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101.
102.
采用本体聚合法制备沥青改性聚甲基丙烯酸甲酯(PMMA)块体,研究了热辐射通量对其热释放速率平均值、质量损失速率平均值、点燃时间、CO及CO_2产率的影响。结果表明,添加沥青的PMMA点燃后300 s内平均热释放速率由569 kW/m~2降低到了525 kW/m~2,沥青使其燃烧更加平稳;沥青改性PMMA的平均热释放速率、质量损失速率和CO产率与热辐射通量成线性递增关系;点燃时间随着辐射通量的增加而呈指数衰减趋势;CO_2产率在热辐射通量低于40 kW/m~2时基本不变,高于40 kW/m~2时呈线性递增。添加沥青之后PMMA能够平稳燃烧使其可以作为锥形量热仪标准物质候选物,得到的燃烧特性与热辐射通量的函数关系式为其不确定度评估提供了依据。 相似文献
103.
In this paper, we report a thorough study on the thermal stability and fire behavior of polyethersulfone (PES) filled with 2 wt% nano-sized aluminum oxide hydroxide particles (boehmite). The nanocomposite was prepared through melt compounding technique in a co-rotating twin screw extruder. The obtained morphology of the composite was studied by scanning electron microscopy (SEM) coupled with elemental analysis, proving that an even distribution of sub-micron boehmite particles was obtained. PES shear modulus, measured by DMA, is increased by 30% in the boehmite nanocomposite. Thermal stability of the produced materials was studied through thermal gravimetric analysis (TGA), whereas the combustion behavior through cone calorimeter and vertical burning (UL-94) tests. Cone calorimeter results show that a significant overall flame retardant effect was observed due to the presence of boehmite nanoparticles, which could not be detected by UL-94 fire scenario where neat PES is already top ranked V0. 相似文献
104.
2,4-二硝基甲苯热解自催化特性鉴别及其热解动力学 总被引:1,自引:0,他引:1
为研究2,4-二硝基甲苯(2,4-DNT)的热危险性及其分解反应的特征, 利用差示扫描量热仪(DSC)对该物质进行了动态扫描测试, 得到其起始分解温度T0范围为272.4-303.5℃, 分解热ΔHd约为2.22 kJ·g-1. 在此基础上, 采用瑞士安全技术与保障研究所提出的快速鉴别法(瑞士方法)及数值模拟技术, 对其分解反应的特性参数进行了推算, 结果表明其分解具有自催化性. 采用Malek法分析了该物质分解反应的最概然机理函数并得出了相关动力学参数, 表明其分解具有自催化性且符合Sestak-Berggren 双参数自催化模型(SB模型), 这与瑞士方法所得结论一致. 采用等温DSC测试获得了该物质的‘钟形’热解曲线, 从而验证了两种方法的结论. 相似文献
105.
H. H. Hakobyan M. O. Simonyan 《Journal of Contemporary Physics (Armenian Academy of Sciences)》2007,42(5):209-213
Longitudinal profiles of pion and proton showers are measured, up to 20 nuclear interaction lengths at the energies of 20–180 GeV, Measurements have been performed in the iron-scintillation hadron Tile calorimeter of the ATLAS Project on the beams of the Super Proton Synchrotron (SPS) at the European Organization of Nuclear Research (CERN). Comparative analysis of longitudinal profiles of pion and proton showers was made. The experimental data were parameterized and compared with the results of Monte-Carlo simulation. 相似文献
106.
A conduction calorimeter was used to determine the effect of the ignition temperature on the hydration reactivity of C2S in the system C2S-C4A3¯S-C¯S relevant to sulphoaluminate belite cement. The results thus obtained showed that the kinetics and mechanism of hydration of the system C2S-C4A3¯S-C¯S are influenced by the temperature of C2S synthesis. The hydration reactivity of C2S increases with increasing temperature of ignition. 相似文献
107.
Two methods for the absolute calibration of flow calorimeters (used for measuring the differences in heat capacities of two fluids) have been investigated. In the recommended method of calibration, a change in the flow rate of the fluids is used to minic a change in the heat capacity of the fluid. In the other method of calibration, heat loss is measured using a fluid of known heat capacity, and it is assumed this heat loss is constant. This calibration method is not recommended because the heat loss is, in general, not constant. For some calorimeters the difference between the two methods of calibration is negligible, while for others erros as high as 40% are caused by choosing the wrong method. A detailed analysis of the heat losses in this kind of calorimetry shows why the two calibration methods give different results and leads to various methods of improving calorimeter construction and operation. Because chemical standardization is far more convenient for routine use, the recommended absolute calibration method has been used to establish 3.00 mol-kg–1 aqueous NaCl as a chemical standard for temperatures between 325 and 600K at 17.7 MPa. 相似文献
108.
109.
A flame-retardant epoxy resin based on a reactive phosphorus-containing monomer of DODPP and its thermal and flame-retardant properties 总被引:1,自引:0,他引:1
A flame-retardant epoxy resin (EP) was synthesized based on a novel reactive phosphorus-containing monomer, 4-[(5,5-dimethyl-2-oxide-1,3,2-dioxaphosphorinan-4-yl)oxy]-phenol (DODPP), and its structures were characterized by FTIR, 1H NMR and 31P NMR spectra. The DODPP-EP3/LWPA (low molecular weight polyamide), which contains 2.5% phosphorus, can reach UL-94 V-0 rating and a limiting oxygen index (LOI) value of 30.2%. The thermal properties and burning behaviours of cured epoxy resins were investigated by differential scanning calorimeter (DSC), thermogravimetry (TG), LOI, UL-94 tests and cone calorimetry. The morphologies of residues of cured epoxy resins were investigated by scanning electron microscopy (SEM). DSC shows that the glass-transition temperatures of cured epoxy resins decrease with increasing phosphorus content. TGA shows that the onset decomposition temperatures and the maximum-rate decomposition temperatures decrease, while char yields increase, with the increase of phosphorus content. The data from the cone calorimeter tests give the evidence that heat release rate (HRR), peak heat release rate (PHRR), average heat release rate (Av-HRR), average mass loss rate (Av-MLR) and the fire growth rate index (FIGRA) decrease significantly for DODPP-EP3/LWPA. SEM shows that the DODPP-EP3/LWPA forms lacunaris and compact charred layers which inhibit the transmission of heat during combustion. 相似文献
110.
Y. Xu-Wu Z. Hang-Guo S. Wu-Juan W. Xiao-Yan G. Sheng-Li 《Journal of Thermal Analysis and Calorimetry》2008,92(3):961-965
The copper(II) complex of 6-benzylaminopurine (6-BAP) has been prepared with dihydrated cupric chloride and 6-benzylaminopurine.
Infrared spectrum and thermal stabilities of the solid complex have been discussed. The constant-volume combustion energy,
Δc
U, has been determined as −12566.92±6.44 kJ mol−1 by a precise rotating-bomb calorimeter at 298.15 K. From the results and other auxiliary quantities, the standard molar enthalpy
of combustion, Δc
H
m
θ, and the standard molar of formation of the complex, Δf
H
m
θ, were calculated as −12558.24±6.44 and −842.50±6.47 kJ mol−1, respectively. 相似文献