高分辨率制冷型中波广角红外成像系统的光学设计

设计了一个F数为2,工作波段为3.7～4.8μm,全视场2ω=111.2°的高分辨率制冷型中波广角红外成像光学系统。该系统采用二次成像构型,通过Si、Ge、ZnSe三种材料六片式对称布局,利用折/衍混合器件及非球面,实现了光学被动消热差设计,使系统在-55℃至+80℃的宽温范围内,在空间频率为33lp/mm处的光学传递函数(MTF)均大于0.4,系统在15μm的像素尺寸内,能量集中度大于70%;采用f-θ设计,使成像系统对不同视场具有相同的角分辨率;通过引入光阑像差和控制像方视场角,使像面具有较好的均匀性,边缘视场最低相对照度为中心视场的90.9%,且具有近100%的冷光阑效率,同时,系统具有较好的冷反射抑制效果,该光学系统适用于像素为15μm,分辨率为640pixel×512pixel的中波制冷探测器。     

傅里叶变换红外光谱对水溶性气溶胶复折射率的测量分析方法研究

当前大气气溶胶的成分比较复杂,其水溶性离子成分影响着大气质量,并且对人类健康不利。因此,对水溶性离子成分进行快速可靠的检测是环境科学领域中的一项重要研究工作。以SO24-为例,研究采用傅里叶变换红外光谱(FTIR)技术,对水溶性气溶胶离子的消光系数进行测量,并通过理论分析计算得到其复折射率N的过程。通过测量大气气溶胶水溶性SO24-离子的质量消光截面k和消光系数α,再根据消光系数α来计算复折射率N的虚部ni,使用KK(Kramers-Kronig)关系,来计算复折射率N的实部nr,并对实验结果进行了分析和讨论。     

光学读出非制冷红外成像技术的光学灵敏度分析

不同于传统的非制冷红外成像技术,提出了基于微电子机械系统(MEMS)的新概念光学读出非制冷红外成像技术。它的光学读出系统基于空间刀口滤波原理,具有高灵敏度、高分辨率和高抗震性等优点,但同时也受到了反光板的弯曲变形、粗糙度等复杂因素的影响。在大量实验数据的基础上,利用夫琅禾费近场衍射理论,建立了复杂因素下光学灵敏度的理论分析模型,详细分析了刀口滤波位置、反光板的长度、曲率半径、粗糙度、LED光源的强度以及扩展宽度等对光学灵敏度的影响,并提出了通过极限操作使系统的光学灵敏度最大化的光学优化方法。     

水热法制备一维钛酸纳米材料及其在太阳光反射涂料中的应用研究

以微米级二氧化钛(P25)为原料,用水热法制备了一维纳米钛酸材料,分析了纳米钛酸的形貌、红外特性和晶体结构。并进一步对纳米钛酸作为太阳光反射涂料填料的效果进行了研究,其涂层在可见光波段(380～780 nm)范围平均反射率可达到76.15%,在红外波段(780～2500 nm)范围平均反射率可达47.34%。     

Complexes of 8-Aminoquinoline. I. The Infrared Spectra of the Ligand,the Tris Complexes of Iron,Cobalt and Nickel Perchlorates and Their ND2 Analogues

Abstract

Deuteration of 8-aminoquinoline (aq) at the amino groups and comparison of the infrared spectrum of aq with those of aniline and quinoline enables reliable assignments to be proposed for the amino stretching and bending modes and the internal modes of the aminoquinoline rings. The spectra of the tris(8-aminoquinoline) complexes of iron, cobalt and nickel perchlorates have been examined over the range 4000–50 cm^?1 with assignments based on the ligand study and the effects of metal ion substitution and deuteration of the nickel complex. The existence of two vM-NH₂ and two vM-N(aq) bands is consistent with facial (cis-cis) octahedral coordination about the metal ion.     

