅水问题.针对坝底无摩擦,无坡度的理想情形进行讨论,给出方溃坝和圆溃坝问题的数值模拟结果. 相似文献
49.
Marcos Almeida Bezerra Sérgio Mitihiro do Nascimento Maêda Eliane Padua Oliveira Maria de Fátima Batista de Carvalho Ricardo Erthal Santelli 《Spectrochimica Acta Part B: Atomic Spectroscopy》2007
In the present paper a procedure is proposed for the determination of traces of Cd, Co, Mn and Cr in petroleum industry produced water by inductively coupled plasma optical emission spectrometry. The procedure is based on cloud point extraction of these metals, as their dithizonate complexes, into the surfactant-rich phase of octylphenoxypolyethoxyethanol surfactant (Triton X-114). Extractions were carried out in solutions with salinities between 10‰ and 70‰. Since residual salinity in the surfactant-rich phase caused differences in its transport to the plasma, yttrium was used as an internal standard to correct for this effect. The simultaneous metal extraction procedure was optimized by response surface methodology using a Doehlert design and desirability function. Enhancement factors of 21, 21, 9 and 19, along with limits of quantification of 0.093, 0.20, 0.73 and 1.2 μg L− 1, and precision expressed as relative standard deviation (n = 8, 20.0 μg L− 1) of 5.8, 1.2, 1.7 and 5.7% were obtained for Cd, Co, Mn and Cr, respectively. The accuracy was evaluated by spike recovery tests on the high salinity water samples with salinity of 40 and 63‰. 相似文献
50.
Jonatan Lenells 《Journal of Mathematical Analysis and Applications》2007,325(2):1468-1478
We use the inverse scattering transform to show that a solution of the Camassa-Holm equation is identically zero whenever it vanishes on two horizontal half-lines in the x-t space. In particular, a solution that has compact support at two different times vanishes everywhere, proving that the Camassa-Holm equation has infinite propagation speed. 相似文献