全文获取类型
收费全文 | 3796篇 |
免费 | 473篇 |
国内免费 | 580篇 |
专业分类
化学 | 1943篇 |
晶体学 | 22篇 |
力学 | 342篇 |
综合类 | 79篇 |
数学 | 1210篇 |
物理学 | 1253篇 |
出版年
2024年 | 13篇 |
2023年 | 37篇 |
2022年 | 53篇 |
2021年 | 85篇 |
2020年 | 85篇 |
2019年 | 94篇 |
2018年 | 79篇 |
2017年 | 133篇 |
2016年 | 136篇 |
2015年 | 136篇 |
2014年 | 225篇 |
2013年 | 309篇 |
2012年 | 248篇 |
2011年 | 247篇 |
2010年 | 207篇 |
2009年 | 243篇 |
2008年 | 281篇 |
2007年 | 282篇 |
2006年 | 218篇 |
2005年 | 225篇 |
2004年 | 191篇 |
2003年 | 164篇 |
2002年 | 154篇 |
2001年 | 129篇 |
2000年 | 111篇 |
1999年 | 112篇 |
1998年 | 108篇 |
1997年 | 93篇 |
1996年 | 66篇 |
1995年 | 55篇 |
1994年 | 50篇 |
1993年 | 24篇 |
1992年 | 52篇 |
1991年 | 27篇 |
1990年 | 25篇 |
1989年 | 14篇 |
1988年 | 20篇 |
1987年 | 11篇 |
1986年 | 18篇 |
1985年 | 13篇 |
1984年 | 15篇 |
1983年 | 4篇 |
1982年 | 9篇 |
1981年 | 11篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1977年 | 6篇 |
1976年 | 7篇 |
1974年 | 5篇 |
1973年 | 3篇 |
排序方式: 共有4849条查询结果,搜索用时 46 毫秒
41.
The density of neutral oxygen atoms in the MESOX set-up, one device of the PROMES-CNRS solar facilities, was determined by a fiber-optics catalytic probe (FOCP). Plasma was created in a flowing air within a quartz tube with the outer diameter of 5 cm by a 2.45 GHz microwave generator with the output power up to 1000 W. The flow of air was varied between 4 and 20 l/h. The O-atom density was found to increase monotonously with the increasing discharge power, and it decreased with the increasing flow rate. The degree of dissociation of oxygen molecules in the plasma column depended largely on the flow rate. At the air flow of 4 l/h it was about 80% but it decreased to about 20% at the flow of 20 l/h. 相似文献
42.
43.
44.
Relationships have been established between the average conversion degree and the dissociation time for polydisperse granular
material, taking its grain size distribution into account. It has been checked in which cases the kinetic curves obtained
by a numerical solution can be described in terms of KEKAM equation.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
45.
功能色素材料——苯重氮氨基偶氮苯类光度显色剂的研究罗小民周伟良孙培培吴斌才(华东师范大学化学系上海200062)关键词光度显色剂离解电子光谱HMO法中图分类号621.13功能色素材料包括光致变色、电致变色、热致变色和压敏变色材料以及光度显色剂等。这些... 相似文献
46.
47.
Relationships between average degree of transformation and time of dissociation were derived for polydisperse granular materials
with account to the type of grain size distribution. It has been checked, under what conditions the kinetic curves obtained
by numeric solution of those relationships may be described in terms of equations D1 α2=kt
, F2 [1/(1 - α) - 1 =kt] and F3 [1/(1 - α)2 - 1=kt].
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
48.
二组分混合物的最小流化特性 Ⅰ.混合/分离状态与最小流化空隙率 总被引:1,自引:0,他引:1
分析了二组分混合物的3种混合/分离状态及在完全混合时发生连续相转变的极限组成。提出一个判别非等密度体系混合/分离状态的法则与确定混合物空隙率简易可行的随意松散堆积方法。 相似文献
49.
Rabindra N. Roy Lakshmi N. Roy Jason G. Grant Mason P. Cummins Bennett J. Tabor III Sarah J. Richards Curtis A. Himes Bret R. Lively Penny L. Blackwell Ashley N. Simon 《Journal of solution chemistry》2002,31(11):861-872
The values of the second dissociation constant, pK
2, for the dissociation of the NH+ charge center of the zwitterionic buffer compounds 4-(N-morpholino)butanesulfonic acid (MOBS), and N-(2-hydroxyethyl)piperazine-N-4-butanesulfonic acid (HEPBS) have been determined from 5 to 55°C, including, 37°C at intervals of 5°C. The electromotive-force (emf) measurements have been made utilizing hydrogen electrodes and silver–silver chloride electrodes. The value of pK
2 for MOBS was found to be 7.702 ± 0.0005, and 8.284 ± 0.0004 for HEPBS, at 25°C, respectively. The related thermodynamic quantities, G
o, H
o, S
o, and C
p
o for the dissociation processes of MOBS and HEPBS have been derived from the temperature coefficients of pK
2. Both the MOBS and HEPBS buffer materials are useful as primary pH standards for the control of pH 7.3 to 8.6 in the region close to that of physiological fluids. 相似文献
50.
Thermodynamics of the dissociation of 2-aminopyridinium ion in synthetic seawater and a standard for pH in marine systems 总被引:1,自引:0,他引:1
Buffer solutions composed of 2-aminopyridinium chloride and 2-aminopyridine in synthetic seawater are useful as a supplement to buffers of Tris (pH 8.2) and Bis (pH 8.8) in standardizing measurements of hydrogen ion concentration (pm
H
or pH(SWS)) in oceanography. The dissociation constant of 2-amino-pyridinium ion over the range of salinities (S) from 30 to 40 has now been determined from the emf of cells without liquid junction at eight temperatures (T) from 278.15 to 313.15 K. The results fit the equation pK=2498.31/T–15.3274+2.4050 lnT+S(0.012928–2.9417×10–5T) with a standard deviation of 0.0023. Thermodynamic constants for the dissociation process and standard reference values of pm
H
and pH(SWS) were derived from the data. The pm
H
of the buffer consisting of 2-aminopyridinium chloride and 2-aminopyridine (each 0.04 molal) in synthetic seawater of salinity 35 varies from 7.356 at 278.15 K to 6.601 at 313.15 K. 相似文献