AFS–3100原子荧光光度计联机异常故障排除

介绍了北京海光仪器公司生产的AFS–3100原子荧光光度计在使用过程中仪器与电脑通讯失败的故障原因及排除方法。     

A Novel Chemo‐selective Epoxidation across Acrylate Ester: Synthesis of New Water‐Soluble Forskolin Analogues

While removing the TBDMS group from OH protection, a novel epoxidation reaction occurred across acrylate ester attached to a forskolin fragment. Besides spectroscopic data, the epoxide formation was confirmed by ring opening with a secondary amine. This unique epoxidation reaction, to our knowledge, is not known in the literature. This reaction led us to discover a simple deblocking protocol. The epoxide and the desired Michael substrates were used to introduce imidazole into forskolin.     

航空通信网络中复杂干扰过滤技术研究

航空通信环境中存在复杂的干扰信号,对正常的通信信号造成强烈的干扰。利用传统算法进行干扰信号过滤,无法避免由于干扰信号过于复杂导致过滤不充分的缺陷。提出一种基于加权残差优化算法的航空通信网络中复杂干扰过滤方法。对原始信号进行降频处理,能够消除峰值干扰信号,提高了信号的准确性。根据加权残差修正优化算法的相关原理,对通信信号进行残差优化处理,经过处理后的通信信号在受到干扰时会形成零陷,实现了对复杂干扰信号的过滤。实验结果表明,利用该算法进行航空通信网络中复杂干扰信号过滤,能够有效提高过滤的准确性,效果令人满意。     

智能弹药的实时仿真可视化系统设计

针对仿真可视化系统开发时间长、开发费用高的问题,提出了一种利用Unity3D引擎进行实时仿真可视化系统开发的模块式设计方法。首先,对武器仿真可视化系统进行了分析,提出了智能弹药实时仿真可视化系统的五大模块;然后,通过在3ds Max下建立智能弹药模型和Unity3D下的二次开发,构建了智能弹药仿真可视化系统的仿真环境,以C#为编程工具,设计了仿真驱动、串口数据通讯和仿真输出模块;最终,实现了智能弹药实时仿真可视化系统。实验证明,该系统可以有效地在监视器上实时显示出智能弹药的飞行姿态、飞行参数和飞行轨迹。     

Application of oxetane ring opening toward stereoselective synthesis of zincophorin fragment

A stereoselective synthesis of the C1–C11 fragment of zincophorin was achieved by using an intramolecular oxetane ring opening reaction as the key step. The oxetane moiety was synthesized by employing a desymmetrization protocol developed at our group and a non-Evans syn aldol as the key steps toward the synthesis.     

Stereoselective total synthesis of penaresidin A starting from d-galactal

A stereoselective total synthesis of penaresidin A has been accomplished involving Sharpless asymmetric epoxidation, regioselective ring-opening of epoxide, azetidine formation via S_N2 reaction, Jung’s protocol, and Julia–Kocienski olefination. This approach has successfully demonstrated the synthetic utility of d-galactal in the construction of azetidine core of the natural product.     

Fiber optical parametric amplifiers in optical communication systems

The prospects for using fiber optical parametric amplifiers (OPAs) in optical communication systems are reviewed. Phase‐insensitive amplifiers (PIAs) and phase‐sensitive amplifiers (PSAs) are considered. Low‐penalty amplification at/or near 1 Tb/s has been achieved, for both wavelength‐ and time‐division multiplexed formats. High‐quality mid‐span spectral inversion has been demonstrated at 0.64 Tb/s, avoiding electronic dispersion compensation. All‐optical amplitude regeneration of amplitude‐modulated signals has been performed, while PSAs have been used to demonstrate phase regeneration of phase‐modulated signals. A PSA with 1.1‐dB noise figure has been demonstrated, and preliminary wavelength‐division multiplexing experiments have been performed with PSAs. 512 Gb/s have been transmitted over 6,000 km by periodic phase conjugation. Simulations indicate that PIAs could reach data rate x reach products in excess of 14,000 Tb/s × km in realistic wavelength‐division multiplexed long‐haul networks. Technical challenges remaining to be addressed in order for fiber OPAs to become useful for long‐haul communication networks are discussed.

     

One-pot synthesis of dihydropyrimidines via eco-friendly phosphorus derivatives catalysis

A straightforward, cost effective and eco-friendly protocol for the Biginelli reaction relying on the use of readily available hypophosphorous acid is presented. The methodology developed displays improvements compared to existing methods, is high-yielding, robust and was applied to a panel of dihydropyrimidines and thio-derivatives with various substituents. Related urea derivatives such as guanidines, benzimidazoles and benzothiazoles also reacted efficiently to afford more complex scaffolds. Thus, this rapid and convenient catalysis allows access to a wide diversity of structures including original biologically relevant heterocycles.     

Avoiding Pitfalls in Comparison of Activity and Selectivity of Solid Catalysts for Electrochemical HMF Oxidation

Electrocatalytic oxidation of 5-hydroxymethylfurfural (HMF) offers a renewable approach to produce the value-added platform chemical 2,5-furandicarboxylic acid (FDCA). The key for the economic viability of this approach is to develop active and selective electrocatalysts. Nevertheless, a reliable catalyst evaluation protocol is still missing, leading to elusive conclusions on criteria for a high-performing catalyst. Herein, we demonstrate that besides the catalyst identity, secondary parameters such as materials of conductive substrates for the working electrode, concentration of the supporting electrolyte, and electrolyzer configurations have profound impact on the catalyst performance and thus need to be optimized before assessing the true activity of a catalyst. Moreover, we highlight the importance of those secondary parameters in suppressing side reactions, which has long been overlooked. The protocol is validated by evaluating the performance of free-standing Cu-foam, and CuCoO modified with NaPO₂H₂ and Ni, which were immobilized on boron-doped diamond (BDD) electrodes. Recommended practices and figure of merits in carefully evaluating the catalyst performance are proposed.     

Synthesis and Optoelectronic Properties of a Quinoxalino-Phenanthrophenazine (QPP) Extended Tribenzotriquinacene (TBTQ)

A six-step synthesis towards a tribenzotriquinacene (TBTQ) bearing three quinoxalinophenanthrophenazine (QPP) units is presented. The optoelectronic properties are investigated and the effect of the three-dimensional arrangement of the individual QPP planes is examined using optical spectroscopy, electrochemical analysis and quantum-chemical calculations.