Mononuclear copper(I) complexes with triphenylphosphine and N,N′-disubstituted thioureas: synthesis,characterization, and biological evaluation

Abstract

Twelve new complexes, of the general formula CuCl(TPP)₂Tu^1–12 (Tu?=?thiourea), were synthesized by the reaction of CuCl(TPP)₃ (TPP?=?triphenylphosphine) and various N,N′-disubstituted thioureas. The structures of the synthesized complexes were characterized by different techniques such as Fourier transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy (¹H, ¹³C, ³¹P, and ¹⁹F), and the representative complexes (1, 2 and 12) were analyzed via single crystal X-ray diffraction. The single crystal X-ray analysis revealed that copper(I) is coordinated with chlorine, two TPP, and the thiourea ligands through the sulfur atom in a mononuclear distorted tetrahedral mode. The compounds were tested for antibacterial, antifungal, cytotoxicity, antileishmanial, and antioxidant activities. The results showed that the synthesized complexes are significantly more active than the free ligands and the commercial reference compounds. The high biological activities of the complexes versus free ligands can be attributed to the copper(I) chloride complexation with thiourea ligands. The synthesized complexes were also evaluated, both experimentally and theoretically, for DNA binding studies. The UV-visible spectroscopic and molecular docking studies demonstrated that the complexes are conjugating with DNA through a groove binding mode.     

基于可能性信息质量合成的双模态红外图像融合算法选取

针对双模态红外图像在融合时异类差异特征两两合成出现信息冗余导致所选择的融合算法相互冲突,造成融合效果差甚至失效的问题,提出了一种基于可能性信息质量合成的双模态红外图像融合算法选取方法。首先计算双模态红外图像多融合算法下不同差异特征的融合有效度,利用可能性框架得到对应的可能性分布向量子集;其次计算向量子集的信息量和可信度,并对多个向量子集进行加权合成;然后构建基于信息质量的排序函数,得到每种融合算法下的非支配子集;最后构建多融合算法得分函数的联合分布对多种融合算法优化选择。实验结果表明,将基于质量来整合多个差异特征的方法运用于双模态红外图像融合算法选取中,所选出的融合算法在加权综合指标上高于其他算法均值55%以上,证明了本文方法的有效性和合理性;由多组实验算得本文方法平均耗时10.083 s,在时间效率上也符合实时图像融合应用的工程需求。     

基于可能性分布联合落影的红外图像融合算法选取

针对双模态红外图像实际融合需求中常涉及到异类差异特征协同优化融合,且现有差异特征属性无法针对性地调整融合算法进行有效驱动,导致融合效果差等问题,提出了基于可能性分布联合落影的双模态红外图像融合算法选取的方法。首先计算双模态红外图像差异特征幅值的融合有效度,利用K最近邻法得到差异特征幅值的概率密度分布,得到差异特征频次属性的分布;然后通过差异特征幅值属性与频次属性构造差异特征权重函数,建立异类差异特征权重函数与多融合算法间的可能性分布合成,得到异类差异特征权重函数多融合算法融合有效度的联合落影;最后构建融合性能指标动态选取最优融合算法。实验结果表明,本文方法所选出的最优融合算法在等级得分指标上明显优于其他算法,验证了本文将可能性分布联合落影运用于双模态红外图像最优融合算法选取中具有可行性。     

Towards an understanding of the helium–acetylene van der Waals complex

The weakly bound complex He–C₂D₂ is studied in the ν ₃ fundamental band of C₂D₂ (≈2440?cm^?1) using a tuneable infrared diode laser to probe a pulsed supersonic slit jet expansion. This is the first published spectrum for helium–acetylene. Transitions observed in the region of the C₂D₂ R(0) line are assigned with the help of theoretical results based on an ab initio intermolecular potential, and fitted using a simple Coriolis model. The results indicate that the complex is rather close to the free rotor limit, helping to explain the absence of previous data. Scaled parameters from the model are used to predict a spectrum for He–C₂H₂.     

Ionic Liquids for and by Analytical Spectroscopy

Abstract

In this mini‐review we highlight two aspects of ionic liquids that to date have either no or limited studies. They are (1) exploitation of unique features of ionic liquids to develop novel spectroscopic methods and (2) development of novel spectroscopic methods, for the sensitive and accurate determination of thermal physical properties of ionic liquids. In the first category, we will describe several novel methods which were developed utilizing unique properties of ionic liquids for measurements which are not possible otherwise. They include the sensitive and accurate method to determine enantiomeric compositions of a variety of pharmaceutical products with different size, shape, and functional groups. This method is based on the use of a chiral IL which serves both as a solvent and also as a chiral selector. Ionic liquids have also been successfully used to substantially enhance the sensitivity of thermal lens measurements. In the second category, we will describe recent development in which transient grating technique and thermal lens technique have been successfully used for the sensitive, accurate, nondestructive determination of thermal physical properties of ILs.