全文获取类型
收费全文 | 4443篇 |
免费 | 616篇 |
国内免费 | 282篇 |
专业分类
化学 | 1975篇 |
晶体学 | 75篇 |
力学 | 458篇 |
综合类 | 62篇 |
数学 | 609篇 |
物理学 | 2162篇 |
出版年
2024年 | 9篇 |
2023年 | 31篇 |
2022年 | 78篇 |
2021年 | 104篇 |
2020年 | 110篇 |
2019年 | 101篇 |
2018年 | 100篇 |
2017年 | 131篇 |
2016年 | 170篇 |
2015年 | 119篇 |
2014年 | 201篇 |
2013年 | 379篇 |
2012年 | 240篇 |
2011年 | 276篇 |
2010年 | 220篇 |
2009年 | 267篇 |
2008年 | 310篇 |
2007年 | 275篇 |
2006年 | 256篇 |
2005年 | 237篇 |
2004年 | 204篇 |
2003年 | 201篇 |
2002年 | 138篇 |
2001年 | 142篇 |
2000年 | 112篇 |
1999年 | 148篇 |
1998年 | 105篇 |
1997年 | 87篇 |
1996年 | 60篇 |
1995年 | 83篇 |
1994年 | 54篇 |
1993年 | 58篇 |
1992年 | 54篇 |
1991年 | 37篇 |
1990年 | 32篇 |
1989年 | 20篇 |
1988年 | 35篇 |
1987年 | 20篇 |
1986年 | 15篇 |
1985年 | 21篇 |
1984年 | 13篇 |
1983年 | 8篇 |
1982年 | 15篇 |
1981年 | 15篇 |
1980年 | 14篇 |
1979年 | 5篇 |
1978年 | 9篇 |
1977年 | 12篇 |
1974年 | 5篇 |
1973年 | 2篇 |
排序方式: 共有5341条查询结果,搜索用时 15 毫秒
41.
R. Murugesan P. Sami T. Jeyabalan A. Shunmugasundaram 《Journal of Chemical Sciences》1995,107(1):1-10
Bonding and redox properties of mono- and dititanium substituted 12-heteropolytungsto-phosphates and their complexes with
bivalent Mn, Co, Ni and Cu are studied by UV-Vis, ESR and cyclicvoltammetric techniques. The heteropoly blue analogue [TiIIITiIVW10PO40]8− is unstable and its presence in solution is proved by optical and ESR spectroscopy. ESR results reveal that the odd electron
is trapped on the titanium atom at 77 K. The optical electronegativity of Ti(III) in this heteropoly blue is estimated to
be 2.4 from the intervalence charge transfer (IVCT) bands. X-ray powder diffraction results show that the complexes K5MII[Ti2W10PO40].xH2O(MII = Cu or Mn) are isomorphous with K7[Ti2W10PO40].6H2O. Electronic spectroscopy indicates very high symmetry around the bivalent metal ion M in the K5MII[Ti2W10PO40].xH2O complexes. This high symmetry is confirmed in K5Cu[Ti2W10PO40] by the observation of dynamic Jahn-Teller (JT) distortion at 300 K and static JT distortion at 77 K. 相似文献
42.
A multiparameter boundary-value problem of fresh infiltration water seepage in a drained fringe above quiescent saline water is solved in the direct statement and studied in detail. 相似文献
43.
N. B. Brusnikina A. V. Lotov 《Computational Mathematics and Mathematical Physics》2007,47(11):1779-1787
A method is proposed for approximating the reachable set of a dynamic system with a state space dimension no higher than six-eight considered on a finite time interval. The system is governed by linear differential equations with piecewise constant coefficients and impulse actions specified at prescribed times. The method is based on guaranteed-accuracy polyhedral approximations of reachable sets at researcher-specified times. Every approximation is constructed using the preceding one. A procedure is described for choosing parameters of the method that ensure the required accuracy with close-to-minimal time costs. 相似文献
44.
Characterization of semiconductor laser frequency chirp based on signal distortion in dispersive optical fiber 总被引:1,自引:0,他引:1
P. Krehlik 《Opto-Electronics Review》2006,14(2):119-124
In the paper, the simple method of laser chirp parameters estimation is presented. It is based on measuring time-domain distortions
of chirped signal transmitted through dispersive fiber and finding laser chirp parameters by matching measured distortions
to calculated ones. Experiments undertaken with 1.55 μm telecommunication grade distributed feedback (DFB) lasers and standard
single-mode fiber are described, together with some practical remarks on measurement setup and main conclusions. 相似文献
45.
