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121.
Terry Spencer 《Accreditation and quality assurance》2005,10(6):308-314
This presentation deals with issues of comparability and traceability in food analysis in Australia from several perspectives. This includes the current national (Australian) and increasingly international (Codex) performance-based approach to food analysis. The Australian food regulatory process will be described, particularly those aspects that impact on the analysis of food in a regulatory sense. This section will also describe two areas where specific methods have been mandated in legislation and discuss two case studies where the analytical method has impacted on the elaboration of standards. Other areas to be covered include regulation/requirements relating to supply/availability of reference materials, the use of proficiency testing as a means of ensuring comparability, and, finally, some thoughts on what role BIPM/CCQM may play in the analysis of food.Electronic Supplementary Material Supplementary material is available for this article at
相似文献
Terry SpencerEmail: Phone: +612-6213-6102Fax: +612-6213-6815 |
122.
The robustness testing of a normal-phase liquid chromatographic (LC) method for the determination of R-timolol and other related substances in S-timolol maleate was performed applying a two-level Plackett-Burman design. Two qualitative and five quantitative factors were examined. Two types of responses were considered, qualitative, i.e. chromatographic performance criteria, and quantitative ones. The latter were taken into account to determine if the analytical procedure was robust. The quantitative responses were the contents of R-timolol in two S-timolol maleate samples. Even though some significant factor effects were observed on the qualitative responses, the R-timolol contents were not significantly different from those observed at nominal conditions, which demonstrated the robustness of the procedure.Since the experiments of the Plackett-Burman design can be assimilated to laboratories in an interlaboratory study, uncertainty can be evaluated using the robustness test data. The robustness test was set-up in such a way that the required variances could be estimated. It was shown that the robustness set-up allows estimating the reproducibility uncertainty without performing an interlaboratory study. 相似文献
123.
Hans-Jörg Jacobasch Günther Bauböck Josef Schurz 《Monatshefte für Chemie / Chemical Monthly》1986,117(10):1133-1144
An apparatus for the determination of zetapotential is described, which allows measurement of both streaming potential and streaming current as well as electroosmosis with one and the same fiber diaphragm with various electrodes (calomel, Ag/AgCl, palladium). Measurements with glass fibers, fibers of polyacrylonitrile and of polyester, and with cellulose pulp show that identical values for the electrokinetic parameters are obtained independent of voltage applied during electroosmosis resp. pressure difference during streaming measurements. This allows the conclusion that the zetapotential in dilute electrolyte solution is here an unequivocally determinable figure.
Herrn Prof. Dr.R. C. Schulz mit den herzlichsten Glückwünschen zum 65. Geburtstag gewidmet. 相似文献
124.
Capillary gc is now rapidly expanding. Naturally, initiation is most often attempted on the basis of the experience acquired with packed columns. However, such an extrapolation is successful only if a number of essential peculiarities of capillary gc are considered. Based on practical examples this paper discusses six essential details: 1) design and maintenance of the gas flow paths, 2) the greatly increased importance of sampling technique, which should not be confined just to stream splitting, 3) the problems in quantitative analysis arising from small sample size, 4) specific sources of trouble related to small amounts of liquid phase, 5) specific arguments for the choice of the carrier gas, clearly pointing to hydrogen as the ideal carrier and, 6) the different way to approach column production. Figures for all selected examples are given. 相似文献
125.
The factors influencing the electrochemical behaviour of a supercapacitor have been partly examined in this work. The effects
of so-called intrinsic parameters, i.e. exchange current density, unit cell length and double layer (DL) capacitance; as well
as the so-called application parameters, i.e. cell current, on the cell potential discharge time have been considered. The
contributions of each type of capacitors, DL capacitor and faradaic supercapacitor under various states of operation and material
have been analyzed, and the competing (compensating) effects of the two types of capacitors as regards to the discharge and
power characteristics manifested by current–potential and energy–power (Ragone plots) are elucidated. 相似文献
126.
化学位移估算研究ATP构象随溶液pH值的变化 总被引:2,自引:0,他引:2
利用Johnson和Bovey的理论和方法计算了不同扭曲角χ(O4′-C1′-N9-C4)的ATP(5′-三磷酸腺苷)分子中糖环质子H1′和H2′由于环流效应引起的化学位移.H1′的化学位移与扭曲角χ有较强的依赖关系,反映了ATP在溶液中细微的构象变化.将计算结果与实验结果比较,证明在本文讨论的pH值范围(1~10)内,Mg2+加入后,ATP的扭曲角χ在230~360°范围内变化.随溶液的pH值减小,ATP分子的构象由trans 构象通过-gauche构象转变为cis构象. 从而证明在酸性条件下, ATP倾向于以cis构象存在,而在碱性条件下trans构象更为稳定,从另一方面支持了在酸性条件下N1参与配位而在碱性条件下N7参与配位的结论.在讨论中也考虑了由pH变化所引起的环流强度的变化. 相似文献
127.
Summary The quantitative use of high speed capillary electrophoresis (HSCE) is examined by applying high voltages across short capillaries.
Acceptable performance in terms of injection precision and migration times were achieved within 1–2 minute analysis times.
HSCE was used for the novel CE application of dissolution test sample solution analysis. The results generated by HSCE compared
well with those generated using validated on-line UV absorbance measurements. It is concluded that HSCE is a viable alternative
and supplement to standard analytical methods employed in dissolution test analysis. 相似文献
128.
Dong-shanZhou Xiao-liangWang BoChe LiangLi Jin-luChen GiXue 《高分子科学》2005,(2):159-163
Entropic contribution to the interaction parameter xeff in the model incompressible polymer/oligomer system is calculated by the lattice cluster theory (LCT). It is found that in the oligomer solvent, there exists a wide concentration range that the non-combinatorial “entropic interaction” term xeff φ1φ2 perceptibly counteracts the mean field combinary entropy ΔSMF. With the increase of the solvent size, both xeff and the ratio xefc φ1φ2/ΔSMF first reach their maximum and finally become trivially to zero. It is worth noting that no any demixing was found in the current calculation. This makes the controversial idea “entropically driven demixing” even elusive. However, we propose that further work on compressible polymer solution with structured monomer will witness the demixing owning to an increased configurational correlation. 相似文献
129.
Soncini A Domene C Engelberts JJ Fowler PW Rassat A van Lenthe JH Havenith RW Jenneskens LW 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(4):1257-1266
Why are some (4n+2)π systems aromatic, and some not? The ipsocentric approach to the calculation of the current density induced in a molecule by an external magnetic field predicts a four‐electron diatropic (aromatic) ring current for (4n+2)π carbocycles and a two‐electron paratropic (antiaromatic) current for (4n)π carbocycles. With the inclusion of an electronegativity parameter, an ipsocentric frontier‐orbital model also predicts the transition from delocalised currents in carbocycles to nitrogen‐localised currents in alternating azabora‐heterocycles, which rationalises the differences in (magnetic) aromaticity between these isoelectronic π‐conjugated systems. Ab initio valence‐bond calculations confirm the localisation predicted by the naïve model, and coupled‐Hartree–Fock calculations give current‐density maps that exhibit the predicted delocalised‐to‐localised/carbocycle–heterocycle transition. 相似文献
130.
有限线性扩散区域内EC'反应催化电流吴志斌,董绍俊,吴浩青(同济大学化学系,上海,200092)(中国科学院长春应用化学研究所)(复旦大学化学系)关键词有限线性扩散空间,EC'反应,催化电流化学修饰电极等有关膜电极及薄层池的电极过程动力学问题均涉及到... 相似文献