WU Xiu-Lan WANG Fen REN Qiang 《结构化学》2007,26(6):732-736
Homogeneous cordierite has been synthesized at low cost by talc-magnesite and coal gangue as the main raw materials. The mechanism of synthesizing cordierite under such a com- posing system of raw materials, and the effect of temperature on the crystal cell parameters and microstructure and thermal expansion coefficient of cordierite crystal have been studied via testing methods of XRD, SEM, etc. The result shows that the homogeneous cordierite can be synthesized by the systematic composing materials of “talc-magnesite—coal gangue—talc” with heat pre- servation at 1350 ℃ for 1 h; as the keeping time is prolonged, Al3+ and Mg2+ in cordierite crystal are replaced by a few impurity ions such as Fe3+, Fe2+, etc., and the crystal cell parameters of cordierite present an increase trend; as the high-temperature heat preservation is prolonged, the content of glassy phase in the sample is increased, its density is improved, and its thermal expansion coeffi- cient presents an increase trend. 相似文献
46.
A new algorithm/program has been elaborated for simultaneous processing of different sets of vapour–liquid equilibrium data. The program was tested with six binary hexane + isomeric pentanol systems, each of them measured at three different isobaric conditions and one isothermal system of tert-butyl-methyl-ether + 2-methyl-2-propanol measured at three different temperatures. The correlation uses the maximum likelihood method, taking into account real behaviour of vapour phase. The parameters obtained are valid within the whole temperature range of the data, and are consistent in comparison with those obtained from individual correlations of isobars or isotherms. Results are presented for the Wilson and NRTL equations. 相似文献
47.
二(邻香草醛缩丙醇胺)异硫氰酸根合锰(Ⅲ)的合成与晶体结构 总被引:2,自引:0,他引:2
本文报道了一个新配合物—二(邻香草醛缩丙醇胺根)异硫氰酸根合锰(Ⅲ)的合成及其晶体结构。配合物属于单斜晶系,空间群为P21/c,晶胞参数为:a=8.565(1), b=21.814(2), c=12.787(2)?, β=92.80(1)°。锰为六配位,在两个邻香草醛缩丙醇胺Schiff碱配体中,一个为三齿配体,另一个为双齿配体。NCS-离子以N在轴向上与锰发生配位,由于Jahn-Teller效应,其键长为2.193?。另外晶胞中存在着罕见的H……S-C≡N氢键。 相似文献
48.
为了探讨铒离子掺杂材料的激光制冷可能性, 依据测量样品的吸收光谱, 计算了Er3 掺杂的ZBLAN玻璃材料的Judd-Ofelt参数, 得到Ω2=3.01×10-20 cm2, Ω4=1.59×10-20 cm2, Ω6=1.03×10-20 cm2, 进而获得了2H11/2, 4S3/2及其以下各能级间跃迁的跃迁几率、分支比、寿命等数据. 测量了77 K到315 K温度范围内Er3 较强的两个绿色发射2H11/2, 4S3/2→4I15/2的发射谱及荧光寿命. 讨论了2H11/2, 4S3/2这样处于热平衡中的两个能级的量子效率的计算方法, 进而计算了它们的量子效率, 并与其它材料进行了比较. 相似文献
49.
气液色谱法是研究酸碱相互作用热力学性质的有效方法之一,适合于气液表面化学反应的研究,可以得到一些用其他方法难以获得的热力学参数,丰富了表面化学领域的研究,具有重要的理论意义和应用价值。文献[1—4]利用气液色谱法测量了Ni[THDD]_2、Ni[(C_8H_(17)O)_2PS_2]_2与含氮、含氧有机碱加合反应的平衡常数、标准焓变和标准熵变值。作为酸碱加合反应研究的一部份,本文测定了Ni[C_8H_(17)O)_2PS_2]_2与五员杂环化合物呋喃、噻吩和吡咯反应的热力学参数。 相似文献
50.
In this review paper, the NBS scale and its limitations are briefly discussed. The magnitude of liquid junction potentials and some calculated values are presented. The use of a molality scale for hydrogen electrode concentration cells at high temperatures is described, and results from measurements on ionization equilibria are summarized. Use of this scale is also recommended for certain circumstances with cells without liquid junction. As an alternative activity scale, use of the Pitzer ion-interaction treatment for ions is recommended for special cases. Finally, reference data are presented for ±HCl in HCl(aq) to 350°C and (HCl+NaCl)(aq) to 200°C that were derived by use of the Pitzer ion-interaction treatment.Presented at the Second International Symposium on Chemistry in High Temperature Water, Provo, UT, August 1991. 相似文献